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A simple non-local theoretical model is developed considering concentrated ionic surfactant solutions as regular ones. Their thermodynamics is described by the Cahn-Hilliard theory coupled with electrostatics. It is discovered that unstable…

Soft Condensed Matter · Physics 2012-01-19 R. Tsekov

Periodic supercell models of electric double layers formed at the interface between a charged surface and an electrolyte are subject to serious finite size errors and require certain adjustments in the treatment of the long-range…

Chemical Physics · Physics 2024-07-10 Thomas Sayer , Chao Zhang , Michiel Sprik

Polymeric ionic liquids are emerging polyelectrolyte materials for modern electrochemical applications. In this paper, we propose a self-consistent field theory of the polymeric ionic liquid on a charged conductive electrode. Taking into…

Soft Condensed Matter · Physics 2022-02-02 Yury A. Budkov , Nikolai N. Kalikin , Andrei L. Kolesnikov

Near-critical binary mixtures containing ions and confined between two charged and selective surfaces are studied within a Landau-Ginzburg theory extended to include electrostatic interactions. Charge density profiles and the effective…

Soft Condensed Matter · Physics 2012-02-28 Faezeh Pousaneh , Alina Ciach , Anna Maciolek

In this paper, we investigate the open tight-binding model with $N$ sites coupled to two reservoirs on its edges with the nonequilibrium Green function method to understand effects of open boundaries. As a result, we obtain an analytical…

Statistical Mechanics · Physics 2019-12-13 Takahisa Fukadai , Tomohiro Sasamoto

We study the Landau-Lifshitz system associated with Maxwell equations in a bilayered ferromagnetic body when super-exchange and surface anisotropy interactions are present in the spacer in-between the layers. In the presence of these…

Analysis of PDEs · Mathematics 2014-02-27 Gilles Carbou , Pierre Fabrie , Kévin Santugini-Repiquet

A simple Lennard-Jones fluid confined in a slit nanopore with hard walls is studied on the basis of a multilayer structured model. Each layer is homogeneous and parallel to the walls of the pore. The Helmholtz energy of this system is…

Mesoscale and Nanoscale Physics · Physics 2010-03-17 G. J. Zarragoicoechea , A. G. Meyra , V. A. Kuz

We develop a thermodynamic description of accumulation-layer heterostructures in which the induced sheet density is partitioned between the near-interface accumulation-layer charge and a complementary screening charge in the surrounding…

Mesoscale and Nanoscale Physics · Physics 2026-05-04 Elmar Böckenhoff

This paper is devoted to the asymptotic analysis of boundary layers in periodic homogenization. We investigate the behaviour of the boundary layer corrector, defined in the half-space $\Omega_{n,a}:=\{y\cdot n-a>0\}$, far away from the…

Analysis of PDEs · Mathematics 2012-05-08 Christophe Prange

This note concerns a nonlinear ill-posedness of the Prandtl equation and an invalidity of asymptotic boundary-layer expansions of incompressible fluid flows near a solid boundary. Our analysis is built upon recent remarkable linear…

Analysis of PDEs · Mathematics 2011-03-15 Yan Guo , Toan Nguyen

We revisit a classical problem of theoretical electrochemistry: the response of an electric double layer capacitor (EDLC) subject to a small, suddenly applied external potential. We solve the Debye-Falkenhagen equation to obtain exact…

Chemical Physics · Physics 2018-06-06 Mathijs Janssen , Markus Bier

We construct, by numerical means, static solutions of the spherically symmetric Einstein-Vlasov-Maxwell system and investigate various features of the solutions. This extends a previous investigation \cite{AR1} of the chargeless case. We…

General Relativity and Quantum Cosmology · Physics 2011-01-24 Hakan Andreasson , Mikael Eklund , Gerhard Rein

Ions in ionic liquids and concentrated electrolytes reside in a crowded, strongly-interacting environment, leading to the formation of discrete layers of charges at interfaces. Here, we propose a continuum theory that captures the…

We study in-gap electronic states induced by a nonmagnetic defect with short-range potential in two-dimensional topological insulators and trace their evolution as the distance between the defect and the boundary changes. The defect located…

Mesoscale and Nanoscale Physics · Physics 2015-02-13 Vladimir A. Sablikov , Aleksei A. Sukhanov

We consider asymptotic behavior of solutions to the oblique-Dirichlet mixed boundary conditions without the strict monotonicity of the equation in the variable corresponding to the unknown function for "thin domains" i.e. when the N+1…

Analysis of PDEs · Mathematics 2026-04-08 Isabeau Birindelli , Ariela Briani , Hitoshi Ishii

We investigate singularly perturbed elliptic problems with multiplicative nonlocal diffusion terms subject to Robin boundary conditions. The diffusion depends on a global quantity of the solution, which introduces a nonlocal coupling…

Analysis of PDEs · Mathematics 2026-04-08 Chiun-Chang Lee , Sang-Hyuck Moon , Wen Yang

Two overall neutral surfaces with positive and negative charged domains ("patches") have been shown in recent experiments to exhibit long-range attraction when immersed in an ionic solution. Motivated by the experiments, we calculate…

Soft Condensed Matter · Physics 2016-08-31 Ram M. Adar , David Andelman , Haim Diamant

Progress in electrochemical applications of ionic liquids builds on an understanding of electrical double-layer. This computational study focuses on structure-determined quantities -- maximum packing density, potentials and capacitances --…

We study the electro-diffusion properties of a domain containing a cusp-shaped structure in three dimensions when one ionic specie is dominant. The mathematical problem consists in solving the steady-state Poisson-Nernst-Planck (PNP)…

Neurons and Cognition · Quantitative Biology 2017-10-09 J. Cartailler , D. Holcman

Understanding how electrolyte-filled porous electrodes respond to an applied potential is important to many electrochemical technologies. Here, we consider a model supercapacitor of two blocking cylindrical pores on either side of a…

Soft Condensed Matter · Physics 2022-04-05 Jie Yang , Mathijs Janssen , Cheng Lian , René van Roij
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