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Ultraviolet (UV) radiation is common to most planetary environments, and could play a key role in the chemistry of molecules relevant to abiogenesis (prebiotic chemistry). In this work, we explore the impact of UV light on prebiotic…
The thermodynamic dissipation theory for the origin of life asserts a thermodynamic imperative for the origin of life, suggesting that the fundamental molecules of life originated as self-organized molecular photon dissipative structures…
Energetic processing of interstellar ice mantles and planetary atmospheres via photochemistry is a critical mechanism in the extraterrestrial synthesis of prebiotic molecules. Photochemistry is defined as chemical processes initiated by…
Potentially-habitable planets orbiting M-dwarfs are of intense astrobiological interest because they are the only rocky worlds accessible to biosignature search over the next 10+ years due to a confluence of observational effects.…
The origin of complex organic molecules such as amino acids and their precursors found in meteorites and comets is unknown. Previous studies have accounted for the complex organic inventory of the Solar System by aqueous chemistry on warm…
The dozens of rocky exoplanets discovered in the Circumstellar Habitable Zone (CHZ) currently represent the most suitable places to host life as we know it outside the Solar System. However, the presumed presence of liquid water on the CHZ…
The UV environment is a key boundary condition for the origin of life. However, considerable uncertainty exists as to planetary conditions and hence surface UV at abiogenesis. Here, we present two-stream multi-layer clear-sky calculations…
Ultraviolet (UV) light plays a key role in surficial theories of the origin of life, and numerous studies have focused on constraining the atmospheric transmission of UV radiation on early Earth. However, the UV transmission of the natural…
The growth of luminous structures and the building blocks of life in the Universe began as primordial gas was processed in stars and mixed at galactic scales. The mechanisms responsible for this development are not well understood and have…
Radiative feedback from populations II stars played a vital role in early structure formation. Particularly, photons below the Lyman limit can escape the star forming regions and produce a background ultraviolet (UV) flux which consequently…
UV radiation can induce photochemical processes in exoplanet atmospheres and produce haze particles. Recent observations suggest that haze and/or cloud layers could be present in the upper atmospheres of exoplanets. Haze particles play an…
Photochemistry has the potential to substantially impact the atmospheric composition of exoplanets with consequences on the radiative transfer, thermal structure and dynamics of the atmospheres, particularly in UV-rich stellar environments.…
In situ exploration of the planetary atmospheres requires the development of laboratory experiments to understand the molecular growth pathways initiated by photochemistry in the upper layers of the atmospheres. Major species and dominant…
The interstellar medium is characterized by a rich and diverse chemistry. Many of its complex organic molecules are proposed to form through radical chemistry in icy grain mantles. Radicals form readily when interstellar ices (composed of…
The ongoing discovery of exoplanets has sparked significant interest in finding suitable worlds that could potentially support life. Stellar ultraviolet (UV; 100-3000 \AA) radiation may play a crucial role in determining the habitability of…
The formation of low-mass stars in molecular clouds involves accretion disks and jets, which are of broad astrophysical interest. Accreting stars represent the closest examples of these phenomena. Star and planet formation are also…
In the search for life on Earth-like planets around other stars, the first (and likely only) information will come from the spectroscopic characterization of the planet's atmosphere. Of the countless number of chemical species terrestrial…
Ultraviolet radiation is known to inhibit photosynthesis, induce DNA destruction and cause damage to a wide variety of proteins and lipids. In particular, UV radiation between 200-300 nm becomes energetically very damaging to most of the…
We describe the photochemical dissipative structuring of fatty acids from CO and CO2 saturated water under the solar UVC and UVA photon potential prevalent at Earth's surface during the Archean. Their association into vesicles and their…
Solar X-ray and UV radiation (0.1-320 nm) received at Earth's surface is an important aspect of the circumstances under which life formed on Earth. The quantity that is received depends on two main variables: the emission of radiation by…