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Understanding the electrodes' surface morphology influence on the ions' distribution is essential for designing the supercapacitors with enhanced energy density characteristics. We develop a model for the structure of electrolytes near the…

Statistical Mechanics · Physics 2021-06-30 Timur Aslyamov , Konstantin Sinkov , Iskander Akhatov

We present a first-principles approach to describe magnetic and superconducting systems and the phenomena of competition between these electronic effects. We develop a density functional theory: SpinSCDFT, by extending the Hohenberg-Kohn…

Superconductivity · Physics 2016-05-10 A. Linscheid , A. Sanna , F. Essenberger , E. K. U. Gross

An ideal conductor electrode in contact with a semi-infinite two-dimensional two-component plasma in an external potential is considered. The model is mapped onto an integrable sine-Gordon theory with Dirichlet boundary conditions. The…

Statistical Mechanics · Physics 2011-07-19 L. Šamaj , B. Jancovici

The properties of hydrogen at warm dense matter (WDM) conditions are of high importance for the understanding of astrophysical objects and technological applications such as inertial confinement fusion. In this work, we present extensive…

Plasma Physics · Physics 2023-06-12 Tobias Dornheim , Maximilian Böhme , Zhandos Moldabekov , Jan Vorberger

The time-dependent, mean-field Newns-Anderson model for a spin-polarised adsorbate approaching a metallic surface is solved in the wide-band limit. Equations for the time-evolution of the electronic structure of the adsorbate-metal system…

Materials Science · Physics 2009-11-11 M. S. Mizielinski , D. M. Bird , M. Persson , S. Holloway

The computational study of energy storage and conversion processes calls for simulation techniques that can reproduce the electronic response of metal electrodes under electric fields. Despite recent advancements in machine-learning methods…

Materials Science · Physics 2024-05-14 Andrea Grisafi , Augustin Bussy , Mathieu Salanne , Rodolphe Vuilleumier

The response of an infinite, periodic, insulating, solid to an infinitesimally small electric field is investigated in the framework of Density Functional Theory. We find that the applied perturbing potential is not a unique functional of…

mtrl-th · Physics 2016-09-07 X. Gonze , Ph. Ghosez , R. W. Godby , .

We explore a new formalism to study the nonlinear electronic density response based on Kohn-Sham density functional theory (KS-DFT) at partially and strongly quantum degenerate regimes. It is demonstrated that the KS-DFT calculations are…

Plasma Physics · Physics 2022-05-10 Zhandos Moldabekov , Jan Vorberger , Tobias Dornheim

The Ewald3D sum with the tinfoil boundary condition (e3dtf) evaluates the electrostatic energy of a finite unit cell inside an infinitely periodic supercell. Although it has been used as a {\it de facto} standard treatment of electrostatics…

Chemical Physics · Physics 2019-07-24 Cong Pan , Shasha Yi , Zhonghan Hu

We present a modeling of the nonlinear optical response of a metal surface in order to account for recent experimental results from two-color Sum-Frequency Generation experiments on gold. The model allows calculating the surface and bulk…

Chemical Physics · Physics 2019-05-16 Bertrand Busson , Laetitia Dalstein

Given the considerable theoretical challenges in understanding strongly coupled metals and non-Fermi liquids, it is valuable to have a framework to understand properties of metals that are universal, in the sense that they must hold in any…

Strongly Correlated Electrons · Physics 2023-07-14 Dominic V. Else

Spin-current density functional theory (SCDFT) is a formally exact framework designed to handle the treatment of interacting many-electron systems including spin-orbit coupling at the level of the Pauli equation. In practice, robust and…

Semilocal density functional theory is the most used computational method for electronic structure calculations in theoretical solid-state physics and quantum chemistry of large systems, providing good accuracy with a very attractive…

Other Condensed Matter · Physics 2016-03-31 L. A. Constantin , E. Fabiano , J. M. Pitarke , F. Della Sala

We comment on the macroscopic model for surface plasmons of H.-Y. Deng [New J. Phys. 21 (2019) 043055; arXiv:1712.06101] and a claim, based on energy conversion from charges to the electric field, that surface plasmons on metallic surfaces…

Optics · Physics 2020-05-11 Gino Wegner , Carsten Henkel

The ordinary surface magnetic phase transition is studied for the exactly solvable anisotropic spherical model (ASM), which is the limit D \to \infty of the D-component uniaxially anisotropic classical vector model. The bulk limit of the…

Statistical Mechanics · Physics 2009-10-31 D. A. Garanin

Modern nanophotonic and meta-optical devices utilize a tremendous number of structural degrees of freedom to enhance light--matter interactions. A fundamental question is how large such enhancements can be. We develop an analytical…

Optics · Physics 2020-11-13 Zeyu Kuang , Lang Zhang , Owen D. Miller

In a recent Letter, Dornheim et al. [PRL 125, 085001 (2020)] have investigated the nonlinear density response of the uniform electron gas in the warm dense matter regime. More specifically, they have studied the cubic response function at…

In this paper, we investigate the energy minimization model of the ensemble Kohn-Sham density functional theory for metallic systems, in which a pseudo-eigenvalue matrix and a general smearing approach are involved. We study the invariance…

Numerical Analysis · Mathematics 2022-01-19 Xiaoying Dai , Stefano de Gironcoli , Bin Yang , Aihui Zhou

First-principles calculations using density functional theory based on norm-conserving pseudopotentials have been performed to investigate the Cs adsorption on the Si(001) surface for 0.5 and 1 ML coverages. We found that the saturation…

Strongly Correlated Electrons · Physics 2007-05-23 R. Shaltaf , E. Mete , S. Ellialtioglu

Recently, a novel low-energy collective excitation has been predicted to exist at metal surfaces where a quasi two-dimensional (2D) surface-state band coexists with the underlying three-dimensional (3D) continuum. Here we present a model in…

Materials Science · Physics 2009-11-10 J. M. Pitarke , V. U. Nazarov , V. M. Silkin , E. V. Chulkov , E. Zaremba , P. M. Echenique