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Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity…

Quantum Gases · Physics 2014-03-06 Justyna A. Cwik , Sahinur Reja , Peter B. Littlewood , Jonathan Keeling

A fundamental theoretical framework is formulated for the investigation of rovibronic spectra resulting from the coupling of molecules to one mode of the radiation field in an optical cavity. The approach involves the computation of (1)…

Atomic and Molecular Clusters · Physics 2018-08-15 Tamás Szidarovszky , Attila. G. Császár , Gábor J. Halász , Lorenz S. Cederbaum , Ágnes Vibók

We introduce a theoretical framework that allows for the systematic and efficient description of the ultrafast nonlinear response of molecular polaritons, i.e., hybrid light-matter states, in the collective regime of large numbers of…

Quantum Physics · Physics 2025-05-22 Michael Reitz , Arghadip Koner , Joel Yuen-Zhou

Electronic states in metallic nanoclusters form energy shells and degree of their filling depends on the number of delocalized electrons. In the region close to half-filling the cluster geometry oscillates between the prolate and oblate…

Superconductivity · Physics 2015-06-23 Vladimir Kresin , Yurii Ovchinnikov , Jacques Friedel

The interaction of atomic clusters with short, intense pulses of laser light to form extremely hot, dense plasmas has attracted extensive experimental and theoretical interest. The high density of atoms within the cluster greatly enhances…

Atomic Physics · Physics 2009-11-11 Zachary B. Walters , Robin Santra , Chris H. Greene

In a microcavity, light-matter coupling is quantified by the vacuum Rabi frequency $\Omega_R$. When $\Omega_R$ is larger than radiative and non-radiative loss rates, the system eigenstates (polaritons) are linear superposition of photonic…

The propagation of light in strongly coupled atomic media takes place through the formation of polaritons - hybrid quasi-particles resulting from a superposition of an atomic and a photonic excitation. Here we consider the propagation under…

Quantum Gases · Physics 2020-09-30 Johannes Lang , Darrick E. Chang , Francesco Piazza

Fabry-Perot microcavities can strongly enhance interactions between light and molecules, leading to the formation of hybrid light-matter states known as polaritons. Polaritons possess much smaller effective masses and much larger group…

Chemical Physics · Physics 2023-10-18 Zeyu Zhou , Hsing-Ta Chen , Maxim Sukharev , Joseph E. Subotnik , Abraham Nitzan

We report on collective non-linear dynamics in an optical lattice formed inside a high finesse ring cavity in a so far unexplored regime, where the light shift per photon times the number of trapped atoms exceeds the cavity resonance…

Quantum Physics · Physics 2009-11-10 B. Nagorny , Th. Elsaesser , A. Hemmerich

We demonstrate the effects of cavity quantum electrodynamics for a quantum dot coupled to a photonic molecule, consisting of a pair of coupled photonic crystal cavities. We show anti-crossing between the quantum dot and the two super-modes…

Mesoscale and Nanoscale Physics · Physics 2012-07-30 Arka Majumdar , Armand Rundquist , Michal Bajcsy , Jelena Vučković

Cooling a range of molecules to ultracold temperatures (<1 mK) is a difficult but important challenge in molecular physics and chemistry. Collective cavity cooling of molecules is a promising method that does not rely on molecular energy…

Atomic Physics · Physics 2012-05-11 Guangjiong Dong , Chang Wang , Weiping Zhang

Molecular polaritons are hybrid light-matter states that enable the exploration of potential cavity-modified chemistry. The development of dynamical, first-principles approaches for simulating molecular polaritons is important for…

Chemical Physics · Physics 2025-07-18 Millan F. Welman , Tao E. Li , Sharon Hammes-Schiffer

We demonstrate theoretically and experimentally that the nonlinear interaction between excitations whose harmonic energies coincide gives rise to a strong coupling that opens a new coherent ultrafast energy relaxation path. Instead of an…

Mesoscale and Nanoscale Physics · Physics 2016-05-31 Pierre Gilliot , Bertrand Yuma , Marc Ziegler , Mathieu Gallart , Bernd Hönerlage

There is currently great interest in the strong coupling between the quantized photon field of a cavity and electronic or other degrees of freedom in materials. A major goal is the creation of novel collective states entangling photons with…

Strongly Correlated Electrons · Physics 2019-01-15 Giacomo Mazza , Antoine Georges

The generation and control of entanglement in a quantum mechanical system is a critical element of nearly all quantum applications. Molecular systems are a promising candidate, with numerous degrees of freedom able to be targeted. However,…

Quantum Physics · Physics 2023-07-28 Davis M. Welakuh , Spyros Tserkis , Scott E. Smart , Prineha Narang

Coupling light to ensembles of strongly interacting particles has emerged as a promising route toward achieving few photon nonlinearities. One specific way to implement this kind of nonlinearity is to interface light with highly excited…

Quantum Physics · Physics 2017-10-25 Callum R. Murray , Thomas Pohl

Polaritonic chemistry offers the possibility of modifying molecular properties and even influencing chemical reactivity through strong coupling between vibrational transitions and confined light modes in optical cavities. Despite…

Chemical Physics · Physics 2025-05-16 Thomas Schnappinger , Markus Kowalewski

Excitons in a semiconductor monolayer form a collective resonance that can reflect resonant light with extraordinarily high efficiency. Here, we investigate the nonlinear optical properties of such atomistically thin mirrors and show that…

Mesoscale and Nanoscale Physics · Physics 2022-03-02 Valentin Walther , Lida Zhang , Susanne F. Yelin , Thomas Pohl

Bose condensed light can form new phases [1] in a dye filled cavity due to the presence of the orientational disorder created by dye molecules which are essentially frozen on the time scale of the photonic thermalization (few ps). At longer…

Quantum Gases · Physics 2020-05-06 Victor Fleurov , Anatoly B. Kuklov

Coherent bosonic ensembles offer the promise of harnessing quantum effects in photonic and quantum circuits. In the dynamic equilibrium regime, the application of polariton condensates is hindered by exciton-polariton scattering induced…

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