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We consider the resonant van der Waals interaction between two correlated identical two-level atoms (at least one of which being excited) within the framework of macroscopic cavity quantum electrodynamics in linear, dispersing and absorbing…

Quantum Physics · Physics 2018-05-09 Saeideh Esfandiarpour , Robert Bennett , Hassan Safari , Stefan Yoshi Buhmann

The effective capillary interaction potentials for small colloidal particles trapped at the surface of liquid droplets are calculated analytically. Pair potentials between capillary monopoles and dipoles, corresponding to particles floating…

Soft Condensed Matter · Physics 2015-05-27 J. Guzowski , M. Tasinkevych , S. Dietrich

We calculate the van der Waals dispersive interaction between a neutral but polarizable atom and a perfectly conducting isolated sphere in the nonretarded case. We make use of two separate models, one being the semiclassical…

Quantum Physics · Physics 2009-03-13 M. M. Taddei , T. N. C. Mendes , C. Farina

Long range electrostatic and van der Waals coefficients up to terms of order R-8 have been evaluated by the sum over states method using ab initio and time dependent density functional theory. We employ several widely used density…

Chemical Physics · Physics 2015-05-30 Jason N. Byrd , Robin Cote , John A. Montgomery

The van der Waals dispersion interaction between two chiral molecules in the presence of arbirary magnetoelectric media is derived using perturbation theory. To be general, the molecular polarisabilities are assumed to be of electric,…

Quantum Physics · Physics 2020-06-24 Hassan Safari , Pablo Barcellona , Stefan Yoshi Buhmann , Akbar Salam

The van der Waals atom-surface attraction, scaling as C3 z-3 for z the atom-surface distance, is expected to be valid in the distance range 1-1000 nm, covering 8-10 orders of magnitudes in the interaction energy. A Cs vapour nanocell allows…

For microwave-dressed polar molecules, we analytically derive an intermolecular potential composed of an anisotropic van der Waals shielding core and a long-range dipolar interaction. We validate this effective potential by comparing its…

Atomic Physics · Physics 2023-05-17 Fulin Deng , Xing-Yan Chen , Xin-Yu Luo , Wenxian Zhang , Su Yi , Tao Shi

The structure and stability of atomic and molecular systems with van der Waals (vdW) bonding are often determined by the interplay between attractive dispersion interactions and repulsive interactions caused by electron confinement. Arising…

Chemical Physics · Physics 2022-02-17 Ornella Vaccarelli , Dmitry V. Fedorov , Martin Stöhr , Alexandre Tkatchenko

We investigate the van der Waals interactions in solid molecular hydrogen structures. We calculate enthalpy and the Gibbs free energy to obtain zero and finite temperature phase diagrams, respectively. We employ density functional theory…

Materials Science · Physics 2019-05-10 Sam Azadi , Graeme J. Ackland

Van der Waals (vdW) materials offer new ways to assemble artificial electronic media with properties controlled at the design stage, by combining atomically defined layers into interfaces and heterostructures. Their potential for…

In a framework for long-range density-functional theory we present a unified full-field treatment of the asymptotic van der Waals interaction for atoms, molecules, surfaces, and other objects. The only input needed consists of the electron…

Condensed Matter · Physics 2009-10-31 Erika Hult , Henrik Rydberg , Bengt I. Lundqvist , David C. Langreth

We present a theoretical approach to determine the electronic properties of nanoscale systems exhibiting strong electron-electron and electron-phonon interactions and coupled to metallic electrodes. This approach is based on an…

Strongly Correlated Electrons · Physics 2009-11-13 A. Martin-Rodero , A. Levy Yeyati , F Flores , R. C. Monreal

Potential steps exceeding 1 eV are regularly formed at metal|insulator interfaces, even when the interaction between the materials at the interface is weak physisorption. From first-principles calculations on metal|h-BN interfaces we show…

Mesoscale and Nanoscale Physics · Physics 2014-12-01 Menno Bokdam , Geert Brocks , Paul J. Kelly

By utilizing the current transients in scanning tunneling spectroscopy, the local interfacial electronics between multiwalled carbon nanotubes and several supporting substrates has been investigated. Voltage offsets in the tunneling spectra…

Condensed Matter · Physics 2007-05-23 R. Czerw , B. Foley , D. Tekleab , A. Rubio , P. M. Ajayan , D. L. Carroll

A simple theory is proposed for the dispersive molecular binding of unusually high magnitude due to an enhanced polarizability. Two alternative ways have so far been considered in the literature leading to the polarizability enhancement:…

Soft Condensed Matter · Physics 2007-05-23 Mladen Georgiev , Alexander Gochev , Jai Singh

A general expression was obtained for the dynamic energy of the van der Waals interaction of a neutral atom with a flat slit whose walls are characterized by a frequency-dependent dielectric permittivity. The interaction of cesium atoms…

Mesoscale and Nanoscale Physics · Physics 2015-01-06 G. V. Dedkov , A. A. Kyasov

Alkaline-earth-like transition-metal atoms such as Zn and Cd are promising candidates for precision measurements and quantum many-body physics experiments. Here, we theoretically investigate the properties of diatomic molecules containing…

Atomic Physics · Physics 2021-11-02 Klaudia Zaremba-Kopczyk , Michał Tomza

Compact analytical forms are derived for the interactions involving thin disks in two dimensions using an integration approach. These include interactions between a disk and a material point, between two disks, and between a disk and a…

Soft Condensed Matter · Physics 2025-11-27 Binghan Liu , Junwen Wang , Gary S. Grest , Shengfeng Cheng

The 1%-accurate calculations of the van der Waals interaction between an atom and a cavity wall are performed in the separation region from 3 nm to 150 nm. The cases of metastable He${}^{\ast}$ and Na atoms near the metal, semiconductor or…

Quantum Physics · Physics 2009-11-11 A. O. Caride , G. L. Klimchitskaya , V. M. Mostepanenko , S. I. Zanette

The method recently developed to include Van der Waals interactions in the Density Functional Theory by using the Maximally-Localized Wannier functions, is improved and extended to the case of atoms and fragments weakly bonded (physisorbed)…

Other Condensed Matter · Physics 2009-11-13 Pier Luigi Silvestrelli , Karima Benyahia , Sonja Grubisic Francesco Ancilotto , Flavio Toigo