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Motivated by renewed interest in the physics of branched polymers, we present here a complete characterization of the connectivity and spatial properties of $2$ and $3$-dimensional single-chain conformations of randomly branching polymers…

Soft Condensed Matter · Physics 2020-03-23 Irene Adroher-Benítez , Angelo Rosa

A ring polymer is a random walk whose steps obey a single linear condition; their sum vanishes. Factoring the graph Laplacian into the product of the incidence matrix and its transpose allows us to show that for a more complicated network,…

Statistical Mechanics · Physics 2025-10-20 Jason Cantarella , Tetsuo Deguchi , Clayton Shonkwiler , Erica Uehara

The statistical mechanics of a long knotted collapsed polymer is determined by a free-energy with a knot-dependent subleading term, which is linked to the length of the shortest polymer that can hold such knot. The only other parameter…

Statistical Mechanics · Physics 2014-12-01 Marco Baiesi , Enzo Orlandini , Attilio L. Stella

Unconcatenated, unknotted polymer rings in the melt are subject to strong interactions with neighboring chains due to the presence of topological constraints. We study this by computer simulation using the bond-fluctuation algorithm for…

Statistical Mechanics · Physics 2009-10-31 M. Mueller , J. P. Wittmer , M. E. Cates

Rooted, weighted continuum random trees are used to describe limits of sequences of random discrete trees. Formally, they are random quadruples $(\mathcal{T},d,r,p)$, where $(\mathcal{T},d)$ is a tree-like metric space, $r\in\mathcal{T}$ is…

Probability · Mathematics 2021-01-29 Noah Forman

Dynamical properties of a long polymer ring in a melt of unknotted and unconcatenated rings are calculated. We re-examine and generalize the well known model of a ring confined to a lattice of topological obstacles in the light of the…

Soft Condensed Matter · Physics 2015-06-22 Jan Smrek , Alexander Y. Grosberg

Stochastic simulations are used to characterize the knotting distributions of random ring polymers confined in spheres of various radii. The approach is based on the use of multiple Markov chains and reweighting techniques, combined with…

Soft Condensed Matter · Physics 2009-11-11 C. Micheletti , D. Marenduzzo , E. Orlandini , D. W. Sumners

Polymers in a melt may be subject to topological constraints, as in the example of unlinked polymer rings. How to do statistical mechanics in the presence of such constraints remains a fundamental open problem. We study the effect of…

Statistical Mechanics · Physics 2015-12-04 Pablo Serna , Guy Bunin , Adam Nahum

We study structural properties of a ring polymeric melt confined in a film in comparison to a linear counterpart using molecular dynamics simulations. Local structure orderings of ring and linear polymers in the vicinity of the surface are…

Soft Condensed Matter · Physics 2015-10-21 Eunsang Lee , YounJoon Jung

The statistics of meander and related problems are studied as particular realizations of compact polymer chain foldings. This paper presents a general discussion of these topics, with a particular emphasis on three points: (i) the use of a…

High Energy Physics - Theory · Physics 2007-05-23 P. Di Francesco , O. Golinelli , E. Guitter

The goal of these lectures is to review some mathematical aspects of random tree models used in evolutionary biology to model gene trees or species trees. We start with stochastic models of tree shapes (finite trees without edge lengths),…

Probability · Mathematics 2017-08-30 Amaury Lambert

Using well-known results from statistical physics, concerning the almost-sure behavior of the free energy of directed polymers in a random medium, we prove that random tree codes achieve the distortion-rate function almost surely under a…

Information Theory · Computer Science 2008-12-15 Neri Merhav

Two ring polymers close to each other in space may be either in a segregated phase if there is a strong repulsion between monomers in the polymers, or intermingle in a mixed phase if there is a strong attractive force between the monomers.…

Soft Condensed Matter · Physics 2022-11-23 EJ Janse van Rensburg , E Orlandini , MC Tesi , SG Whittington

Polymers are an effective test-bed for studying topological constraints in condensed matter due to a wide array of synthetically-available chain topologies. When linear and ring polymers are blended together, emergent rheological properties…

Soft Condensed Matter · Physics 2024-04-25 Daniel L. Vigil , Ting Ge , Michael Rubinstein , Thomas C. O'Connor , Gary S. Grest

The size of rings (also called cyclic polymers) in bidisperse blends of chemically identical rings is analyzed by computer simulations. Data of entangled ring blends and blends of interpenetrating rings are compared and it is shown that the…

Soft Condensed Matter · Physics 2021-03-31 Michael Lang

Random heteropolymers are a minimal description of biopolymers and can provide a theoretical framework to the investigate the formation of loops in biophysical experiments. A two--state model provides a consistent and robust way to study…

Quantitative Methods · Quantitative Biology 2016-09-28 Y. Zhan , L. Giorgetti , G. Tiana

We discuss a notion of convergence for binary trees that is based on subtree sizes. In analogy to recent developments in the theory of graphs, posets and permutations we investigate some general aspects of the topology, such as a…

Combinatorics · Mathematics 2024-02-14 Rudolf Grübel

Extensive molecular simulations are applied to characterize the equilibrium dynamics, entanglement topology, and nonlinear extensional rheology of symmetric ring-linear polymer blends with systematically varied ring fraction $\phi_R$.…

Soft Condensed Matter · Physics 2021-12-15 Thomas C. O'Connor , Ting Ge , Gary S. Grest

Monte Carlo simulations of coarse-grained polymers provide a useful tool to deepen the understanding of conformational and statistical properties of polymers both in physical as well as in biological systems. In this study we sample compact…

Soft Condensed Matter · Physics 2009-05-07 Manfred Bohn , Dieter W. Heermann

Rotation distances measure the differences in structure between rooted ordered binary trees. The one-dimensional skeleta of associahedra are rotation graphs, where two vertices representing trees are connected by an edge if they differ by a…

Data Structures and Algorithms · Computer Science 2020-06-29 Sean Cleary , Haris Nadeem