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In this review, latest updates in the poly (ethylene oxide) based electrolytes are summarized. The ultimate goal of researchers globally is towards the development of free standing solid polymeric separator for energy storage devices. This…

Applied Physics · Physics 2018-08-14 Anil Arya , A L Sharma

Management of heat during charging and discharging of Li-ion batteries is critical for their safety, reliability, and performance. Understanding the thermal conductivity of the materials comprising batteries is crucial for controlling the…

Materials Science · Physics 2021-03-17 Zhe Cheng , Beniamin Zahiri , Xiaoyang Ji , Chen Chen , Darshan Chalise , Paul V. Braun , David G. Cahill

Solid-state batteries (SSB) are emerging as next-generation electrochemical energy storage devices. Achieving high energy density in SSB relies on solid polymer electrolytes (SPE) that are electrochemically stable against both lithium metal…

Soft Condensed Matter · Physics 2026-01-07 Amaury Coste , Thomas Meyer , Claire Villevielle , Fannie Alloin , Stefano Mossa , Benoit Coasne

Polymer electrolytes (PEs) are promising candidates for use in next-generation high-voltage batteries, as they possess advantageous elastic and electrochemical properties. However, PEs still suffer from low ionic conductivity and need to be…

The solid-state electrolyte is critical for achieving next-generation high energy density and high-safety batteries. Solid polymer electrolytes (SPEs) possess great potential for commercial application owing to their compatibility with the…

Materials Science · Physics 2023-07-04 Xiong Xiong Liu , Shengfa Feng , Pengcheng Yuan , Yaping Wang , Long Pan , ZhengMing Sun

As one of the most promising next-generation energy storage device, lithium metal batteries have been extensively investigated. However, the poor safety issue and undesired lithium dendrites growth hinder the development of lithium metal…

Blend solid polymer electrolyte based on PEO, PVP complexed with lithium LiBOB were synthesized by solution cast technique and impact of LiBOB on the morphology, structure, and electrochemical properties is examined. The XRD and FESEM…

Materials Science · Physics 2018-07-05 Anil Arya , Mohd Sadiq , A. L. Sharma

We present the results from an extensive atomistic molecular dynamics simulation study of poly(ethylene oxide) (PEO) doped with various amounts of lithium-bis(trifluoromethane)sulfonimide (LiTFSI) salt under the influence of external…

Soft Condensed Matter · Physics 2021-03-10 Alina Wettstein , Diddo Diddens , Andreas Heuer

We analyze, through molecular dynamics simulations, the temperature dependence of the thermal conductivity (k) of chain-oriented amorphous polyethylene (PE). We find that at increasing levels of orientation, the temperature corresponding to…

Materials Science · Physics 2019-08-14 Rajmohan Muthaiah , Jivtesh Garg

We present an extensive molecular dynamics (MD) simulation study of poly(ethylene oxide) (PEO) based densely cross-linked polymers, focussing on structural properties as well as the systems dynamics in the presence of lithium salt.…

Soft Condensed Matter · Physics 2022-11-15 Mirko Fischer , Andreas Heuer , Diddo Diddens

Enhancing the ion conduction in solid electrolytes is critically important for the development of high-performance all-solid-state lithium-ion batteries (LIBs). Lithium thiophosphates are among the most promising solid electrolytes, as they…

Materials Science · Physics 2024-01-11 Zhimin Chen , Tao Du , N. M. Anoop Krishnan , Yuanzheng Yue , Morten M. Smedskjaer

Amorphous polymers are known as thermal insulators, increasing their thermal conductivities have not been guided by fully understood physics. In this work, we use molecular dynamics simulations to study the thermal transport mechanism of…

Soft Condensed Matter · Physics 2019-04-03 Xingfei Wei , Tengfei Luo

Electrolytes as nanostructured materials are very attractive for batteries or other types of electronic devices. (PEO)8ZnCl2 polymer electrolytes and nanocomposites (PEO)8ZnCl2/TiO2 were prepared from PEO and ZnCl2 and with addition of TiO2…

Materials Science · Physics 2008-09-04 Aleksandra Turkovic , Mario Rakic , Pavo Dubcek , Magdy Lucic-Lavcevic , Sigrid Bernstorff

Lithium-ion batteries employing solid-state electrolytes (SSEs) are emerging as a safer and more compact alternative to conventional batteries using liquid electrolytes, especially for miniaturized energy storage systems. However, the…

Solid polymer electrolytes (SPE) have the potential to increase both the energy density and stability of lithium-based batteries, but low Li-ion conductivity remains a barrier to technological viability. SPEs are designed to maximize Li-ion…

Chemical Physics · Physics 2017-01-24 Brett M. Savoie , Michael A. Webb , Thomas F. Miller

In order to replace the conventional liquid electrolytes by solid electrolytes, high room temperature ionic conductivity is required. To achieve such high ionic conductivity, the series Li7-3xGaxLa3Zr1.9Ge0.1O12 was prepared by solid-state…

Materials Science · Physics 2024-05-09 Muktai Aote , A. V. Deshpande , Anuj Khapekar , Kajal Parchake

Solid-state electrolyte batteries are expected to replace liquid electrolyte lithium-ion batteries in the near future thanks to their higher theoretical energy density and improved safety. However, their adoption is currently hindered by…

Polymer electrolytes incorporating Li$_{10}$GeP$_{2}$S$_{12}$ (LGPS) nanoparticles show promise for solid-state lithium batteries owing to their enhanced ionic conductivity, though the governing mechanisms remain unclear. We combine…

The vast amount of computational studies on electrical conduction in solid-state electrolytes is not mirrored by comparable efforts addressing thermal conduction, which has been scarcely investigated despite its relevance to thermal…

Materials Science · Physics 2024-06-18 Davide Tisi , Federico Grasselli , Lorenzo Gigli , Michele Ceriotti

A systematic study was performed to measure the effective thermal conductivity of ceramic particle beds, a promising heat transfer and thermal energy storage media for concentrating solar power (CSP). The thermal conductivity of the ceramic…

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