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Many intercalation compounds possess layered structures or inter-penetrating lattices that enable phase separation into three or more stable phases, or "stages," driven by competing intra-layer and inter-layer forces. While these structures…

Chemical Physics · Physics 2017-06-27 Raymond B. Smith , Edwin Khoo , Martin Z. Bazant

We develop a convergent reaction-drift-diffusion master equation (CRDDME) to facilitate the study of reaction processes in which spatial transport is influenced by drift due to one-body potential fields within general domain geometries. The…

Numerical Analysis · Mathematics 2025-01-22 Samuel A. Isaacson , Ying Zhang

A mathematical model has been developed to simulate the kinetic and thermal behaviour of a porous solid pellet undergoing chemical reaction with a gas. The model describes the chemical reaction itself, the transfer of the gaseous species…

Chemical Physics · Physics 2016-12-14 F Patisson , D Ablitzer

We introduce a microscopically realistic model of a physical gel and use computer simulations to study its static and dynamic properties at thermal equilibrium. The phase diagram comprises a sol phase, a coexistence region ending at a…

Soft Condensed Matter · Physics 2015-06-25 Pablo I. Hurtado , Ludovic Berthier , Walter Kob

Physics-guided sampling with diffusion model priors has shown promise for solving partial differential equation (PDE) governed problems, but applications to chemically meaningful reaction-transport systems remain limited. We apply…

Chemical Physics · Physics 2026-03-06 Andrew Millard , Henrik Pedersen

A collisional model of a confined quasi-two-dimensional granular mixture is considered to analyze homogeneous steady states. The model includes an effective mechanism to transfer the kinetic energy injected by vibration in the vertical…

Statistical Mechanics · Physics 2020-12-30 Ricardo Brito , Rodrigo Soto , Vicente Garzó

We investigate Turing instability and pattern formation in two-dimensional domains for two reaction-diffusion models, obtained as diffusive limits of kinetic equations for mixtures of monatomic and polyatomic gases. The first model is of…

Mathematical Physics · Physics 2026-02-23 Stefano Boccelli , Giorgio Martalò , Romina Travaglini

We investigate the fast-reaction asymptotics for a one-dimensional reaction-diffusion (RD) system describing the penetration of the carbonation reaction in concrete. The technique of matched-asymptotics is used to show that the RD system…

Materials Science · Physics 2011-12-30 Jonathan D. Evans , Andrea Fernández , Adrian Muntean

The steady-state of a generalized coagulation-decoagulation model on a one-dimensional lattice with reflecting boundaries is studied using a matrix-product approach. It is shown that the quadratic algebra of the model has a four-dimensional…

Statistical Mechanics · Physics 2009-11-13 Farhad H. Jafarpour , Ali Aghamohammadi

We complete the existing literature on the kinetic theory of systems with long-range interactions. Starting from the BBGKY hierarchy, or using projection operator technics or a quasilinear theory, a general kinetic equation can be derived…

Statistical Mechanics · Physics 2015-05-18 Pierre-Henri Chavanis

A generalized kinetic model equation which takes into account the frequency depence of the thermal conductivity is used to analyze the problem of sound propagation in dilute polyatomic gases. By comparing the theoretical results with some…

Fluid Dynamics · Physics 2015-06-15 Sebastian Fischer , Wilson Marques

A simple one-dimensional gas-piston kinetic model gives the interaction potential between two colliding heavy ions. In the frame of the classical, thermodynamical approach, the colliding heavy ions are not submitted to friction, but…

Nuclear Theory · Physics 2019-05-10 Mario J. Pinheiro

A thermodynamic approach to rapid phase transformations within a diffuse interface in a binary system is developed. Assuming an extended set of independent thermodynamic variables formed by the union of the classic set of slow variables and…

Materials Science · Physics 2009-11-10 Peter Galenko , David Jou

A solid-liquid-gas moving contact line is considered through a diffuse-interface model with the classical boundary condition of no-slip at the solid surface. Examination of the asymptotic behaviour as the contact line is approached shows…

Fluid Dynamics · Physics 2013-10-07 David N. Sibley , Andreas Nold , Nikos Savva , Serafim Kalliadasis

Soft condensed matter structures often challenge us with complex many-body phenomena governed by collective modes spanning wide spatial and temporal domains. In order to successfully tackle such problems mesoscopic coarse-grained (CG)…

Soft Condensed Matter · Physics 2023-07-12 Vlad P Sokhan , Michael A Seaton , Ilian T Todorov

The step motions considered are those in which crystallization is controlled by a single diffusion process, either the substance diffusion for growth from solution or the flow of latent heat from the step for growth from melt. Quasi-static…

Condensed Matter · Physics 2009-10-22 Serge Yu. Potapenko

We study a nonlinear kinetic model of mass exchange between interacting grains. The transition rates follow the Arrhenius equation with an activation energy that depends on the grain mass. We show that the activation parameter can be…

Statistical Mechanics · Physics 2015-10-27 Dionissios T. Hristopulos , Aliki D. Muradova

The behavior of dynamical system interacting with non-equilibrium medium is investigated. Formally exact kinetic equations are derived for the statistical operator of the dynamical system and the macroscopic parameters of the medium. In the…

Statistical Mechanics · Physics 2016-12-30 Mikheil Zviadadze , Alexander kvirikadze

Motivated by bacterial chemotaxis and multi-species ecological interactions in heterogeneous environments, we study a general one-dimensional reaction-cross-diffusion system in the presence of spatial heterogeneity in both transport and…

Pattern Formation and Solitons · Physics 2023-03-08 Eamonn A. Gaffney , Andrew L. Krause , Philip K. Maini , Chenyuan Wang

In this work, a thermodynamically consistent and conservative diffuse-interface model for gas-liquid-solid multiphase flows is proposed. In this model, a novel free energy for the gas-liquid-solid multiphase flows is established according…

Fluid Dynamics · Physics 2025-04-09 Chengjie Zhan , Xi Liu , Zhenhua Chai , Baochang Shi