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We studied by means of computer simulations the low temperature properties of two-dimensional parahydrogen clusters comprising between 7 and 30 molecules. Computed energetics is in quantitative agreement with that reported in the only…

Statistical Mechanics · Physics 2014-06-05 Saheed Idowu , Massimo Boninsegni

We study by Quantum Monte Carlo simulations the local superfluid response of small (up to 27 molecules) parahydrogen clusters, down to temperatures as low as 0.05 K. We show that at low temperature superfluidity is not confined at the…

Statistical Mechanics · Physics 2009-11-13 Fabio Mezzacapo , Massimo Boninsegni

We present results of a theoretical study of para-hydrogen and ortho-deuterium clusters at low temperature (0.5 K < T < 3.5 K), based on Path Integral Monte Carlo simulations. Clusters of size up to N=21 para-hydrogen molecules are nearly…

Statistical Mechanics · Physics 2007-05-23 Fabio Mezzacapo , Massimo Boninsegni

Structural and superfluid properties of para-Hydrogen clusters of size up to N=40 molecules, are studied at low temperature (0.5 K < T < 4 K) by Path Integral Monte Carlo simulations. The superfluid fraction displays an interesting,…

Statistical Mechanics · Physics 2009-11-11 Fabio Mezzacapo , Massimo Boninsegni

We present results of a theoretical study of structural and superfluid properties of parahydrogen clusters comprising 25, 26 and 27 molecules at low temperature. The microscopic model utilized here is based on the Silvera-Goldman pair…

Statistical Mechanics · Physics 2016-09-28 Fabio Mezzacapo , Massimo Boninsegni

First principle computer simulations yield evidence of a finite superfluid response at low temperature of a parahydrogen cluster of 15 molecules in bulk superfluid He-4. The superfluid fraction is worth ~44% at T=0.25 K, growing to about…

Other Condensed Matter · Physics 2020-10-20 Massimo Boninsegni

Computer simulations yield evidence of superfluid behavior of nanoscale size clusters of parahydrogen adsorbed on a graphite substrate at low temperature ($T\lesssim 0.25 \text{ K}$). Clusters with a number of molecules between 7 and 12…

Other Condensed Matter · Physics 2025-11-04 K. M. Kolevski , M. Boninsegni

We introduce a new criterion--based on multipole dynamical correlations calculated within Reptation Quantum Monte Carlo--to discriminate between a melting vs. freezing behavior in quantum clusters. This criterion is applied to small…

Other Condensed Matter · Physics 2007-05-23 Stefano Baroni , Saverio Moroni

A muonium hydride molecule is a bound state of muonium and hydrogen atoms. It has half the mass of a parahydrogen molecule and very similar electronic properties in its ground state. The phase diagram of an assembly of such particles is…

Statistical Mechanics · Physics 2021-05-12 Youssef Kora , Massimo Boninsegni , Dam Thanh Son , Shiwei Zhang

Confinement has generally the effect of suppressing order in condensed matter. Indeed, phase transitions such as freezing, or the superfluid transition in liquid helium, occur at lower temperatures in confinement than they do in the bulk.…

Mesoscale and Nanoscale Physics · Physics 2014-08-22 Tokunbo Omiyinka , Massimo Boninsegni

We investigate mixed (50/50) clusters of parahydrogen and orthodeuterium at low temperature, by means of Quantum Monte Carlo simulations. Our results provide evidence of liquid-like behavior and partial isotopic separation in a cluster of…

Mesoscale and Nanoscale Physics · Physics 2025-03-27 Kiril M. Kolevski , Jie-Ru Hu , Massimo Boninsegni

We study by computer simulations the effect of confinement on the superfluid properties of small two-dimensional (2D) parahydrogen clusters. For clusters of fewer than twenty molecules, the superfluid response in the low temperature limit…

Mesoscale and Nanoscale Physics · Physics 2015-04-02 Saheed Idowu , Massimo Boninsegni

The possible superfluid transition of supercooled liquid parahydrogen is investigated by quantum Monte Carlo simulations. The cooling protocol adopted here allows for the investigation of a fluid phase down to a temperature T=0.25 K. No…

Statistical Mechanics · Physics 2018-03-07 Massimo Boninsegni

The low temperature physics of parahydrogen (ph2) confined in cylindrical channels of diameter of the order of 1 nm is studied theoretically by Quantum Monte Carlo simulations. On varying the attractive strength of the wall of the…

Chemical Physics · Physics 2016-03-09 Tokunbo Omiyinka , Massimo Boninsegni

Among all the freezing transitions, that of water into ice is probably the most relevant to biology, physics, geology or atmospheric science. In this work we investigate homogeneous ice nucleation by means of computer simulations. We…

Soft Condensed Matter · Physics 2013-12-04 E. Sanz , C. Vega , J. R. Espinosa , R. Caballero-Bernal , J. L. F. Abascal , C. Valeriani

We present a microscopic analysis of the quantum solvation structures of para-H$_2$ around the OCS molecule when embedded in low temperature $^4$He droplets. The structures of clusters containing M=5 and 6 para-H$_2$ molecules are compared…

Condensed Matter · Physics 2009-11-10 Yongkyung Kwon , K. Birgitta Whaley

The superfluid response of nanoscale size quasi-2D He-4 droplets adsorbed on a graphite substrate is investigated by computer simulations. It is found that clusters comprising as few as 7 atoms are stable at temperatures lower than < 0.15…

Other Condensed Matter · Physics 2025-05-05 K. M. Kolevski , M. Boninsegni

The interplay between magic number stabilities and superfluidity of small para-hydrogen clusters with sizes $N = 5$ to 40 and temperatures $0.5 K \leq T \leq 4.5 $K is explored with classical and quantum Path Integral Monte Carlo…

Computational Physics · Physics 2010-09-14 S. A. Khairallah , M. B. Sevryuk , D. M. Ceperley , J. P. Toennies

We present results from large-scale molecular dynamics (MD) simulations of homogeneous vapor-to-liquid nucleation. The simulations contain between one and eight billion Lennard-Jones (LJ) atoms, covering up to 1.2 {\mu}s (56 million…

Chemical Physics · Physics 2013-08-22 Jürg Diemand , Raymond Angélil , Kyoko K. Tanaka , Hidekazu Tanaka

Macroscopic systems of hydrogen molecules exhibit a rich thermodynamic phase behavior. Due to the simplicity of the molecular constituents a detailed exploration of the thermal properties of these boson systems at low temperatures is of…

Other Condensed Matter · Physics 2009-11-11 Thomas Lindenau , Manfred L. Ristig , Klaus A. Gernoth , Javier Dawidowski , Francisco J. Bermejo
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