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The current state of the art in direct water splitting in photo-electrochemical cells (PECs) is presented together with: (i) a case study of water splitting using a simple solar cell with the most efficient water splitting electrodes and…

Although photoelectrochemical water splitting is likely to be an important and powerful tool to provide environmentally friendly hydrogen, most developments in this field have been conducted on a laboratory scale so far. In order for the…

Solar water splitting provides a promising path for sustainable hydrogen production and solar energy storage. One of the greatest challenges towards large-scale utilization of this technology is reducing the hydrogen production cost. The…

Photoelectrochemical (PEC) water splitting offers an elegant approach for solar energy conversion into hydrogen fuel. Large-scale hydrogen production requires stable and efficient photoelectrodes and scalable PEC cells that are fitted for…

Photosynthesis is nature's route to convert intermittent solar irradiation into storable energy, while its use for an industrial energy supply is impaired by low efficiency. Artificial photosynthesis provides a promising alternative for…

Materials Science · Physics 2015-09-16 Matthias M. May , Hans-Joachim Lewerenz , David Lackner , Frank Dimroth , Thomas Hannappel

Photoelectrochemical (PEC) water splitting to generate hydrogen is one of the most studied methods for converting solar energy into clean fuel because of its simplicity and potentially low cost. Despite over 40 years of intensive research,…

Materials Science · Physics 2019-01-02 Ling-Ju Guo , Jun-Wei Luo , Tao He , Su-Huai Wei , Shu-Shen Li

Photocatalytic water splitting has greatly stimulated as an ideal technique for producing hydrogen (H$_{2}$) fuel by employing two renewable sources, i.e., water and solar energy. Here, we have adopted a facile hydrothermal approach for the…

Chemical Physics · Physics 2022-01-04 Fahmida Sharmin , Dayal Chandra Roy , M. A. Basith

We propose a solar thermal energy conversion system consisting of a solar absorber, a thermoradiative cell or negative illumination photodiode, and a photovoltaic cell. Because it is a heat engine, this system can also be paired with…

The majority of photoelectrochemical (PEC) water splitting cells cannot drive the overall water splitting reactions without the assistance of an external power source. To provide added power, the cells are usually connected to photovoltaic…

Applied Physics · Physics 2018-10-31 Gideon Segev , Jeffery Beeman , Ian D. Sharp

The photocatalytic splitting of water into molecular hydrogen and molecular oxygen with sunlight is the dream reaction for solar energy conversion. Since decades, transition-metal-oxide semiconductors and supramolecular organometallic…

Chemical Physics · Physics 2018-07-10 Wolfgang Domcke , Johannes Ehrmaier , Andrzej L. Sobolewski

We develop a new approach to calculate the obtainable limit of photoconversion efficiency of tandem solar cells (SCs) and applied it to SCs with both vertical and lateral designs at AM0 and AM1.5 conditions. To get the maximum efficiency,…

Materials Science · Physics 2013-09-13 A. V. Sachenko , V. P. Kostylyov , N. P. Kulish , I. O. Sokolovskyi , A. I. Shkrebtii

In this perspective, we discuss a novel water-splitting scenario, namely the direct oxidation of water molecules by organic photooxidants in hydrogen-bonded chromophore-water complexes. In comparison with the established scenario of…

Chemical Physics · Physics 2022-03-15 Wolfgang Domcke , Andrzej L. Sobolewski

STEP (Solar Thermal Electrochemical Production) is an alternative solar energy conversion process. New and original, unpublished STEP results are compared with other STEP results. The STEP process uses semiconductors, solar energy and…

Materials Science · Physics 2019-01-23 Stuart Licht

We adapt the computational hydrogen electrode approach to explicitly account for photo-generated charges and use it to computationally screen for viable catalyst/co-catalyst combinations for photo-catalytic water splitting. The hole energy…

Materials Science · Physics 2013-07-31 Harald Oberhofer , Karsten Reuter

The splitting of water with sunlight using photoelectrochemical cell (PEC) to produce hydrogen is a promising avenue for sustainable energy production. The greatest virtue of PEC is that it uses sunlight as the only source to split water,…

Chemical Physics · Physics 2013-05-14 Qiang Yu , Chuanbao Cao

Fuel cells, batteries, thermochemical and other energy conversion devices involve the transport of a number of (electro-)chemical species through distinct materials so that they can meet and react at specified multi-material interfaces.…

Analysis of PDEs · Mathematics 2017-02-02 Lincoln Collins , Kaushik Bhattacharya

Concentrating solar power, particularly parabolic trough system with solar concentrations less than 50, requires spectrally selective solar absorbers that are thermally stable at high temperatures of 400degC above to achieve high…

Applied Physics · Physics 2020-12-16 Hassan Alshehri , Qing Ni , Sydney Taylor , Ryan McBurney , Hao Wang , Liping Wang

Solar cell thermal recovery is recently attracting more and more attention in the research community as a viable solution to increase photovoltaic efficiency. However the convenience of the implementation of such strategy is bound to the…

Applied Physics · Physics 2018-09-06 Bruno Lorenzi , Maurizio Acciarri , Dario Narducci

Recently, significant progress in the development of III-V/Si dual-junction solar cells has been achieved. This not only boosts the efficiency of Si-based photovoltaic solar cells, but also offers the possibility of highly efficient green…

We obtain theoretical expressions for the photocurrent in the Heterojunction solar cells with Intrinsic Thin layer (HIT cells). Our calculations take into account tunneling of electrons and holes through wide-bandgap layers of $\alpha$-Si:H…

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