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Hexagonal boron nitride (h-BN) has attracted significant attention due to its superior properties as well as its potential as an ideal dielectric layer for graphene-based devices. The h-BN films obtained via chemical vapor deposition in…

Materials Science · Physics 2015-03-11 Guangyuan Lu , Tianru Wu , Qinghong Yuan , Huishan Wang , Haomin Wang , Feng Ding , Xiaoming Xie , Mianheng Jiang

The scalable synthesis of two-dimensional (2D) hexagonal boron nitride (h-BN) is of great interest for its numerous applications in novel electronic devices. Highly-crystalline h-BN films, with single-crystal sizes up to hundreds of…

Tuning thermal transport in nanostructured materials is a powerful approach to develop high-efficiency thermoelectric materials. Using a recently developed approach based on the phonon mean free path dependent Boltzmann transport equation,…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Giuseppe Romano , Jeffrey C. Grossman

We present a theory of the phononic thermal (Kapitza) resistance at the interface between graphene or another single-layer two-dimensional (2D) crystal (e.g. MoS$_{2}$) and a flat substrate, based on a modified version of the cross-plane…

Mesoscale and Nanoscale Physics · Physics 2016-10-26 Zhun-Yong Ong , Yongqing Cai , Gang Zhang

Understanding the energy transport by charge carriers and phonons in two-dimensional (2D) van der Waals heterostructures is essential for the development of future energy-efficient 2D nanoelectronics. Here, we performed in situ spatially…

Mesoscale and Nanoscale Physics · Physics 2017-11-21 Daehee Kim , Hanul Kim , Wan Soo Yun , Kenji Watanabe , Takashi Taniguchi , Heesuk Rho , Myung-Ho Bae

A new dislocation structure-square-octagon pair (4|8) is discovered in two-dimensional boron nitride (h-BN), via first-principles calculations. It has lower energy than corresponding pentagon-heptagon pairs (5|7), which contain unfavorable…

Materials Science · Physics 2012-08-02 Yuanyue Liu , Xiaolong Zou , Boris I. Yakobson

Thermal properties of molybdenum disulfide (MoS$_2$) have recently attracted attention related to fundamentals of heat propagation in strongly anisotropic materials, and in the context of potential applications to optoelectronics and…

Two-dimensional (2D) crystals, such as graphene, hexagonal boron nitride and transitional metal dichalcogenides, have attracted tremendous amount of attention over the past decade due to their extraordinary thermal, electrical and optical…

Materials Science · Physics 2017-02-16 Y. Zhao , Z. Wan , U. Hetmaniuk , M. P. Anantram

In this study, we use the transient thermal grating optical technique \textemdash a non-contact, laser-based thermal metrology technique with intrinsically high accuracy \textemdash to investigate room-temperature phonon-mediated thermal…

Graphene is impermeable to all gases and liquids, and even such a small atom as hydrogen is not expected to penetrate through graphene's dense electronic cloud within billions of years. Here we show that monolayers of graphene and hexagonal…

Hexagonal boron nitride (h-BN) is well-established as a requisite support, encapsulant and barrier for 2D material technologies, but also recently as an active material for applications ranging from hyperbolic metasurfaces to room…

Phonon size effects induce ballistic transport in nanomaterials, challenging Fourier's law. Nondiffusive heat transport is captured by the Peierls-Boltzmann transport equation (BTE), commonly solved under the relaxation time approximation…

Mesoscale and Nanoscale Physics · Physics 2020-03-10 Giuseppe Romano

Two-dimensional transition metal dichalcogenides (TMDCs) are finding promising electronic and optical applications due to their unique properties. In this letter, we systematically study the phonon transport and thermal conductivity of…

Materials Science · Physics 2014-09-30 Xiaokun Gu , Ronggui Yang

We have investigated the lattice thermal transport across the asymmetric tilt grain boundary between armchair and zigzag graphene by nonequilibrium molecular dynamics (NEMD). We have observed significant temperature drop and ultra-low…

Mesoscale and Nanoscale Physics · Physics 2015-05-30 Hai-Yuan Cao , Hongjun Xiang , Xin-Gao Gong

Similar to the diode in electronics, a thermal diode is a two-terminal device that allows heat to transfer easier in one direction (forward bias) than in the opposite direction (reverse bias). Unlike conductive and convective thermal…

Applied Physics · Physics 2021-08-17 Dudong Feng , Shannon K. Yee , Zhuomin M. Zhang

Hexagonal boron nitride (h-BN) nanomesh, a two-dimensional insulating monolayer, grown on the (111) surface of rhodium exhibits an intriguing hexagonal corrugation pattern with a lattice constant of 3.2 nm. Despite numerous experimental and…

Materials Science · Physics 2020-08-19 Luis Henrique de Lima , Thomas Greber , Matthias Muntwiler

Hexagonal boron nitride (hBN) is a wide bandgap van der Waals material that is emerging as a powerful platform for quantum optics and nanophotonics. In this work, we demonstrate whispering gallery mode silica microresonators hybridized with…

We demonstrate a non-monotonic evolution of thermal conductivity of large-area hexagonal boron nitride films with thickness. Wrinkles and defects/impurities are present in these films. Raman spectroscopy, an optothermal non-contact…

Hexagonal boron nitride (hBN) is a natural hyperbolic material that supports both volume-confined hyperbolic polaritons (HPs) and sidewall-confined hyperbolic surface polaritons (HSPs). In this work, we demonstrate effective excitation,…

Mesoscale and Nanoscale Physics · Physics 2018-05-08 S. Dai , M. Tymchenko , Y. Yang , Q. Ma , M. Pita-Vidal , K. Watanabe , T. Taniguchi , P. Jarillo-Herrero , M. M. Fogler , A. Alù , D. N. Basov

Atomically thin hexagonal boron nitride (h-BN) is often regarded as an elastic film that is impermeable to gases. The high stabilities in thermal and chemical properties allow h-BN to serve as a gas barrier under extreme conditions.In this…

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