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Hydrogels are soft materials engineered to suit a multitude of applications that exploit their tunable mechanochemical properties. Dynamic hydrogels employing noncovalent, physically crosslinked networks dominated by either enthalpic or…

Soft Condensed Matter · Physics 2023-11-28 Samya Sen , Anthony C. Yu , Changxin Dong , Andrea I. D'Aquino , Eric A. Appel

In experimental systems, colloidal particles are virtually always at least somewhat polydisperse, which can have profound effects on their ability to crystallize. Unfortunately, accurately predicting the effects of polydispersity on phase…

Soft Condensed Matter · Physics 2025-10-09 Antoine Castagnède , Laura Filion , Frank Smallenburg

The lack of a procedure to determine equilibrium thermodynamic properties of a small system interacting with a bath is frequently seen as a weakness of conventional statistical mechanics. A typical example for such a small system is a…

Chemical Physics · Physics 2022-12-16 Mohammad Rahbar , Christopher J. Stein

Turbulent mixing layers (TMLs) are ubiquitous in multiphase gas. They can potentially explain observations of high ions such as O VI, which have significant observed column densities despite short cooling times. Previously, we showed that…

Astrophysics of Galaxies · Physics 2021-09-01 Brent Tan , S. Peng Oh

Thin elastic solids are easily deformed into a myriad of three-dimensional shapes, which may contain sharp localized structures as in a crumpled candy wrapper, or have smooth and diffuse features like the undulating edge of a flower.…

We developed a new physical model to predict macroscopic properties of inorganic molten systems using a realistic description of inter-atomic interactions. Unlike the conventional approach, which tends to overestimate viscosity by several…

Materials Science · Physics 2015-06-04 Vitaly V. Chaban , Yuriy V. Pereverzev , Oleg V. Prezhdo

Soft nanoparticles hold promise as smart emulsifiers due to their high degree of deformability, permeability and stimuli responsive properties. By means of large-scale simulations we investigate the structural properties of nanogels at…

Soft Condensed Matter · Physics 2019-11-18 Daniel J. Arismendi-Arrieta , Angel J. Moreno

Reconnection physics at micro-scales is investigated in an electron magnetohydrodynamics frame. A new process of collapse of the neutral current sheet is demonstrated by means of analytical and numerical solutions. It shows how at scales…

Plasma Physics · Physics 2017-12-01 I F Shaikhislamov

The essential features of the in vitro refolding of myoglobin are expressed in a solvable physical model. Alpha helices are taken as the fundamental collective coordinates of the system, while the refolding is assumed to be mainly driven by…

Condensed Matter · Physics 2007-05-23 David J. E. Callaway

The thermodynamics and dynamics of supercooled liquids correlate with their elasticity. In particular for covalent networks, the jump of specific heat is small and the liquid is {\it strong} near the threshold valence where the network…

Disordered Systems and Neural Networks · Physics 2015-09-02 Le Yan , Matthieu Wyart

In this work, we study the nature of transitions between inherent structures of a two-dimensional model supercooled liquid. We demonstrate that these transitions occur predominately along a small number of directions on the energy…

Statistical Mechanics · Physics 2013-03-12 Glen M. Hocky , David R. Reichman

It is well-known that the architecture of macromolecules plays an important role in the hydrodynamics and viscosity of its semi-diluted solutions. However, the systematic study of the rheology of macromolecules with complex topology, such…

An analytical description of polymer melts and their mixtures as liquids of interacting soft colloidal particles is obtained from liquid-state theory. The derived center-of-mass pair correlation functions with no adjustable parameters…

Soft Condensed Matter · Physics 2009-11-10 G. Yatsenko , E. J. Sambriski , M. A. Nemirovskaya , M. Guenza

We study the structure and dynamics of a transient network composed of droplets of microemulsion connected by telechelic polymers. The polymer induces a bridging attraction between droplets without changing their shape. A viscoelastic…

Soft Condensed Matter · Physics 2009-10-31 F. Molino , J. Appell , M. Filali , E. Michel , G. Porte , S. Mora , E. Sunyer

{It has recently been proposed that giant molecular complexes form at the sites where streams of diffuse warm atomic gas collide at transonic velocities.} {We study the global statistics of molecular clouds formed by large scale colliding…

Astrophysics · Physics 2009-11-13 P. Hennebelle , R. Banerjee , E. Vazquez-Semadeni , R. Klessen , E. Audit

Encapsulation of chemicals using polymer membranes enables to control their transport and delivery for applications such as agrochemistry or detergency. To rationalize the design of polymer capsules, it is necessary to understand how the…

Soft Condensed Matter · Physics 2018-12-18 Corentin Tregouët , Thomas Salez , Mathilde Reyssat , Cécile Monteux

In this work a new density functional theory framework is developed to predict the salt-concentration dependent swelling state of charged microgels and the local concentration of monovalent ions inside and outside the microgel. For this…

Soft Condensed Matter · Physics 2017-06-28 Arturo Moncho-Jordá , Joachim Dzubiella

The normal modes and relaxation rates of weak colloidal gels are investigated in computations employing different models of the hydrodynamic interactions between colloids. The eigenspectrum is computed for freely draining,…

Fluid Dynamics · Physics 2018-01-17 Zsigmond Varga , James W. Swan

Colloidal gels constitute an important class of materials found in many contexts and with a wide range of applications. Yet as matter far from equilibrium, gels exhibit a variety of time-dependent behaviours, which can be perplexing, such…

Soft Condensed Matter · Physics 2021-09-22 C. Patrick Royall , Malcolm A. Faers , Sian L. Fussell , James E. Hallett

We study the formation of a colloidal gel by means of Molecular Dynamics simulations of a model for colloidal suspensions. A slowing down with gel-like features is observed at low temperatures and low volume fractions, due to the formation…

Soft Condensed Matter · Physics 2009-11-13 A. Fierro , E. Del Gado , A. de Candia , A. Coniglio