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We have studied the electronic structure of BaCoO$_3$ using soft x-ray absorption spectroscopy at the Co-$L_{2,3}$ and O-$K$ edges, magnetic circular dichroism at the Co-$L_{2,3}$ edges, as well as valence band hard x-ray photoelectron…

It has been shown that the crystal-field interactions can produce a non- magnetic singlet ground state for the highly-correlated d6 system situated in the quasi-octahedral crystal field (CEF) surrounding provided the spin-orbit interactions…

Strongly Correlated Electrons · Physics 2009-10-31 R. J. Radwanski , Z. Ropka

The crystal structure of hexagonal-Sr0.6Ba0.4MnO3 allows various competing superexchange interactions, leading to intriguing magnetic properties. Local structural changes modify overlapping between Mn and oxygen ions with temperature.…

To examine the insulating mechanism of 5$d$ transition metal oxide Sr$_2$IrO$_4$, we study the ground state properties of a three-orbital Hubbard model with a large relativistic spin-orbit coupling on a square lattice. Using a variational…

Strongly Correlated Electrons · Physics 2014-09-22 Hiroshi Watanabe , Tomonori Shirakawa , Seiji Yunoki

Spin-orbit coupling (SOC) plays an important role in determining the structural and electronic properties of recently proposed two-dimensional planar pentagonal materials. In this work, density functional theory calculations are employed to…

The 5d iridates have been the subject of much recent attention due to the predictions of a large array of novel electronic phases driven by twisting strong spin-orbit coupling and Hubbard correlation. As a prototype, the single layered…

Materials Science · Physics 2015-03-10 Chengliang Lu , Shuai Dong , Andy Quindeau , Daniele Preziosi , Ni Hu , Marin Alexe

Here we report on the low-energy excitations within the paramagnetic spin-orbit insulator Sr$_3$Ir$_2$O$_7$F$_2$ studied via resonant inelastic X-ray scattering, \textit{ab initio} quantum chemical calculations, and model-Hamiltonian…

Strongly Correlated Electrons · Physics 2022-09-26 Zach Porter , Paul M. Sarte , Thorben Petersen , Mary H. Upton , Liviu Hozoi , Stephen D. Wilson

We report on the cubic double perovskite Ba2MgReO6 containing Re6+ ions with the 5d1 electron configuration. Resistivity, magnetization, and heat capacity measurements using single crystals show that the compound is a Mott insulator with a…

Strongly Correlated Electrons · Physics 2019-06-11 Daigorou Hirai , Zenji Hiroi

Sr2IrO4 exhibits a novel insulating state driven by spin-orbit interactions. We report two novel phenomena, namely a large magnetoresistivity in Sr2IrO4 that is extremely sensitive to the orientation of magnetic field but exhibits no…

Strongly Correlated Electrons · Physics 2015-05-28 M. Ge , T. F. Qi , O. B. Korneta , D. E. De Long , P. Schlottmann , W. P. Crummett , G. Cao

Na$_{3}$Co$_{2}$SbO$_6$ is a promising candidate to realize the Kitaev spin liquid phase since the large Kitaev spin exchange interaction is tunable via the change in electronic structure, such as the trigonal crystal field splitting…

Strongly Correlated Electrons · Physics 2025-08-12 Nam Nguyen , Alex Taekyung Lee , Anh T. Ngo , Hyowon Park

We investigate the thickness-dependent electronic structure of ultrathin SrIrO$_3$ and discover a transition from a semimetallic to a correlated insulating state below 4 unit cells. Low-temperature magnetoconductance measurements show that…

FePS3 is a layered van der Waals (vdW) Ising antiferromagnet that has recently been studied in the context of true 2D magnetism, and emerged as an ideal material platform for investigating strong spin-phonon coupling, and non-linear…

Strongly Correlated Electrons · Physics 2024-06-25 Ramesh Dhakal , Samuel Griffith , Stephen M. Winter

The electronic structure and magnetism of Sr$_2$CeIrO$_6$, an Ir-based double perovskite system has been investigated using first-principles calculations. We found that a strong spin-orbit coupling dictate the electronic and magnetic…

Strongly Correlated Electrons · Physics 2013-01-29 S. K. Panda , I. Dasgupta

The odd-parity spin-triplet Cooper pairing states show a six-fold degeneracy for a quasi-two-dimensional electron system. In this article we show how spin-orbit coupling can lift this degeneracy for Sr_2RuO_4 taking the band structure based…

Superconductivity · Physics 2009-10-31 Kwai-Kong Ng , Manfred Sigrist

The rich physics manifested by 5d oxides falls outside the Mott-Hubbard paradigm used to successfully explain the electronic and magnetic properties of 3d oxides. Much consideration has been given to the extent to which strong spin-orbit…

Transition metal compounds with the $(t_{2g})^4$ electronic configuration are expected to be nonmagnetic atomic singlets both in the weakly interacting regime due to spin-orbit coupling, as well as in the Coulomb dominated regime with…

Strongly Correlated Electrons · Physics 2017-01-16 Christopher Svoboda , Mohit Randeria , Nandini Trivedi

Emergence of novel quantum ground states in correlated electron systems with strong spin-orbit coupling has been a recent subject of intensive studies. While it has been realized that spin-orbit coupling can provide non-trivial band…

Strongly Correlated Electrons · Physics 2016-09-05 Robert Schaffer , Eric Kin-Ho Lee , Bohm-Jung Yang , Yong Baek Kim

The 3$d$-5$d$ based double perovskites offer an ideal playground to study the interplay between electron correlation ($U$) and spin-orbit coupling (SOC) effect, showing exotic physics. The Sr$_2$FeIrO$_6$ is an interesting member in this…

Strongly Correlated Electrons · Physics 2020-10-23 K. C. Kharkwal , Roumita Roy , Harish Kumar , A. K. Bera , S. M. Yusuf , A. K. Shukla , Kranti Kumar , Sudipta Kanungo , A. K. Pramanik

We investigate the electronic structure and magnetic properties of a $J_\text{eff} = 1/2$ iridate Ca$_4$IrO$_6$ and the implications of doping electrons and holes using ab initio density functional theory. Our calculations considering…

Strongly Correlated Electrons · Physics 2022-09-02 Avishek Singh , Jayita Chakraborty , Nirmal Ganguli

The importance of the spin-orbit coupling (SOC) effect in Fe-based superconductors (FeSCs) has recently been under hot debate. Considering the Hund's coupling-induced electronic correlation, the understanding of the role of SOC in FeSCs is…

Superconductivity · Physics 2020-02-19 J. Li , B. Lei , D. Zhao , L. P. Nie , D. W. Song , L. X. Zheng , S. J. Li , B. L. Kang , X. G. Luo , T. Wu , X. H. Chen
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