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In recent papers, several authors have claimed that a definition of the thermodynamic entropy in terms of the logarithm of a volume in phase space, originally suggested by Gibbs, is the only valid definition. Arguing from the Gibbs entropy,…

Statistical Mechanics · Physics 2015-08-26 Robert H. Swendsen , Jian-Sheng Wang

Landauer's erasure principle exposes an intrinsic relation between thermodynamics and information theory: the erasure of information stored in a system, S, requires an amount of work proportional to the entropy of that system. This entropy,…

Quantum Physics · Physics 2011-06-28 Lídia del Rio , Johan Aberg , Renato Renner , Oscar Dahlsten , Vlatko Vedral

Several recent results on thermodynamics have been obtained using the tools of quantum information theory and resource theories. So far, the resource theories utilised to describe thermodynamics have assumed the existence of an infinite…

Quantum Physics · Physics 2017-11-16 Carlo Sparaciari , Jonathan Oppenheim , Tobias Fritz

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

We investigate the validity of the generalized second law of thermodynamics, in the cosmological scenario where dark energy interacts with both dark matter and radiation. Calculating separately the entropy variation for each fluid component…

High Energy Physics - Theory · Physics 2010-07-20 Mubasher Jamil , Emmanuel N. Saridakis , M. R. Setare

The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…

Statistical Mechanics · Physics 2023-09-01 A. Paglietti

The Kelvin-Planck statement of the Second Law of Thermodynamics is a stricture on the nature of heat receipt by any body suffering a cyclic process. It makes no mention of temperature or of entropy. Beginning with a Kelvin-Planck statement…

Mathematical Physics · Physics 2023-08-28 Martin Feinberg , Richard B. Lavine

It is shown that the proof of [1] that the specific heat of the system of classical point particles interacting with each other via uniform gravitational potential energy may be negative is incorrect.

General Physics · Physics 2017-05-03 Ikhtier H. Umirzakov

It is shown that the violation of the positiveness of the entropy due to the Casimir-Lifshitz interaction claimed in several papers is an artifact related to an improper interpretation of the "Casimir entropy", which actually is a…

Statistical Mechanics · Physics 2015-05-20 Lev P. Pitaevskii

The Carnot statement of the second law of thermodynamics poses an upper limit on the efficiency of all heat engines. Recently, it has been studied whether generic quantum features such as coherence and quantum entanglement could allow for…

Statistical Mechanics · Physics 2015-10-14 Bartłomiej Gardas , Sebastian Deffner

This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

Theory and experiment have long discussed negative thermodynamic pressure states, but their microscopic origins are unclear. I address this problem within the framework of quantum thermodynamics. I show that the pressure exerted on the…

Quantum Physics · Physics 2025-04-24 Varazdat Stepanyan

The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

Statistical Mechanics · Physics 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

Despite well over a century of effort, the proper expression for the classical entropy in statistical mechanics remains a subject of debate. The Boltzmann entropy (calculated from a surface in phase space) has been criticized as not being…

Statistical Mechanics · Physics 2017-09-12 Robert H. Swendsen

Recently, exotic black holes whose masses and angular momenta are interchanged have been found, and it is known that their entropies depend only on the $inner$ horizon areas. But a basic problem of these entropies is that the second law of…

High Energy Physics - Theory · Physics 2008-11-26 Mu-In Park

The generalized zeroth law of thermodynamics indicates that the physical temperature in nonextensive statistical mechanics is different from the inverse of the Lagrange multiplier, beta. This leads to modifications of some of thermodynamic…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , S. Martinez , F. Pennini , A. Plastino

We extend on ideas from standard thermodynamics to show that temperature can be assigned to a general nonequilibrium quantum system. By choosing a physically motivated complete set of observables and expanding the system state thereupon,…

Quantum Physics · Physics 2021-05-26 S. Alipour , F. Benatti , M. Afsary , F. Bakhshinezhad , M. Ramezani , T. Ala-Nissila , A. T. Rezakhani

In systems described by the scattering theory, there is an upper bound, lower than Carnot, on the efficiency of steady-state heat to work conversion at a given output power. We show that interacting systems can overcome such bound and…

Statistical Mechanics · Physics 2018-08-27 Rongxiang Luo , Giuliano Benenti , Giulio Casati , Jiao Wang

The second Tisza-Callen postulate of equilibrium thermodynamics states that for any system exists a function of the system's extensive parameters, called entropy, defined for all equilibrium states and having the property that the values…

Statistical Mechanics · Physics 2016-03-23 Dragos-Victor Anghel

In effective field theory, the positivity bounds of higher derivative operators are derived from analyticity, causality, and unitarity. We show that the positivity bounds on some operators of the effective field theory, e.g.,…

High Energy Physics - Theory · Physics 2023-08-02 Qing-Hong Cao , Daiki Ueda
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