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Within the micro-canonical ensemble phase transitions of first order can be identified without invoking the thermodynamic limit. We show for the liquid-gas transition of sodium, potassium, and iron at normal pressure that the transition…

Condensed Matter · Physics 2008-02-03 D. H. E. Gross , M. E. Madjet

We study NaCl ion-pair dissociation in a dilute aqueous solution using computer simulations both for the full system with long range Coulomb interactions and for a well chosen reference system with short range intermolecular interactions.…

Chemical Physics · Physics 2021-10-13 Dedi Wang , Renjie Zhao , John D. Weeks , Pratyush Tiwary

Colloidal crystals formed by size-asymmetric binary particles co-assemble into a wide variety of colloidal compounds with lattices akin to ionic crystals. Recently, a transition from a compound phase with a sublattice of small particles to…

Soft Condensed Matter · Physics 2023-09-12 Ali Ehlen , Hector Lopez-Rios , Monica Olvera de la Cruz

Double ionization of diatomic molecules by short linearly polarized laser pulses is analyzed. We consider the final stage of the ionization process, that is the decay of a highly excited two electron molecule, which is formed after…

Atomic Physics · Physics 2016-09-08 Jakub S. Prauzner-Bechcicki , Krzysztof Sacha , Bruno Eckhardt , Jakub Zakrzewski

The process of homogeneous crystal nucleation has been considered in a model liquid, where the interparticle interaction is described by a short-range spherical oscillatory potential. Mechanisms of initiating structural ordering in the…

Materials Science · Physics 2018-12-18 Bulat N. Galimzyanov , Dinar T. Yarullin , Anatolii V. Mokshin

The model of dipole fluid for the ionic liquids similar to the molten NaCl is proposed. The estimates for the critical parameters are obtained with the help of the van der Waals equation of state. The influence of the rotation on the…

Soft Condensed Matter · Physics 2009-11-07 V. L. Kulinskii , N. P. Malomuzh

Previous experimental reports of long-range interactions in ionic liquids (ILs) stand in contradiction with theoretical predictions and numerical simulations. To provide insights into the literature discrepancies regarding the experimental…

Soft Condensed Matter · Physics 2026-03-24 Benjamin Cross , Léo Garcia , Elisabeth Charlaix , Patrick Kékicheff

The transition from a nematic to an isotropic state in a self-closing spherical liquid crystal shell with tangential alignment is a stimulating phenomenon to investigate, as the topology dictates that the shell exhibits local isotropic…

Soft Condensed Matter · Physics 2024-02-02 Yucen Han , Jan Lagerwall , Apala Majumdar

In this work, we study the nematic-isotropic phase transition based on the dynamics of the Landau--De Gennes theory of liquid crystals. At the critical temperature, the Landau--De Gennes bulk potential favors the isotropic phase and nematic…

Analysis of PDEs · Mathematics 2021-07-28 Tim Laux , Yuning Liu

Sessile droplets of a ferroelectric nematic liquid crystalline material were exposed to surface electric fields produced by pyroelectric and photogalvanic (photovoltaic) effects in X-cut iron-doped lithium niobate crystals. The resulting…

Surface active ionic liquids (SAILs) combine useful characteristics of both ionic liquids (ILs) and surfactants, hence are promising candidates for a wide range of applications. However, the effect of SAIL ionic structures on their…

Using Shapefinders, which are ratios of Minkowski functionals, we study the morphology of neutral hydrogen (HI) density fields, simulated using semi-numerical technique (inside-out), at various stages of reionization. Accompanying the…

Cosmology and Nongalactic Astrophysics · Physics 2018-09-21 Satadru Bag , Rajesh Mondal , Prakash Sarkar , Somnath Bharadwaj , Varun Sahni

The existence of a phase transition between two distinct liquid phases in single-component network-forming liquids (e.g., water, silica, silicon) has elicited considerable scientific interest. The challenge, both for experiments and…

Soft Condensed Matter · Physics 2022-05-30 Yagyik Goswami , Srikanth Sastry

Lithium-ion transport is significantly retarded in ionic liquids (ILs). In this work, we performed extensive molecular dynamics (MD) simulations to mimic the kinetics of lithium ions in ILs using [\emph{N}-methyl-\emph{N}-propylpyrrolidium…

Computational Physics · Physics 2023-09-19 YeongKyu Lee , JunBeom Cho , Junseong Kim , Won Bo Lee , YongSeok Jho

The phase behaviour and dynamics of molecular ionic liquids are studied using primitive models and extensive computer simulations. The models account for size disparity between cation and anion, charge location on the cation, and…

Soft Condensed Matter · Physics 2012-02-23 G. C. Ganzenmüller , P. J. Camp

A longstanding question in water research is the possibility that supercooled liquid water can undergo a liquid-liquid phase transition (LLT) into high- and low-density liquids. We used several complementary molecular simulation techniques…

Liquid crystals in two dimensions do not support long-ranged nematic order, but a quasi-nematic phase where the orientational correlations decay algebraically is possible. The transition from the isotropic to the quasi-nematic phase can be…

Statistical Mechanics · Physics 2014-12-30 Richard L. C. Vink

Viscoelastic phase separation of colloidal suspensions can be interrupted to form gels either by glass transition or by crystallization. With a new confocal microscopy protocol, we follow the entire kinetics of phase separation, from…

Soft Condensed Matter · Physics 2018-02-05 Hideyo Tsurusawa , John Russo , Mathieu Leocmach , Hajime Tanaka

We present Monte Carlo simulation results of the two-dimensional Zwanzig fluid, which consists of hard line segments which may orient either horizontally or vertically. At a certain critical fugacity, we observe a phase transition with a…

Statistical Mechanics · Physics 2009-11-13 T. Fischer , R. L. C. Vink

Computer simulations are presented of the isotropic-to-nematic transition in a liquid crystal confined between two parallel plates a distance H apart. The plates are neutral and do not impose any anchoring on the particles. Depending on the…

Statistical Mechanics · Physics 2010-08-20 J. M. Fish , R. L. C. Vink