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We demonstrate that a simple silver coated ball lens can be used to accurately measure the entire distribution of radiative transition rates of quantum dot nanocrystals. This simple and cost-effective implementation of Drexhage's method…

We perform a combined experimental and theoretical investigation of the orientational dynamics of rod-like colloidal particles in dilute suspension as they are subjected to a time-dependent homogeneous planar elongational flow. Our…

Colloidal semiconductor quantum dots (QDs) are excellent luminescent nanomaterials for a broad range of optoelectronic applications. Their photoluminescence blinking, however, hinders their practical use in many aspects. It has been shown…

Optics · Physics 2024-02-27 Zhiyuan Wang , Jianwei Tang , Jiahao Han , Juan Xia , Tianzi Ma , Xue-Wen Chen

Recent transient absorption experiments on CdS nanorods suggest that photoexcited holes rapidly trap to the surface of these particles and then undergo diffusion along the rod surface. In this paper, we present a semiperiodic DFT model for…

Chemical Physics · Physics 2022-06-30 R. Peyton Cline , James K. Utterback , Steven E. Strong , Gordana Dukovic , Joel D. Eaves

Colloidal nanocrystals are unique optical gain materials due to their high intrinsic absorption, excellent quantum yield, and tunable emission. However, integration of colloidal nanocrystal solutions into photonic systems for lasing…

The exciton states of strained CdTe/CdS core-shell tetrapod-shaped nanocrystals were theoretically investigated by the numerical diagonalization of a configuration interaction Hamiltonian based on the single-band effective mass…

Mesoscale and Nanoscale Physics · Physics 2015-06-23 Yuanzhao Yao , Takashi Kuroda , Dmitry N. Dirin , Maria S. Sokolikova , Roman B. Vasiliev

Photo-luminescence intermittency (blinking) in semiconductor nanocrystals (NCs), a phenomenon ubiquitous to single-emitters, is generally considered to be temporally random intensity fluctuations between bright (On) and dark (Off) states.…

Mesoscale and Nanoscale Physics · Physics 2020-01-29 Amitrajit Mukherjee , Korak Kumar Ray , Chinmay Phadnis , Arunasish Layek , Soumya Bera , Arindam Chowdhury

Binary compositions of surface ligands are known to improve the colloidal stability and fluorescence quantum yield of nanocrystals (NCs), due to ligand-ligand interactions and surface organization. Herein, we follow the thermodynamics of a…

Soft Condensed Matter · Physics 2023-06-16 Orian Elimelech , Meirav Oded , Daniel Harries , Uri Banin

Diffusion of tracer dye molecules in water confined to nanoscale is an important subject with a direct bearing on many technological applications. It is not yet clear however, if the dynamics of water in hydrophilic as well as hydrophobic…

Soft Condensed Matter · Physics 2022-01-19 Shivprasad Patil , V. J. Ajith

Semiconductor nanocrystals are a promising class of materials for a variety of novel optoelectronic devices, since many of their properties, such as the electronic gap and conductivity, can be controlled. Much of this control is achieved…

Chemical Physics · Physics 2017-06-06 Nadav Geva , James J. Shepherd , Lea Nienhaus , Moungi G. Bawendi , Troy Van Voorhis

Zinc-blende CdSe semiconducting nanoplatelets (NPL) show outstanding quantum confinement properties thanks to their small, atomically-controlled, thickness. For example, they display extremely sharp absorption peaks that make them very…

Applied Physics · Physics 2019-12-09 Ivan Dozov , Claire Goldmann , Patrick Davidson , Benjamin Abécassis

A complex InAs/CdSe/ZnSe Core/Shell1/Shell2 (CSS) structure is synthesized, where the intermediate CdSe buffer layer decreases strain between the InAs core and the ZnSe outer shell. This structure leads to significantly improved…

Applied Physics · Physics 2021-05-25 Assaf Aharoni , Taleb Mokari , Inna Popov , Uri Banin

The vibrational spectroscopy of semiconductor nanostructures can provide important information on their structure. In this work, experimental Raman and infrared spectra are compared with vibrational spectra of CdSe/CdS core/shell…

Using a combination of continuous wave and time-resolved spectroscopy, we study the effects of interfacial conditions on the radiative lifetimes and photoluminescence intensities of colloidal CdTe/CdS quantum dots (QDs) embedded in a…

Mesoscale and Nanoscale Physics · Physics 2015-08-25 Girija Gaur , Dmitry S. Koktysh , Daniel M. Fleetwood , Robert A. Weller , Robert A. Reed , Sharon M. Weiss

The yet virtually unexplored class of soft colloidal rods with small aspect ratio is investigated and shown to exhibit a very rich phase and dynamic behavior, spanning from liquid to nearly melt state. Instead of nematic order, these short…

We report the observation of power law dynamics on nanosecond to microsecond time scales in the fluorescence decay from semiconductor nanocrystals, and draw a comparison between this behavior and power-law fluorescence blinking from single…

Other Condensed Matter · Physics 2008-01-27 P. H. Sher , J. M. Smith , P. A. Dalgarno , R. J. Warburton , X. Chen , P. J. Dobson , S. M. Daniels , N. L. Pickett , P. O'Brien

The quest for an integrated light source that promises high energy efficiency and fast modulation for high-performance photonic circuits has led to the development of room-temperature telecom-wavelength nanoscale laser with high spontaneous…

Unique optical properties of colloidal semiconductor quantum dots (QDs), arising from quantum mechanical confinement of charge within these structures, present a versatile testbed for the study of how high electric fields affect the…

Transport properties of artificial solids composed of colloidal CdSe nanocrystals (NCs) are studied from 6 K to 250 K, before and after annealing. Annealing results in greatly enhanced dark and photocurrent in NC solids, while transmission…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 M. Drndic , M. Vitasovic , N. Y. Morgan , M. A. Kastner , M. G. Bawendi

Quantum dots play a promising role in the development of novel optical and biosensing devices. In this study, we investigated steady-state and time-dependent luminescence properties of InGaP/ZnS core/shell colloidal quantum dots in a…

Materials Science · Physics 2012-07-30 Subhasish Chatterjee , Nikesh V. Valappil , Vinod M. Menon