English
Related papers

Related papers: Analysis of Generalized Debye-H\"uckel Equation fr…

200 papers

We consider a rather general class of evolutionary PDEs involving dissipation (of possibly fractional order), which competes with quadratic nonlinearities on the regularity of the overall equation. This includes as prototype models,…

Analysis of PDEs · Mathematics 2015-06-16 Animikh Biswas , Eitan Tadmor

We implement a well-established concept to consider dispersion effects within a Poisson-Boltzmann approach of continuum solvation of proteins. The theoretical framework is particularly suited for boundary element methods. Free parameters…

Biological Physics · Physics 2007-11-28 Parimal Kar , Max Seel , Ulrich H. E. Hansmann , Siegfried Hoefinger

The Poisson-Nernst-Planck-Bikermann (PNPB) model, in which the ions and water molecules are treated as different species with non-uniform sizes and valences with interstitial voids, can describe the steric and correlation effects in ionic…

Mathematical Physics · Physics 2022-01-06 Jian-Guo Liu , Yijia Tang , Yu Zhao

Hot, dense plasmas exhibit screened Coulomb interactions, resulting from the collective effects of correlated many-particle interactions. In the lowest particle correlation order (pair-wise correlations), the interaction between charged…

Atomic Physics · Physics 2016-11-29 R. K. Janev , Song Bin Zhang , Jian Guo Wang

Experimentally determined empirical formulae for the concentration dependent relative permittivity of aqueous solutions of MgCl$_{2}$ and NiCl$_{2}$ are utilized to calculate the osmotic coefficient and the mean activity coefficient of…

Soft Condensed Matter · Physics 2025-04-01 A. O. Quiñones , Z. Abbas , C. W. Outhwaite , L. B. Bhuiyan

The Vlasov-Poisson system for ions is a kinetic equation for dilute, unmagnetised plasma. It describes the evolution of the ions in a plasma under the assumption that the electrons are thermalized. Consequently, the Poisson coupling for the…

Analysis of PDEs · Mathematics 2026-05-15 Megan Griffin-Pickering

The Debye-Falkenhagen differential equation is commonly used as a mean-field macroscopic model for describing electrochemical ionic drift and diffusion in dilute binary electrolytes when subjected to a suddenly applied potential smaller…

Classical Physics · Physics 2023-08-02 Anis Allagui , Georgii Paradezhenko , Anastasiia Pervishko , Dmitry Yudin , Hachemi Benaoum

We study the steady state response of a dilute monovalent electrolyte solution to an external source with a constant relative velocity with respect to the fluid. The source is taken as a combination of three perturbations: an external force…

Fluid Dynamics · Physics 2018-09-19 Ram M. Adar , Yuki Uematsu , Shigeyuki Komura , David Andelman

We find that the Debye-H\"uckel nonideality of dilute aqueous electrolytes is sufficient to drive volume phase transitions and criticality, even in the absence of a self-attracting or elastic network. Our result follows from a Landau…

Soft Condensed Matter · Physics 2011-12-25 Kyle J. Welch , Fred Gittes

The Poisson-Boltzmann (PB) theory is one of the most important theoretical models describing charged systems continuously. However, it suffers from neglecting ion correlations, which hinders its applicability to more general charged systems…

Statistical Mechanics · Physics 2020-08-26 Mao Su , Yanting Wang

Non-local electrostatic interactions associated with the finite solvent size and ion polarizability are investigated within the mean-field linear response theory. To this end, we introduce a field theoretic model of a polar liquid composed…

Soft Condensed Matter · Physics 2015-06-15 Sahin Buyukdagli , Tapio Ala-Nissila

We reconsider the thermodynamic derivation by L. Boltzmann of the Stefan law and we generalize it for various different physical systems {\it whose chemical potential vanishes}. Being only based on classical arguments, therefore independent…

Quantum Gases · Physics 2018-04-09 Gilles Montambaux

The interaction between charged objects in an electrolyte solution is a fundamental question in soft matter physics. It is well-known that the electrostatic contribution to the interaction energy decays exponentially with object separation.…

Soft Condensed Matter · Physics 2017-08-02 Alpha A. Lee , Carla Perez-Martinez , Alexander M. Smith , Susan Perkin

We study the interactions between two negatively charged macroscopic surfaces confining positive counterions. A density-functional approach is introduced which, besides the usual mean-field interactions, takes into account the correlations…

Soft Condensed Matter · Physics 2015-06-25 A. Diehl , M. N. Tamashiro , Marcia C. Barbosa , Yan Levin

The behavior of a non-conductive quasi-planar lipid membrane in an electrolyte and in a static (DC) electric field is investigated theoretically in the nonlinear (Poisson-Boltzmann) regime. Electrostatic effects due to charges in the…

Soft Condensed Matter · Physics 2015-05-18 Falko Ziebert , David Lacoste

Mobile charge in an electrolytic solution can in principle be represented as the divergence of ionic polarization. After adding explicit solvent polarization a finite volume of electrolyte can then be treated as a composite non-uniform…

Soft Condensed Matter · Physics 2021-03-03 Michiel Sprik

The elusive presence of an anomalously increasing screening length at high ionic concentrations hampers a complete picture of interactions in electrolytes. Theories which extend the diluted Debye-Huckel framework to higher concentrations…

Soft Condensed Matter · Physics 2025-09-01 Ioannis Skarmoutsos , Stefano Mossa

The Poisson Nernst-Planck equations for charge concentration and electric potential in a ball is a model of electro-diffusion of ions in the head of a neuronal dendritic spine. We study the relaxation and the steady state when an initial…

Classical Physics · Physics 2015-05-12 Z. Schuss J. Cartailler , D. Holcman

We revisit the nonlinear second-order differential equations $$ \ddot{x}(t)=a (x )\dot{x}(t)^2+b(t)\dot{x}(t) $$ where $a(x)$ and $b(t)$ are arbitrary functions on their argument from the perspective of Lie-Hamilton systems. For the…

Mathematical Physics · Physics 2025-03-28 Rutwig Campoamor-Stursberg , Eduardo Fernandez-Saiz , Francisco J. Herranz

In this work, we study the Cauchy problem of Poiseuille flow of the full Ericksen-Leslie model for nematic liquid crystals. The model is a coupled system of two partial differential equations: One is a quasi-linear wave equation for the…

Analysis of PDEs · Mathematics 2023-09-06 Geng Chen , Weishi Liu , Majed Sofiani