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The probability distribution of the entropy production for the effusion of an ideal gas between two compartments is calculated explicitly. The fluctuation theorem is verified. The analytic results are in good agreement with numerical data…

Statistical Mechanics · Physics 2007-05-23 B. Cleuren , C. Van den Broeck , R. Kawai

If a system is at thermodynamic equilibrium, an observer cannot tell whether a film of it is being played forward or in reverse: any transition will occur with the same frequency in the forward as in the reverse direction. However, if…

Statistical Mechanics · Physics 2020-07-01 John W. Biddle , Jeremy Gunawardena

The statistical mechanical basis of the fluctuation theory of mixtures is reviewed. An overview of the statistical mechanical relations between the microscopic properties of a system and its macroscopic properties is presented. The…

Statistical Mechanics · Physics 2018-11-20 G. Ali Mansoori , Enrico Matteoli

Constraint tightening to non-conservatively guarantee recursive feasibility and stability in Stochastic Model Predictive Control is addressed. Stability and feasibility requirements are considered separately, highlighting the difference…

Systems and Control · Computer Science 2016-05-13 Matthias Lorenzen , Fabrizio Dabbene , Roberto Tempo , Frank Allgöwer

In this note we discuss a paradigmatic example of interacting particles subject to non conservative external forces and to the action of thermostats consisting of external (finite) reservoirs of particles. We then consider a model of…

Statistical Mechanics · Physics 2009-11-11 F. Bonetto , G. Gallavotti , A. Giuliani , F. Zamponi

A unified thermodynamic formalism describing the efficiency of learning is proposed. First, we derive an inequality, which is more strength than Clausius's inequality, revealing the lower bound of the entropy-production rate of a subsystem.…

Statistical Mechanics · Physics 2025-04-15 Shanhe Su , Ousi Pan , Shihao Xia , Jincan Chen , Chikako Uchiyama

Living systems at the molecular scale are composed of many constituents with strong and heterogeneous interactions, operating far from equilibrium, and subject to strong fluctuations. These conditions pose significant challenges to…

Statistical Mechanics · Physics 2023-04-11 Emma Lathouwers , Joseph N. E. Lucero , David A. Sivak

Traditionally, it is understood that fluctuations in the equilibrium distribution are not evident in thermodynamic systems of large $N$ (the number of particles in the system) \cite{Huang1}. In this paper we examine the validity of this…

Mathematical Physics · Physics 2007-10-03 Kieran Kelly , Przemysław Repetowicz , Seosamh macRéamoinn

Heat fluctuations of a harmonic oscillator in contact with a thermostat and driven out of equilibrium by an external deterministic force are studied experimentally and theoretically within the context of Fluctuation Theorems. We consider…

Statistical Mechanics · Physics 2007-05-23 Sylvain Joubaud , Nicolas B. Garnier , Sergio Ciliberto

According to the second law, the efficiency of cyclic heat engines is limited by the Carnot bound that is attained by engines that operate between two thermal baths under the reversibility condition whereby the total entropy does not…

Quantum Physics · Physics 2018-01-12 Wolfgang Niedenzu , Victor Mukherjee , Arnab Ghosh , Abraham G. Kofman , Gershon Kurizki

A new universality in optimization of trade-off between power and efficiency for low-dissipation Carnot cycles is presented. It is shown that any trade-off measure expressible in terms of efficiency and the ratio of power to its maximum…

Statistical Mechanics · Physics 2016-05-05 Viktor Holubec , Artem Ryabov

We study local power fluctuations in numerical simulations of stationary, homogeneous, isotropic turbulence in two and three dimensions with Gaussian forcing. Due to the near-Gaussianity of the one-point velocity distribution, the…

Statistical Mechanics · Physics 2009-11-13 M. M. Bandi , Sergei G. Chumakov , Colm Connaughton

We consider the quality factor Q, which quantifies the trade-off between power, efficiency, and fluctuations in steady-state heat engines modeled by dynamical systems. We show that the nonlinear scattering theory, both in classical and…

Statistical Mechanics · Physics 2020-10-28 Giuliano Benenti , Giulio Casati , Jiao Wang

Single-molecule experiments have found near-perfect thermodynamic efficiency in the rotary motor F1-ATP synthase. To help elucidate the principles underlying nonequilibrium energetic efficiency in such stochastic machines, we investigate…

Statistical Mechanics · Physics 2019-09-05 Joseph N. E. Lucero , Aliakbar Mehdizadeh , David A. Sivak

Optimisation of heat engines at the micro-scale has applications in biological and artificial nano-technology, and stimulates theoretical research in non-equilibrium statistical physics. Here we consider non-interacting overdamped particles…

Soft Condensed Matter · Physics 2021-06-02 Giulia Gronchi , Andrea Puglisi

We analytically derive universal bounds that describe the trade-off between thermodynamic cost and precision in a sequence of events related to some internal changes of an otherwise hidden physical system. The precision is quantified by the…

Statistical Mechanics · Physics 2024-06-18 Patrick Pietzonka , Francesco Coghi

Thermodynamic parameters such as temperature and pressure can be defined from the statistical behavior of a system. Therefore, thermal fluctuation is an inseparable characteristic of these parameters which eventually finds its way into…

Computational Physics · Physics 2017-02-28 Alek Bedroya , Mahmud Bahmanabadi

Fluctuations of observables as functions of time, or "fluctuation patterns", are studied in a chaotic microscopically reversible system that has irreversibly reached a nonequilibrium stationary state. Supposing that during a certain, long…

chao-dyn · Physics 2008-10-08 G. Gallavotti

Randomly coupled Ising spins constitute the classical model of collective phenomena in disordered systems, with applications covering ferromagnetism, combinatorial optimization, protein folding, stock market dynamics, and social dynamics.…

Disordered Systems and Neural Networks · Physics 2016-08-24 David Dahmen , Hannah Bos , Moritz Helias

We generalize the link between fluctuation theorems and thermodynamic uncertainty relations by deriving a bound on the variance of fluxes that satisfy an isometric fluctuation theorem. The resulting bound, which depends on the system's…

Statistical Mechanics · Physics 2020-02-11 Hadrien Vroylandt , Karel Proesmans , Todd R. Gingrich