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We study the significance and characteristics of interfacial dynamical charge transfer at metal-organic interfaces for the organic semiconductor model system 1,4,5,8-naphthalene-tetracarboxylic dianhydride (NTCDA) on Ag(111) quantitatively.…

Chemical Physics · Physics 2016-05-26 Phil Rosenow , Peter Jakob , Ralf Tonner

First-principles density-functional theory has been used to investigate equilibrium geometries, total energies, and diffusion barriers for H as an interstitial impurity absorbed in $\alpha$-Fe. Internal strains/stresses upon hydrogen…

Materials Science · Physics 2011-06-03 J. Sanchez , J. Fullea , C. Andrade , P. L. de Andres

Using a theory of polarizable fluids, we extend a variational treatment of an excess electron to the many-electron case corresponding to finite metal concentrations in metal-ammonia solutions (MAS). We evaluate dielectric, optical, and…

Statistical Mechanics · Physics 2009-11-13 Gennady N. Chuev , Pascal Quemerais , Jason Crain

Thermoelectric materials convert a temperature gradient into a voltage. This phenomenon is relatively well understood for inorganic materials, but much less so for organic semiconductors (OSs). These materials present a challenge because…

Diffusion is a fundamental physical phenomenon with critical applications in fields such as metallurgy, cell biology, and population dynamics. While standard diffusion is well-understood, anomalous diffusion often requires complex non-local…

Statistical Mechanics · Physics 2026-01-16 Gabriel Barreiro , Vladimir Pérez-Veloz

The application of modern layer-by-layer growth techniques to transition-metal oxide materials raises the possibility of creating new classes of materials with rationally designed correlated electron properties. An important step toward…

Materials Science · Physics 2010-10-07 Myung Joon Han , Chris A. Marianetti , Andrew J. Millis

Dielectric microstructures have been reported to have negative influences on perm-selective ion transportation because ions do not migrate in areas where the structures are located. However, the structure can promote the transportation if…

Applied Physics · Physics 2019-11-05 Keon Huh , So-Yoon Yang , Jae Suk Park , Jung A Lee , Hyomin Lee , Sung Jae Kim

We investigate the effect of hydrogen on the mobility of a screw dislocation in body-centered cubic (bcc) iron using first-principles calculations, and show that an increase of screw dislocation velocity is expected for a limited…

Materials Science · Physics 2013-10-16 M. Itakura , H. Kaburaki , M. Yamaguchi , T. Okita

Ion hydrations are ubiquitous in natural and fundamental processes. A quantitative analysis of a novel CO2 sorbent driven by ion hydrations was presented by molecular dynamics (MD). We explored the humidity effect on the diffusion and…

Chemical Physics · Physics 2017-02-23 Xiaoyang Shi , Hang Xiao , Xi Chen , Tao Wang , Klaus. S. Lackner

Groundwater pollution poses a significant threat to environmental sustainability during urbanization. Existing remediation methods like pump-and-treat and electrokinetics have limited ion transport control. This study introduces a coupled…

Cooling of atomic motion is a crucial tool for many branches of atomic physics, ranging from fundamental physics explorations to quantum information and sensing. For trapped ions, electromagnetically-induced-transparency (EIT) cooling has…

Efficient and safe energy storage technologies are essential for realizing a sustainable and electrified society. Among the key challenges, the design of superionic conductors for all-solid-state batteries often faces a fundamental…

Materials Science · Physics 2025-11-06 Rikuya Ishikawa , Kyohei Takae , Rei Kurita

The fast beam-ion instability (FII) is caused by the interaction of an electron bunch train with the residual gas ions. The ion oscillations in the potential well of the electron beam have an inherent frequency spread due to the nonlinear…

Accelerator Physics · Physics 2019-10-23 Gennady Stupakov

The search for materials displaying a large magnetoelectric effect has occupied researchers for many decades. The rewards could include not only advanced electronics technologies, but also fundamental insights concerning the dielectric and…

Many theoretical studies were devoted in the past to ion-specific effects, trying to interpret a large body of experimental evidence, such as surface tension at air/water interfaces and force measurements between charged objects. Although…

Soft Condensed Matter · Physics 2014-04-22 Dan Ben-Yaakov , David Andelman , Rudi Podgornik

The paper shows how the diffusive movement of ions through a channel protein can be described as a chemical reaction over an arbitrary shaped potential barrier. The result is simple and intuitive but without approximation beyond the…

Biomolecules · Quantitative Biology 2008-07-10 Bob Eisenberg

The variation with energy of the total cross section for elastic electron scattering from atoms of several elements is caused primarily by shape resonances corresponding to the formation of temporary negative ions. It is shown that such…

Atomic Physics · Physics 2007-05-23 Peter Nicoletopoulos

Atomistic computer simulations are applied to investigate the atomic structure, thermal stability, and diffusion processes in Al-Si interphase boundaries as a prototype of metal-ceramic interfaces in composite materials. Some of the most…

Materials Science · Physics 2023-08-24 Ian Chesser , Raj Koju , Akshay Vellore , Yuri Mishin

Dislocations are one-dimensional (1D) topological line defects where the lattice deviates from the perfect crystal structure. The presence of dislocations transcends condensed matter research and gives rise to a diverse range of emergent…

We find that ion creation/destruction dominates the behavior of electrochemical reaction barriers, through grand-canonical electronic structure calculations of proton-deposition on transition metal surfaces. We show that barriers respond to…

Chemical Physics · Physics 2023-11-10 Xi Chen , Georg Kastlunger , Andrew A. Peterson