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The dispersal of high dielectric constant ferroelectric ceramic material Ba(0.7)Sr(0.3)TiO(3) (Tc~30 C) and Ba(0.88)Sr(0.12)TiO(3) (Tc~90 C) in an ion conducting polymer electrolyte (PEO:NH4I) is reported to result in an increase in the…

Chemical Physics · Physics 2009-11-10 Pramod Kumar Singh , Amreesh Chandra

We use molecular dynamics simulations of the primitive model of electrolytes to study the ionic structure in aqueous monovalent electrolyte solutions confined by charged planar interfaces over a wide range of electrolyte concentration,…

Soft Condensed Matter · Physics 2020-09-08 Nasim Anousheh , Francisco J. Solis , Vikram Jadhao

Nano-graphene /polymer composites can functionas pressure induced electro-switches, at concentrations around their conductivity percolation threshold. Close to the critical point, the pressure dependence of the electron tunneling through…

Materials Science · Physics 2021-03-30 E. Kolonelou , E. Loupou , P. Klonos , A. E. Sakellis , D. Valadorou , A. Kyritsis , A. N. Papathanassiou

Electronic and dielectric properties of vapor-phase grown MoS_{2} have been investigated in metal/MoS_{2}/silicon capacitor structures by capacitance-voltage and conductancevoltage techniques. Analytical methods confirm the MoS_{2} layered…

Materials Science · Physics 2019-07-19 M. Belete , S. Kataria , U. Koch , M. Kruth , C. Engelhard , J. Mayer , O. Engström , M. C. Lemme

Dielectric spectroscopy measurements over a broad range of temperature and pressure were carried out on poly(oxybutylene) (POB), a type-A polymer (dielectrically-active normal mode). There are three dynamic processes appearing at lower…

Soft Condensed Matter · Physics 2009-11-10 R. Casalini , C. M. Roland

The properties of suspensions of fine particles in dielectric liquid (electrorheological fluids) subjected to an electric field lead to a drastic change of the apparent viscosity of the fluid. For high applied fields (~ 3-5 kV/mm) the…

Chemical Physics · Physics 2007-05-23 Quentin Guegan , J. -N. Foulc , F. Ayela , O. Tillement

Dielectric capacitors are critical components in electronics and energy storage devices. The polymer based dielectric capacitors have advantages of flexibility, fast charge and discharge, low loss, and graceful failure. Elevating the use of…

The rheology of coextruded layered films of polystyrene/poly(methyl methacrylate) (PS/PMMA) has been studied with small and large amplitude oscillations at a temperature above their glass transition. While the complex viscosity remains…

Soft Condensed Matter · Physics 2025-04-25 Anna Dmochowska , Jorge Peixinho , Cyrille Sollogoub , Guillaume Miquelard-Garnier

Cathode materials undergo various phase transitions during the charge/discharge process, and the structural transitions significantly affect the battery performance. Although phonon properties can provide a direct clue for structural…

Materials Science · Physics 2022-08-08 Haeyoon Jung , Jiyeon Kim , Sooran Kim

Polymer composite electrolytes of Nafion and phosphotungstic acid (PWA) are fabricated and analyzed using electrochemical strain microscopy (ESM) and conductive atomic force microscopy (C-AFM) to visualize hydrophilic ion channels near the…

Applied Physics · Physics 2019-09-05 Suran Kim , Chungik Oh , Hongjun Kim , Yuanyuan Shi , Mario Lanza , Kwangsoo No , Seungbum Hong

The morphology and transport properties of thin films of the ionomer Nafion, with thicknesses on the order of the bulk cluster size, have been investigated as a model system to explain the anomalous behaviour of catalyst/electrode-polymer…

Materials Science · Physics 2018-01-16 Peter Vanya , Jonathan Sharman , James A. Elliott

Considering electron correlation appropriately is important to predict the properties of layered transition metal oxides, which have drawn a lot of attention as cathode materials for sodium-ion batteries. Here, we explore the phonon and…

Materials Science · Physics 2022-09-29 Haeyoon Jung , Jiyeon Kim , Sooran Kim

We report the electrochemical sodium-ion kiinetics and distribution of relaxation time (DRT) analysis of a newly designed mixed polyanionic NaFe$_{1.6}$V$_{0.4}$(PO$_{4}$)(SO$_{4}$)$_{2}$@CNT composite as a cathode. The specific capacity of…

Chemical Physics · Physics 2024-04-22 Jayashree Pati , Rajendra S. Dhaka

We investigate ion and polymer dynamics in polymer electrolytes PPO-LiClO4 performing 2H and 7Li NMR line-shape analysis. Comparison of temperature dependent 7Li and 2H NMR spectra gives evidence for a coupling of ion and polymer dynamics.…

Materials Science · Physics 2009-11-11 M. Vogel , T. Thorbrugge

Using optical spectroscopy, we investigated the electrodynamic properties of Nb:SrTiO3/SrTiO3 superlattices. In these superlattices, a large enhancement of the Seebeck coefficient (S) has been reported with decreasing Nb:SrTiO3 layer…

Strongly Correlated Electrons · Physics 2010-07-09 Woo Seok Choi , Hiromichi Ohta , Soon Jae Moon , Yun Sang Lee , Tae Won Noh

Using d. functional theory (DFT) computations, the authors demonstrated a substantial skeletal relaxation when the structure of 2,5-bis-[4-anthracene-9-yl-phenyl]-1,1-dimethyl-3,4-diphenyl-silole (BAS) is optimized in the gas-phase…

Cross-plane electrical and thermal transport in thin films of a conducting polymer (poly(3,4-ethylenedioxythiophene), PEDOT) stabilized with trifluoromethanesulfonate (OTf) is investigated in this study. We explore their electrical…

Materials Science · Physics 2022-06-16 K. Kondratenko , D. Guerin , X. Wallart , S. Lenfant , D. Vuillaume

The accurate characterization of electrical double layer properties of nanoparticles is of fundamental importance for optimizing their physicochemical properties for specific biotechnological and biomedical applications. In this article, we…

Chemical Physics · Physics 2017-04-05 Christian Hunley , Marcelo Marucho

A large body of experimental work on the microstructure and dynamics of simplifiedindustrial nanocomposites made of disordered silica filler in a styrene-butadiene matrixby solid-phase mixing is regrouped and critically discussed in this…

Soft Condensed Matter · Physics 2018-11-21 Anne-Caroline Genix , Guilhem P. Baeza , Julian Oberdisse

The growing library of two-dimensional layered materials is providing researchers with a wealth of opportunity to explore and tune physical phenomena at the nanoscale. Here, we review the experimental and theoretical state-of-art concerning…

Materials Science · Physics 2016-11-23 Bálint Náfrádi , Mohammad Choucair , László Forró
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