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The methods which are actively used for electronic structure calculations of low-lying states of heavy- and superheavy-element compounds are briefly described. The advantages and disadvantages of calculations with the Dirac-Coulomb-Breit…

Chemical Physics · Physics 2009-11-07 A. V. Titov , N. S. Mosyagin , T. A. Isaev , A. N. Petrov

A self-consistent calculation scheme for correlated electron systems is created based on the density-functional theory (DFT). Our scheme is a multi-reference DFT (MR-DFT) calculation in which the electron charge density is reproduced by an…

Strongly Correlated Electrons · Physics 2009-11-13 Koichi Kusakabe , Naoshi Suzuki , Shusuke Yamanaka , Kizashi Yamaguchi

The description of realistic strongly correlated systems has recently advanced through the combination of density functional theory in the local density approximation (LDA) and dynamical mean field theory (DMFT). This LDA+DMFT method is…

Strongly Correlated Electrons · Physics 2009-11-13 B. Amadon , F. Lechermann , A. Georges , F. Jollet , T. O. Wehling , A. I. Lichtenstein

We analyze behavior of correlated electrons described by Hubbard-like models at intermediate and strong coupling. We show that with increasing interaction a pole in a generic two-particle Green function is approached. The pole signals…

Strongly Correlated Electrons · Physics 2009-10-30 V. Janis

New ways to treat electron correlation in electronic structure problems are discussed in the context of many-electron theory. The present work focuses primarily on static correlation. In related work, a method for including dynamical…

Chemical Physics · Physics 2018-09-05 Jerry L. Whitten

Correlated systems represent a class of materials that are difficult to describe through traditional electronic structure methods. The computational demand to simulate the structural dynamics of such systems, with correlation effects…

Strongly Correlated Electrons · Physics 2024-12-06 Rishi Rao , Li Zhu

Green's function methods within many-body perturbation theory provide a general framework for treating electronic correlations in excited states. Here we investigate the cumulant form of the one-electron Green's function based on the…

Chemical Physics · Physics 2021-04-23 F. D. Vila , J. J. Rehr , J. J. Kas , K. Kowalski , B. Peng

A new electronic structure model is developed in which the ground state energy of a molecular system is given by a Hartree-Fock-like expression with parametrized one- and two-electron integrals over an extended (minimal + polarization) set…

Chemical Physics · Physics 2014-02-11 Dimitri N. Laikov

We describe how to use quantum linear algebra to simulate a physically realistic model of disordered non-interacting electrons. The physics of disordered electrons outside of one dimension challenges classical computation due to the…

Quantum Physics · Physics 2025-04-25 Jielun Chen , Garnet Kin-Lic Chan

We consider electronic exchange and correlation effects in density-functional calculations of two-dimensional systems. Starting from wave function calculations of total energies and electron densities of inhomogeneous model systems, we…

Mesoscale and Nanoscale Physics · Physics 2012-05-30 Ilja Makkonen , Mikko M. Ervasti , Ville Kauppila , Ari Harju

We suggest to include the density of electron charge explicitly in the electron potential of density functional theory, rather than implicitly via exchange-correlation functionals. The advantages of the approach are conceptual and…

Materials Science · Physics 2007-05-23 Werner A. Hofer , Krisztian Palotas

A novel hybrid scheme is proposed. The {\it ab initio} LDA calculation is used to construct the Wannier functions and obtain single electron and Coulomb parameters of the multiband Hubbard-type model. In strong correlation regime the…

Strongly Correlated Electrons · Physics 2007-05-23 V. A. Gavrichkov , M. M. Korshunov , S. G. Ovchinnikov , I. A. Nekrasov , Z. V. Pchelkina , V. I. Anisimov

We have studied and resolved occupancy correlations in the existing average structure model of the complex metallic alloy xi'-Al-Pd-Mn [Boudard et al., Phil. Mag. A, 74, 939 (1996)], which has approximately 320 atoms in the unit cell and…

The half-Heusler alloy NiMnSb is one of the local-moment ferromagnets with unique properties for future applications. Band structure calculations predict exclusively majority bands at the Fermi level, thus indicating {100%} spin…

Strongly Correlated Electrons · Physics 2009-11-13 J Minár , J Braun , S Bornemann , H Ebert , M Donath

Electronic properties of heterostructures in which a finite number of Mott-insulator layers are sandwiched by semi-infinite metallic leads are investigated by using the dynamical-mean-field method combined with the Keldysh Green's function…

Strongly Correlated Electrons · Physics 2009-11-13 Satoshi Okamoto

We calculate the electronic and atomic structure of (MnO)n (n=1-4) using the HF exchange, VWN, PBE and B3LYP exchange-correlation functionals. We also perform diffusion Monte Carlo calculation to evaluate more accurate energies. We ompare…

Materials Science · Physics 2009-01-14 Hiori Kino , Lucas K. Wagner , Lubos Mitas

First-principles, density-functional based electronic structure calculations are carried out for MgC(Ni_{1-x}Co_{x})_{3} alloys over the concentration range 0\leq x\leq1, using Korringa-Kohn-Rostoker coherent-potential approximation (KKR…

Materials Science · Physics 2009-11-11 P. Jiji Thomas Joseph , Prabhakar P. Singh

We formulate a quantum embedding algorithm in real-space for the simultaneous theoretical treatment of nonlocal electronic correlations and disorder, the coherent cellular dynamical mean-field theory (C-CDMFT). This algorithm combines the…

Strongly Correlated Electrons · Physics 2026-01-09 Patrick Tscheppe , Marcel Klett , Henri Menke , Sabine Andergassen , Niklas Enderlein , Philipp Hansmann , Thomas Schäfer

I address here the question of the mutual interplay of strong correlations and disorder in the system. I consider random version of the Hubbard model. Diagonal randomness is introduced {\it via} random on-site energies and treated by the…

Disordered Systems and Neural Networks · Physics 2007-05-23 Karol I. Wysokinski

We present an ab-initio formalism for the calculation of transport properties in compositionally disordered systems within the framework of the Korringa-Kohn-Rostoker non-local coherent potential approximation. Our formalism is based upon…

Materials Science · Physics 2009-11-13 P. R. Tulip , J. B. Staunton , S. Lowitzer , D. Ködderitzsch , H. Ebert
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