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We report a combined experimental and theoretical study of the melting curve and the structural behavior of vanadium under extreme pressure and temperature. We performed powder x-ray diffraction experiments up to 120 GPa and 4000 K,…

Materials Science · Physics 2019-10-02 D. Errandonea , S. G. MacLeod , L. Burakovsky , D. Santamaria-Perez , J. E. Proctor , H. Cynn , M. Mezouar

Pressure and temperature dependent susceptibility and Raman scattering experiments on single crystalline Cu_xZn_(1-x)GeO_3 have shown an unusually strong increase of the spin-Peierls phase transition temperature upon applying hydrostatic…

High-temperature and high-pressure experiments were conducted on columbite-type ZnNb2O6, reaching temperatures up to 873 K at ambient pressure and pressures up to 30 GPa at ambient temperature, respectively. Through systematic analysis…

The high pressure(P)-high temperature(T) phase diagram of solid ammonia has been investigated using diamond anvil cell and resistive heating techniques. The III-IV transition line has been determined up to 20 GPa and 500 K both on…

Materials Science · Physics 2009-11-13 Sandra Ninet , Frédéric Datchi

X-ray diffraction with synchrotron radiation has been used for the first time to study chemical interaction in the MnO-ZnO system at 4.8 GPa and temperatures up to 1600 K. Above 750 K, the chemical reaction between MnO and ZnO has been…

Materials Science · Physics 2011-03-24 P. S. Sokolov , A. N. Baranov , C. Lathe , V. Z. Turkevich , V. L. Solozhenko

Elastic neutron-scattering, inelastic x-ray scattering, specific-heat, and pressure-dependent electrical transport measurements have been made on single crystals of AuZn and Au_{0.52}Zn_{0.48} above and below their martensitic transition…

The high pressure and high temperature phase diagram of Ta has been studied in a laser-heated diamond-anvil cell (DAC) using x-ray diffraction measurements up to 52 GPa and 3800 K. The melting was observed at nine different pressures, being…

Materials Science · Physics 2009-11-10 D. Errandonea , M. Somayazulu , D. Hausermann , H. K. Mao

Melting experiments require rapid data acquisition due to instabilities of the molten sample and optical drifting due to the high required laser power. In this work, the melting curve of zirconium has been determined for the first time up…

Materials Science · Physics 2019-08-14 Paraskevas Parisiades , Federico Cova , Gaston Garbarino

We report an investigation of hexagonal Y_(1-x)Eu_xMnO_3 ceramics with x=0, 0.1 and 0.2 using infrared and THz spectroscopies in the temperature range between 5 and 900 K. The temperature dependence of the THz permittivity reveals a kink…

Materials Science · Physics 2012-02-13 V. Goian , S. Kamba , C. Kadlec , D. Nuzhnyy , P. Kuzel , J. Agostinho Moreira , A. Almeida , P. B. Tavares

Manganese, in the a-Mn structure, has been studied using synchrotron powder x-ray diffraction in a diamond anvil cell up to 220 GPa at room temperature combined with density functional calculations (DFT). The experiment reveals an extended…

Experiments and computer simulations have shown that the melt-ing temperature of solid hydrogen drops with pressure above about 65 GPa, suggesting that a liquid state might exist at low temperatures. It has also been suggested that this low…

An assessment of the Sn unary system is presented. First, the literature on phase equilibria, the thermodynamic properties, the volume and related properties, and shock compression of tin is thoroughly reviewed. Second, the Sn system is…

Materials Science · Physics 2022-06-24 Guillaume Deffrennes , Philippe Faure , François Bottin , Jean-Marc Joubert , Benoit Oudot

The phase diagram of oxygen is investigated for pressures from 50 to 130~GPa and temperatures up 1200 K using first principles theory. A metallic molecular structure with the $P6_3/mmc$ symmetry ($\eta^{'}$ phase) is determined to be…

Computational Physics · Physics 2019-02-19 S. F. Elatresh , S. A. Bonev

In situ high-pressure energy dispersive x-ray diffraction experiments on polycrystalline powder TiN with NaCl-type structure have been conducted with the pressure up to 30.1 GPa by using the diamond anvil cell instrument with synchrotron…

Materials Science · Physics 2009-11-11 J. G. Zhao , L. X. Yang , Y. Yu , S. J. You , R. C. Yu , L. C. Chen , F. Y. Li , C. Q. Jin , X. D. Li , Y. C. Li , J. Liu

We investigate the temperature dependence of the pressure-induced softening in the negative thermal expansion material Zn(CN)$_2$ using neutron powder diffraction and molecular dynamics simulations. Both the simulation and experiment show…

Materials Science · Physics 2014-07-02 Hong Fang , Anthony E. Phillips , Martin T. Dove , Matthew G. Tucker , Andrew L. Goodwin

We report high-pressure magnetization and $^{35}$Cl NMR studies on $\alpha$-RuCl$_3$ with pressure up to 1.5~GPa. At low pressures, the magnetic ordering is identified by both the magnetization data and the NMR data, where the $T_N$ shows a…

Strongly Correlated Electrons · Physics 2017-12-06 Y. Cui , J. Zheng , K. Ran , Jinsheng Wen , Zhengxin Liu , B. Liu , Wenan Guo , Weiqiang Yu

Studying the effect of high pressure (exceeding 10 kbar) on the structure of solids allows to gain deeper insight in the mechanism governing crystal structure stability. Here we report a study on the high-pressure behaviour of zinc…

Materials Science · Physics 2020-04-08 Dominik Kurzydłowski , Anna Oleksiak , Sharad Babu Pillai , Prafulla K. Jha

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

Results of X-ray diffraction experiments on solid oxygen at low temperature and at pressures up to 10 GPa are presented.A careful sample preparation and annealing around 240 K allowed to obtain very good diffraction patterns in the…

Materials Science · Physics 2009-11-07 Federico A. Gorelli , Mario Santoro , Lorenzo Ulivi , Michael Hanfland

The electrical and structural characteristics of 50 nm zinc oxide (ZnO) metal-semiconductor-metal (MSM) ultraviolet (UV) photodetectors subjected to proton irradiation at different temperatures are reported and compared. We irradiated the…

Applied Physics · Physics 2019-12-06 Thomas Heuser , Caitlin Chapin , Max Holliday , Yongqiang Wang , Debbie G. Senesky
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