Related papers: The Gibbs Paradox
For an ideal gas consisting N molecules within a volume V, the volume accessible to each molecule at an instantaneous time is V/N. The rest of the volume, (N-1)(V/N), is occupied by other (N-1) molecules. The textbook assumption that a…
This letter presents a new, solely thermodynamical argument for considering the states of the quantum isolated horizon of a black hole as distinguishable. We claim that only if the states are distinguishable, the thermodynamic entropy is an…
Liquid-gas phase transition in statistical mechanics is a long-standing dilemma not yet well explained. In this paper we propose a novel approach to this dilemma, by: 1). Putting forth a new space homogeneity assumption. 2). Giving a new…
For a thought experiment concerning the mixing of two classical gases, Gibbs concluded that the work that can be extracted from mixing is determined by whether or not the gases can be distinguished by a semi-permeable membrane; that is, the…
The dynamical convergence of a system to the thermal distribution, or Gibbs state, is a standard assumption across all of the physical sciences. The Gibbs state is determined just by temperature and the system's energies alone. But at…
Statistical classical mechanics and quantum mechanics are developed and well-known theories that represent a basis for modern physics. The two described theories are well known and have been well studied. As these theories contain numerous…
We introduce into classical mechanics the concept of non-discerned particles for particles that are identical, non-interacting and prepared in the same way. The non-discerned particles correspond to an action and a density which satisfy the…
The statistical mechanics of Gibbs is a juxtaposition of subjective, probabilistic ideas on the one hand and objective, mechanical ideas on the other. In this paper, we follow the path set out by Jaynes, including elements added…
The formulas for the entropy of ideal gases mixture and the entropy change in mixing of ideal gases on the basis of the third law of thermodynamics were obtained. It is shown that when using these formulas, the Gibbs paradox within the…
In the framework of Gibbs statistical theory, the issue of the distribution of particle sizes forming the statistical system and the moments of this distribution are considered. This task is relevant for a wide variety of applications. The…
In statistical mechanics, the generally called Stirling approximation is actually an approximation of Stirling's formula. In this article, it is shown that the term that is dropped is in fact the one that takes fluctuations into account.…
There are three levels of description in classical statistical mechanics, the microscopic/dynamic, the macroscopic/statistical and the thermodynamic. At one end there is a well-used concept of equilibrium in thermodynamics and at the other…
The Gibbs entropy of a macroscopic classical system is a function of a probability distribution over phase space, i.e., of an ensemble. In contrast, the Boltzmann entropy is a function on phase space, and is thus defined for an individual…
The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature since every material absorbs and…
Gibbs measure is one of the central objects of the modern probability, mathematical statistical physics and euclidean quantum field theory. Here we define and study its natural generalization for the case when the space, where the random…
It is well known that, in the context of General Relativity, some spacetimes, when described by a congruence of comoving observers, may consist in a distribution of a perfect (non-dissipative) fluid, whereas the same spacetime as seen by a…
The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature of the theory since every material in…
Colloidal particles are distinguishable. Moreover, their thermodynamic properties are extensive. Statistical Mechanics predicts such behaviour if one accepts that the configurational integral of a system of N colloids must be divided by N!.…
In Physica A vol 387(24) (2008) pp6079-6094 [1], a kinetic equation for gas flows was proposed that leads to a set of four macroscopic conservation equations, rather than the traditional set of three equations. The additional equation…
In this chapter we address the topic of quantum thermodynamics in the presence of additional observables beyond the energy of the system. In particular we discuss the special role that the generalized Gibbs ensemble plays in this theory,…