English
Related papers

Related papers: A global potential energy surface and dipole momen…

200 papers

The present work reports new total photoabsorption cross sections for the $N=Z$ nuclei in the $sd$-shell $^{20}$Ne, $^{24}$Mg, $^{28}$Si, $^{32}$S, $^{36}$Ar, and for $^{26}$Mg. The results are compared to predictions of a data-driven…

Nuclear Experiment · Physics 2026-01-21 R. W. Fearick , O. Le Noan , H. Matsubara , P. von Neumann-Cosel , K. Sieja , A. Tamii

The rovibronic (rotation-vibration-electronic) spectrum of the calcium monohydroxide radical (CaOH) is of interest to studies of exoplanet atmospheres and ultracold molecules. Here, we theoretically investigate the…

The role of numerical accuracy in training and evaluating neural network-based potential energy surfaces is examined for different experimental observables. For observables that require third- and fourth-order derivatives of the total…

Chemical Physics · Physics 2023-11-30 Silvan Käser , Markus Meuwly

The response of the antenna is a source of uncertainty in measurements with the Experiment to Detect the Global EoR Signature (EDGES). We aim to validate the beam model of the low-band (50-100 MHz) dipole antenna with comparisons between…

Instrumentation and Methods for Astrophysics · Physics 2021-07-07 Nivedita Mahesh , Judd D. Bowman , Thomas J. Mozdzen , Alan E. E. Rogers , Raul A. Monsalve , Steven G. Murray , David Lewis

The rise of machine learning has greatly influenced the field of computational chemistry, and that of atomistic molecular dynamics simulations in particular. One of its most exciting prospects is the development of accurate,…

Chemical Physics · Physics 2023-06-14 Silvan Käser , Markus Meuwly

Several nitrogen-bearing molecules, such as methyl cyanide (or acetonitrile, CH$_3$CN) and methyl isocyanide (CH$_3$NC) of interest here, have been observed in various astrophysical environments. The accurate modeling of their abundance…

Chemical Physics · Physics 2023-09-14 Malek Ben Khalifa , Paul J. Dagdigian , Jérôme Loreau

We describe a parallel linear-scaling computational framework developed to implement arbitrarily large multi-state empirical valence bond (MS-EVB) calculations within CHARMM. Forces are obtained using the Hellman-Feynmann relationship,…

Chemical Physics · Physics 2019-07-08 David R. Glowacki , Andrew J. Orr-Ewing , Jeremy N. Harvey

An active learning procedure called Deep Potential Generator (DP-GEN) is proposed for the construction of accurate and transferable machine learning-based models of the potential energy surface (PES) for the molecular modeling of materials.…

Computational Physics · Physics 2019-03-06 Linfeng Zhang , De-Ye Lin , Han Wang , Roberto Car , Weinan E

Beyond diagonal reconfigurable intelligent surface (BD-RIS), with its enhanced degrees of freedom compared to conventional RIS, has demonstrated notable potential for enhancing wireless communication performance. However, a key challenge in…

Signal Processing · Electrical Eng. & Systems 2025-09-15 Yijie Liu , Weidong Mei , He Sun , Dong Wang , Peilan Wang

The calculation of potential energy surfaces for quantum dynamics can be a time consuming task -- especially when a high level of theory for the electronic structure calculation is required. We propose an adaptive interpolation algorithm…

Chemical Physics · Physics 2016-08-24 Markus Kowalewski , Elisabeth Larsson , Alfa Heryudono

The Dipole-Quadrupole theory of Surface Enhanced Hyper Raman Scattering (SEHRS), created by the authors is expounded in details. Peculiarities of the behavior of electromagnetic field on rough metal surfaces are considered. It is…

Optics · Physics 2014-11-17 V. P. Chelibanov , A. M. Polubotko

A trivial flaw in the utilization of artificial neural networks in interpolating chemical potential energy surfaces (PES) whose descriptors are Cartesian coordinates is their dependence on simple translations and rotations of the molecule…

Chemical Physics · Physics 2020-09-15 Sean R. McConnell , Johannes Kästner

A high-dimensional potential energy surface (PES) for CO interaction with the Au(111) surface is developed using a machine-learning algorithm. Including both molecular and surface coordinates, this PES enables the simulation of the recent…

Chemical Physics · Physics 2019-12-04 Meng Huang , Xueyao Zhou , Yaolong Zhang , Linsen Zhou , Maite Alducin , Bin Jiang , Hua Guo

Artificial neural networks are used to fit a potential energy surface. We demonstrate the benefits of using not only energies, but also their first and second derivatives as training data for the neural network. This ensures smooth and…

Chemical Physics · Physics 2020-09-10 April M. Cooper , Philipp P. Hallmen , Johannes Kästner

Machine-learning-based interatomic potential energy surface (PES) models are revolutionizing the field of molecular modeling. However, although much faster than electronic structure schemes, these models suffer from costly computations via…

Computational Physics · Physics 2022-08-08 Denghui Lu , Wanrun Jiang , Yixiao Chen , Linfeng Zhang , Weile Jia , Han Wang , Mohan Chen

In this paper the full and exhaustive algorithm of formation of a smooth molecular Solvent Excluded Surface- SES, and also Solvent Accessible Surface- SAS is presented. These surfaces are a boundary between molecule and solvent. The basis…

Chemical Physics · Physics 2013-03-19 Oleg Kupervasser , N. E. Wanner

We summarize and discuss some of the available experimental and theoretical data important for understanding the role played by subsurface sites in dissociative chemisorption calculations for the H$_2$/Pd(111) system. Then we use a…

chem-ph · Physics 2009-10-28 Ole Martin Løvvik , Roar Aspesæter Olsen

Accurate and efficient simulation of excited state properties is an important and much aspired cornerstone in the study of adsorbate dynamics on metal surfaces. To this end, the recently proposed linear expansion \Delta Self-Consistent…

Materials Science · Physics 2013-07-23 Reinhard J. Maurer , Karsten Reuter

The possibility of cancelation between different contributions to d_e, d_n and d_{Hg} has been reconsidered with special emphasis on the region that is phenomenologically interesting (intermediate values of \tan \beta and sub-TeV sfermion…

High Energy Physics - Phenomenology · Physics 2014-11-18 Seyed Yaser Ayazi , Yasaman Farzan

A hybrid surface integral equation partial differential equation (SIE-PDE) formulation without the boundary condition requirement is proposed to solve the transverse magnetic (TM) electromagnetic problems. In the proposed formulation, the…

Numerical Analysis · Mathematics 2022-09-21 Aipeng Sun , Zekun Zhu , Shunchuan Yang , Zhizhang , Chen