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The rates of exciton transfer within dyads of perylene diimide and terrylene diimide connected by oligophenylene bridge units have been shown to deviate significantly from those of F\"{o}rster's resonance energy transfer theory, according…

Chemical Physics · Physics 2026-01-13 Lei Yang , Seogjoo J. Jang

We investigate the steady-state electronic transport through a suspended dimer molecule coupled to leads. When strongly coupled to a vibrational mode, the electron transport is enhanced at the phonon resonant frequency and higher-order…

Mesoscale and Nanoscale Physics · Physics 2013-02-18 D. H. Santamore , Neill Lambert , Franco Nori

The time-development of photoexcitations in molecular aggregates exhibits specific dynamics of electronic states and vibrational wavefunction. We discuss the dynamical formation of entanglement between electronic and vibrational degrees of…

Quantum Physics · Physics 2007-05-23 Dmitri S. Kilin , Jeffrey A. Cina , Oleg V. Prezhdo

Symmetry breaking caused by geometric fluctuations can enable processes that are otherwise forbidden. An example is a perylene bisimide dyad whose dipole moments are perpendicular to each other. F\"orster-type energy transfer is thus…

Chemical Physics · Physics 2014-12-18 N. Mann , P. Nalbach , S. Mukamel , M. Thorwart

Controlling energy transfer through vibronic resonance is an interesting possibility. Exact treatment of non-adiabatic vibronic coupling is necessary to fully capture its role in driving energy transfer. However, exact treatment of…

Chemical Physics · Physics 2024-06-19 Sanjoy Patra , Amitav Sahu , Vivek Tiwari

Transfer and decay dynamics of an exciton coupled to a polarization vibration in a dimer is investigated in a mixed quantum-classical picture with the exciton decay incorporated by a sink site. Using a separation of time scales, it is…

Condensed Matter · Physics 2009-10-28 Holger Schanz , Ivan Barvik , Bernd Esser

Following the observation of coherent oscillations in non-linear spectra of photosynthetic pigment protein complexes, particularly phycobilliprotein such as PC645, coherent vibronic transport has been suggested as a design principle for…

We study the response of a Dirac fluid to electric fields and thermal gradients at finite wave-numbers and frequencies in the hydrodynamic regime. We find that non-local transport in the hydrodynamic regime is governed by infinite set of…

Strongly Correlated Electrons · Physics 2021-01-05 Egor I. Kiselev , Joerg Schmalian

We have implemented vibronic dynamics for simulations of the third order coherent response of electronic dimers. In the present communication we provide the full and detailed description of the dynamical model, recently used for simulations…

Chemical Physics · Physics 2017-08-31 Václav Perlík , František Šanda

We present calculations of electronic quantum transport in graphene nanoribbons with adsorbed H, F, OH and O, based on a tight binding model derived from extended Huckel theory. The relaxed atomic geometries of the adsorbates and graphene…

Mesoscale and Nanoscale Physics · Physics 2011-06-29 S. Ihnatsenka , G. Kirczenow

Transport in a one-dimensional symmetric device can be activated by the combination of thermal noise and a bi-harmonic drive. For the study case of an overdamped Brownian particle diffusing on a periodic one-dimensional substrate, we…

Statistical Mechanics · Physics 2009-11-11 M. Borromeo , F. Marchesoni

Recent ultrafast optical experiments show that excitons in large biological light-harvesting complexes are coupled to molecular vibration modes. These high-frequency vibrations will not only affect the optical response, but also drive the…

Quantum Physics · Physics 2015-02-12 Arend G. Dijkstra , Chen Wang , Jianshu Cao , Graham R. Fleming

Vibronic effects in resonant electron transport through single-molecule junctions are analyzed. The study is based on generic models for molecular junctions, which include electronic states on the molecular bridge that are vibrationally…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 R. Härtle , M. Thoss

We demonstrate the flexible tunability of excitation transport in Rydberg atoms, under the interplay of controlled dissipation and interaction-induced synthetic flux. Considering a minimum four-site setup -- a triangular configuration with…

Atomic Physics · Physics 2024-03-19 Yiwen Han , Wei Yi

The theoretical and experimental study of energy transfer in photosynthesis has revealed an interesting transport regime, which lies at the borderline between classical transport dynamics and quantum-mechanical interference effects.…

Biological Physics · Physics 2014-02-13 Tobias Kramer , Christoph Kreisbeck

Energy transfer mechanisms for vortex shedding behind a 2D cylinder at a Reynolds number of Re=100 are investigated. We first characterize the energy balances achieved by the true cylinder flow -- both for the flow as a whole and for each…

Fluid Dynamics · Physics 2021-02-24 Bo Jin , Sean Symon , Simon J. Illingworth

The adsorption structure of the molecular switch azobenzene on Ag(111) is investigated by a combination of normal incidence x-ray standing waves and dispersion-corrected density functional theory. The inclusion of non-local collective…

We study transfer of coherent nuclear oscillations between an excitation energy donor and an acceptor in a simple dimeric electronic system coupled to an unstructured thermodynamic bath and some pronounced vibrational intramolecular mode.…

Chemical Physics · Physics 2015-01-08 Tomáš Mančal , Jakub Dostál , Jakub Pšenčík , Donatas Zigmantas

Understanding the transport mechanism of electronic excitations in conjugated polymers is key to advancing organic optoelectronic applications, such as solar cells, OLEDs and flexible electronics. While crystalline polymers can be studied…

Materials Science · Physics 2021-12-13 Francesco Campaioli , Jared H. Cole

We investigate the electron (hole) transport through short double-stranded DNA wires in which the electrons are strongly coupled to the specific vibrational modes (vibrons) of the DNA. We analyze the problem starting from a tight-binding…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Benjamin B. Schmidt , Matthias H. Hettler , Gerd Schön
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