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Copper dopants are varyingly reported to enhance photocatalytic activity at titanium dioxide surfaces through uncertain mechanisms. In order to interpret how copper doping might alter the performance of titanium dioxide photocatalysts in…

Materials Science · Physics 2018-11-26 M. Hussein N. Assadi , Dorian A. H. Hanaor

TiO$_2$ anatase has its significant importance in energy and environmental research. However, the major drawback of this immensely popular semi-conductor is its large bandgap of 3.2 eV. Several non-metals have been doped experimentally for…

Materials Science · Physics 2020-02-25 Pooja Basera , Shikha Saini , Saswata Bhattacharya

The efforts in the optimization of the physical and chemical properties related to the photocatalytic efficiency of TiO2 nanoparticles relies mainly on defect engineering strategies, been the structural and the doping the most common ones.…

Materials Science · Physics 2022-03-07 M. P. Ferreira , H. B. de Carvalho

This paper reports on the structural and optical properties of Co-doped TiO2 thin films grown onto (0001) Al2O3 substrates by non-reactive pulsed laser deposition (PLD) using argon as buffer gas. It is shown that by keeping constant the…

Materials Science · Physics 2013-07-09 S. Rout , N. Popovici , S. Dalui , M. L. Paramês , R. C. Silva , A. J. Silvestre , O. CondE

Electronic structures and optical properties of C-N-codoped anatase TiO2 were calculated by using GGA+U method based on the density functional theory. The calculated results showed that the N-doped, C-doped, and C-N-codoped TiO2 produced 2p…

Materials Science · Physics 2015-08-10 Meili Guo , Jiulin Du

We perform first-principles calculations to investigate the band structure, density of states, optical absorption, and the imaginary part of dielectric function of Cu, Ag, and Au-doped anatase TiO2 in 72 atoms systems. The electronic…

Materials Science · Physics 2015-08-10 Meili Guo , Jiulin Du

TiO$_2$ and SrTiO$_3$ are well known materials in the field of photocatalysis due to their exceptional electronic structure, high chemical stability, non-toxicity and low cost. However, owing to the wide band gap, these can be utilized only…

Materials Science · Physics 2020-09-25 Manish Kumar , Pooja Basera , Shikha Saini , Saswata Bhattacharya

Titanium-based oxides are abundant, chemically stable, non-toxic, and highly versatile materials, with applications ranging from photovoltaics to catalysis. For rutile and anatase phases of Titanium dioxide (TiO2), the bandgap ranges from…

Materials Science · Physics 2022-01-04 Lynet Allan , George O Amolo , Julius Mwabora , Silas Mureramanzi

The structural, electronic, and optical properties of metal (Si, Ge, Sn, and Pb) mono- and co-doped anatase TiO$_{2}$ nanotubes are investigated, in order to elucidate their potential for photocatalytic applications. It is found that Si…

Mesoscale and Nanoscale Physics · Physics 2020-04-29 Mohamed M. Fadlallah , Ulrich Eckern

The Co-doped anatase TiO$_{2}$, a recently discovered room-temperature ferromagnetic insulator, has been studied by the first-principles calculations in the pseudo-potential plane-wave formalism within the local-spin-density approximation…

Materials Science · Physics 2007-05-23 Hongming Weng , Xiaoping Yang , Jinming Dong , H. Mizuseki , M. Kawasaki , Y. Kawazoe

Phase transition from anatase to rutile for the 70nm TiO2 crystallite has been investigated by annealing at different temperatures followed by TDPAC measurement of these TiO2 crystallites adsorbed with 181Hf tracer. The width of the peaks…

Materials Science · Physics 2009-05-11 S. K. Das , D. Banerjee , S. V. Thakare , P. Y. Nabhiraj , R. Menon , R. K. Bhandari , K. Krishnan

In this paper, I demonstrate a density functional theory plus dynamical mean field theory study on the electronic properties of doped $TiO_2$ rutile as well as another tetragonal phase anatase with oxygen vacancy. The density of states and…

Strongly Correlated Electrons · Physics 2021-12-24 S. Koley

The optical properties of thermally annealed TiO2 samples depend on their preparation process, and the TiO2 thin films usually exist in the form of anatase or rutile or the mixture of the two phases. The electronic structures and optical…

Materials Science · Physics 2016-11-29 Li Jinping , Meng Songhe , Qin Liyuan , Hantao Lu

Substitutional doping with transition metals is carried out in the Lepidocrocite phase - the stable monolayer geometry of TiO$_2$, using density functional theory (DFT) methods. The doping is carried out at the differently coordinated O…

Materials Science · Physics 2024-10-14 Kati Asikainen , Matti Alatalo , Marko Huttula , S. Assa Aravindh

We report the growth of electrically-resistive vanadium-doped beta-Ga2O3 single crystals via the optical floating zone technique. By carefully controlling the growth parameters V-doped crystals with very high electrical resistivity compared…

We report on the optical properties of magnetic cobalt-doped anatase phase titanium dioxide Ti_{1-x}Co_{x}O_{2-d} films for low doping concentrations, 0 <= x <= 0.02, in the spectral range 0.2 to 5 eV. For well oxygenated films (d << 1) the…

Strongly Correlated Electrons · Physics 2013-05-29 J. R. Simpson , H. D. Drew , S. R. Shinde , R. J. Choudhary , S. B. Ogale , T. Venkatesan

Titanium dioxide is one of the most widely investigated oxides. This is due to its broad range of applications, from catalysis to photocatalysis to photovoltaics. Despite this large interest, many of its bulk properties have been sparsely…

Materials Science · Physics 2010-03-12 L. Chiodo , J. M. García-Lastra , D. J. Mowbray , A. Iacomino , A. Rubio

Thin TiO2 films on quartz substrates were prepared by spin coating of undoped and metal-ion-doped Sol Gel precursors. These films were characterised by Scanning Electron Microscopy, Laser Raman Microspectroscopy, Xray Diffraction and UV Vis…

Materials Science · Physics 2021-06-08 D. A. H. Hanaor , G. Triani , C. C. Sorrell

The application of beta-TaON for solar-driven water splitting is hindered by limitations in phase purity, stoichiometry, crystallinity, visible-light absorption, carrier mobility, and high recombination rates. This study investigates the…

Doping is considered to be the main method for improving the thermoelectric performance of layered sodium cobaltate (Na$_{1-x}$CoO$_2$). However, in the vast majority of past reports, the equilibrium location of the dopant in the…

Materials Science · Physics 2021-06-25 M. Hussein N. Assadi
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