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We have investigated electronic structures of La$_3$S$_4$ and Ce$_3$S$_4$ using the LSDA and LSDA+$U$ methods. Calculated density of states (DOS) are compared with the experimental DOS obtained by the valence band photoemission…

Materials Science · Physics 2009-11-07 J. H. Shim , Kyoo Kim , B. I. Min , J. -S. Kang

We present the results of self-consistent calculations of the electronic shell and supershell structure for clusters having up to 6000 valence electrons. The ionic background is described in terms of a homogeneous jellium. The calculations…

Condensed Matter · Physics 2009-10-28 Erik Koch , Olle Gunnarsson

Elements of group I in the Periodic table have valence electrons of s-type and are usually considered as simple metals. Crystal structures of these elements at ambient pressure are close-packed and high-symmetry of bcc and fcc types,…

Materials Science · Physics 2017-03-14 V F Degtyareva

A heavy-fermion paramagnet UTe$_2$ has been a strong candidate for a spin-triplet superconductor. Experiments on UTe$_2$ under pressure have been vigorously conducted, and rich phase diagrams have been suggested. Multiple superconducting…

Strongly Correlated Electrons · Physics 2025-12-01 Makoto Shimizu , Youichi Yanase

The results of electronic structure calculations for a variety of palladium hydrides are presented. The calculations are based on density functional theory and used different local and semilocal approximations. The thermodynamic stability…

Materials Science · Physics 2014-11-07 Abdesalem Houari , Samir F. Matar , Volker Eyert

The electronic energy structures and magnetic properties of layered superconductors $R$Ni$_2$B$_2$C, $R$Fe$_4$Al$_8$ and FeSe are systematically studied, by using the density functional theory (DFT). The calculations allowed us to reveal a…

Superconductivity · Physics 2014-04-04 G. E. Grechnev , A. V. Logosha , A. A. Lyogenkaya , A. G. Grechnev , A. V. Fedorchenko

Recent high-pressure x-ray diffraction studies of alkali metals revealed unusual complex structures that follow the body-centered and face-centered cubic structures on compression. The structural sequence of potassium under compression to 1…

Materials Science · Physics 2013-10-18 V F Degtyareva , O Degtyareva

We present a theoretical model of the "isostructural" \gamma-\alpha phase transition in Ce which is based on quadrupolar interactions due to coupled charge density fluctuations of 4f electrons and of conduction electrons. Conduction…

Strongly Correlated Electrons · Physics 2009-10-31 A. V. Nikolaev , K. H. Michel

The electronic structure of $\sigma$-phase Fe$_{100-x}$V$_x$ compounds with 33.3 $\le x \le 60.0$ was calculated from the charge self-consistent Korringa-Kohn-Rostoker method. For the first time, charge densities $\rho_A(0)$ and electric…

Materials Science · Physics 2015-05-14 J. Cieslak , J. Tobola , S. M. Dubiel

We have investigated the low-energy electronic structure of the heavy fermion superconductor CeCoIn5 by angle-resolved photoemission and band structure calculations. We measured the Fermi surface and energy distribution maps along the…

We investigate the electronic structure of BaIrO3, an interesting compound exhibiting charge density wave transition in its insulating phase and ferromagnetic transition at the same temperature, using full potential linearized augmented…

Strongly Correlated Electrons · Physics 2009-11-11 Kalobaran Maiti

We present an extensive study of structure, composition, electronic and magnetic properties of Ce--Pt surface intermetallic phases on Pt(111) as a function of their thickness. The sequence of structural phases appearing in low energy…

Strongly Correlated Electrons · Physics 2015-07-21 C. Praetorius , M. Zinner , A. Köhl , H. Kießling , S. Brück , B. Muenzing , M. Kamp , T. Kachel , F. Choueikani , P. Ohresser , F. Wilhelm , A. Rogalev , K. Fauth

We study the electronic structure of a Pauli paramagnetic compound, La(2)CoSi(3) using photoemission spectroscopy and ab initio band structure calculations. Experimental valence band spectra exhibit signature of electron correlation induced…

Strongly Correlated Electrons · Physics 2014-11-05 Swapnil Patil , Garima Saraswat , Ganesh Adhikary , R. Bindu , E. V. Sampathkumaran , Kalobaran Maiti

Within the framework of the density functional theory, we calculate the electronic structure of $\alpha$-(BEDT-TTF)$_2$I$_3$ at 8K and room temperature at ambient pressure and with uniaxial strain along the $a$- and $b$-axes. We confirm the…

Strongly Correlated Electrons · Physics 2009-11-11 Hiori Kino , Tsuyoshi Miyazaki

The interaction between localized f and itinerant conduction electrons is crucial in the electronic properties of heavy fermion and valence fluctuating compounds. Using high-resolution angle-resolved photoemission spectroscopy, we…

Lanthanide 4f electrons are strongly influenced by spin-orbit coupling, resulting in well-defined J multiplets, which are further split by the crystalline electric field in condensed matter. While the anisotropy of 4f electrons is closely…

CeCu$_2$Si$_2$ is an exemplary correlated electron metal that features two domes of unconventional superconductivity in its temperature-pressure phase diagram. The first dome surrounds an antiferromagnetic quantum critical point, whereas…

Strongly Correlated Electrons · Physics 2017-08-23 Y. Lai , S. M. Saunders , D. Graf , A. Gallagher , K. -W. Chen , F. Kametani , T. Besara , T. Siegrist , A. Shekhter , R. E. Baumbach

The electronic structure and chemical bonding of Beta-Ta synthesized as a thin 001-oriented film (space group P421m) is investigated by 4f core level and valence band X-ray photoelectron spectroscopy and compared to alfa-Ta bulk. For the…

Materials Science · Physics 2018-11-27 Martin Magnuson , Grzegorz Greczynski , Fredrik Eriksson , Lars Hultman , Hans Högberg

The electronic structure of the single molecule magnet system M[Fe(L)2]3*4CHCl3 (M=Fe,Cr; L=CH3N(CH2CH2O)2) has been studied using X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, soft X-ray emission spectroscopy, and…

Rare-earth compounds RCoSi exhibit unique properties, with distinct structural behaviors depending on whether R is a light, middle or heavy rare-earth element. Among them, CeCoSi undergoes a structural phase transition under high pressure,…

Strongly Correlated Electrons · Physics 2025-03-18 Shuai-Kang Zhang , Yuanji Xu , Guojun Li , Junshuai Wang , Zhongpo Zhou , Yipeng An
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