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We present further evidence that gelation is an arrested phase separation in attractive colloid-polymer mixtures, based on a method combining confocal microscopy experiments with numerical simulations recently established in {\bf Nature…

Soft Condensed Matter · Physics 2009-11-13 Emanuela Zaccarelli , Peter J. Lu , Fabio Ciulla , David. A. Weitz , Francesco Sciortino

We present molecular dynamics simulations of aggregation kinetics in a colloidal suspension modeled as a highly asymmetric binary mixture. Starting from a configuration with largely uncorrelated colloidal particles the system relaxes by…

Statistical Mechanics · Physics 2007-05-23 Sorin Bastea

We present a new first-principles theory of dynamic arrest in colloidal mixtures based on the multi-component self-consistent generalized Langevin equation (SCGLE) theory of colloid dynamics [Phys. Rev. E {\bf 72}, 031107 (2005); ibid {\bf…

Materials Science · Physics 2009-11-13 Rigoberto Juárez-Maldonado , Magdaleno Medina-Noyola

Recent theories predict that when a supercooled liquid approaches the glass transition, particle clusters with a special "amorphous order" nucleate within the liquid, which lead to static correlations dictating the dramatic slowdown of…

Soft Condensed Matter · Physics 2016-03-04 Bo Zhang , Xiang Cheng

We report an extensive numerical study of a charged colloidal system with competing short-range depletion attraction and long-range electrostatic repulsion. By analizing the cluster properties, we identify two distinct regions in the phase…

Soft Condensed Matter · Physics 2009-03-18 Juan Carlos Fernandez Toledano , Francesco Sciortino , Emanuela Zaccarelli

The dynamical arrest of gels is the consequence of a well defined structural phase transition, leading to the formation of a spanning cluster of bonded particles. The dynamical glass transition, instead, is not accompanied by any clear…

Soft Condensed Matter · Physics 2016-07-21 Raffaele Pastore , Antonio de Candia , Anallisa Fierro , Massimo Pica Ciamarra , Antonio Coniglio

The possibilities to tune the structure of solid like material resulting from arrested spinodal decomposition is investigated using a system composed of lysozyme, a globular protein, dispersed in a water solution as model system for…

Dynamical heterogeneities in a colloidal fluid close to gelation are studied by means of computer simulations. A clear distinction between some fast particles and the rest, slow ones, is observed, yielding a picture of the gel composed by…

Soft Condensed Matter · Physics 2009-11-10 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

A mixture of hard-sphere particles and model emulsion droplets is studied with a Brownian dynamics simulation. We find that the addition of nonwetting emulsion droplets to a suspension of pure hard spheres can lead to both gas-liquid and…

Soft Condensed Matter · Physics 2015-03-13 Andrea Fortini

The growing interest in the non-equilibrium assembly of colloidal particles in active liquids is driven by the motivation to create novel structures endowed with tunable properties unattainable within the confines of equilibrium systems.…

Soft Condensed Matter · Physics 2024-03-06 Pragya Kushwaha , Sayan Maity , Anjaly S. Menon , Raghunath Chelakkot , Vijayakumar Chikkadi

The aggregation of attractive colloids has been extensively studied from both theoretical and experimental perspectives as the fraction of solid particles is changed, and the range, type and strength of attractive or repulsive forces…

Soft Condensed Matter · Physics 2019-11-07 Safa Jamali , Robert C. Armstrong , Gareth H. McKinley

Simple models based on isotropic interparticle attractions often fail to capture experimentally observed structures of colloidal gels formed through spinodal decomposition and subsequent arrest: the resulting gels are typically denser and…

Soft Condensed Matter · Physics 2021-08-27 Jasper N. Immink , J. J. Erik Maris , Peter Schurtenberger , Joakim Stenhammar

We study a model in which particles interact with short-ranged attractive and long-ranged repulsive interactions, in an attempt to model the equilibrium cluster phase recently discovered in sterically stabilized colloidal systems in the…

Soft Condensed Matter · Physics 2009-11-10 Francesco Sciortino , Stefano Mossa , Emanuela Zaccarelli , Piero Tartaglia

We investigated the viscoelastic properties of colloid-polymer mixtures at intermediate colloid volume fraction and varying polymer concentrations, thereby tuning the attractive interactions. Within the examined range of polymer…

Soft Condensed Matter · Physics 2008-12-05 M. Laurati , G. Petekidis , N. Koumakis , F. Cardinaux , A. B. Schofield , J. M. Brader , M. Fuchs , S. U. Egelhaaf

We report, for the first time, some experimental observations regarding a new type of long range interaction between rigid particles that prevails when they are suspended in an soft elastic gel. A denser particle submerges itself to a…

Soft Condensed Matter · Physics 2014-01-29 Aditi Chakrabarti , Manoj K. Chaudhury

We explore structural and dynamical behavior of concentrated colloidal suspensions made up by C-shape particles using Brownian dynamics computer simulations and theory. In particular, we focus on the entanglement process between nearby…

Soft Condensed Matter · Physics 2016-05-04 Christian Hoell , Hartmut Löwen

We use a combination of original light scattering techniques and particles with unique optical properties to investigate the behavior of suspensions of attractive colloids under gravitational stress, following over time the concentration…

Soft Condensed Matter · Physics 2015-05-27 Giovanni Brambilla , Stefano Buzzaccaro , R. Piazza , Ludovic Berthier , Luca Cipelletti

We study the relation between the directed polymer and the directed percolation models, for the case of a disordered energy landscape where the energies are taken from bimodal distribution. We find that at the critical concentration of the…

Statistical Mechanics · Physics 2009-10-31 Ehud Perlsman , Shlomo Havlin

Self-propelled particles possessing permanent magnetic dipole moments occur naturally in magnetotactic bacteria and in man-made systems like active colloids or micro-robots. Yet, the interplay between self-propulsion and anisotropic…

Soft Condensed Matter · Physics 2024-04-29 Maria Kelidou , Mohammad Fazelzadeh , Baptiste Parage , Sara Jabbari Farouji

Using Brownian dynamics simulations we study gel-forming colloid-polymer mixtures. The focus of this article lies on the differences of dense and dilute gel networks in terms of structure formation both on a local and a global level. We…

Soft Condensed Matter · Physics 2023-12-19 Matthias Gimperlein , Jasper N. Immink , Michael Schmiedeberg