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In this paper we investigate polynomial interpolation using orthogonal polynomials. We use weight functions associated with orthogonal polynomials to define a weighted form of Lagrange interpolation. We introduce an upper bound of error…

Numerical Analysis · Mathematics 2019-10-23 Maha Youssef , Gerd Baumann

Ubiquitous Van der Waals interactions between atoms and molecules are important for many molecular and solid structures. These systems are often studied from first principles using the Density Functional Theory (DFT). However, the commonly…

Materials Science · Physics 2009-11-13 Pier Luigi Silvestrelli

We extend recent computer-assisted design and analysis techniques for first-order optimization over structured functions--known as performance estimation--to apply to structured sets. We prove "interpolation theorems" for smooth and…

Optimization and Control · Mathematics 2024-11-20 Alan Luner , Benjamin Grimmer

In this paper, we propose a trigonometric-interpolation approach for solutions of second order nonlinear ODEs with mixed boundary conditions. The method interpolates secondary derivative $y''$ of a target solution $y$ by a trigonometric…

Numerical Analysis · Mathematics 2025-04-29 Xiaorong Zou

The accuracy of reaction energy profiles calculated with multi-configurational electronic structure methods and corrected by multi-reference perturbation theory depends crucially on consistent active orbital spaces selected along the…

Chemical Physics · Physics 2023-04-14 Moritz Bensberg , Markus Reiher

The general procedure underlying Hartree-Fock and Kohn-Sham density functional theory calculations consists in optimizing orbitals for a self-consistent solution of the Roothaan-Hall equations in an iterative process. It is often ignored…

Chemical Physics · Physics 2017-03-16 Alain C. Vaucher , Markus Reiher

In this series of eight papers we present the applications of methods from wavelet analysis to polynomial approximations for a number of accelerator physics problems. In this part, according to variational approach we obtain a…

Accelerator Physics · Physics 2007-05-23 Antonina N. Fedorova , Michael G. Zeitlin

The Slater-type orbital basis with non-integer principal quantum numbers is a physically and mathematically motivated choice for molecular electronic structure calculations in both non-relativistic and relativistic theory. The…

Quantum Physics · Physics 2022-03-15 A Bagci , Philip E Hoggan , M Adak

We describe a real-space approach to the calculation of the properties of an insulating crystal in an applied electric field, based on the iterative determination of the Wannier functions (WF's) of the occupied bands. It has been recently…

Condensed Matter · Physics 2009-10-22 R. W. Nunes , David Vanderbilt

We present a formal analysis of nonlinear response functions in terms of correlation functions in real- and imaginary-time domains. In particular, we show that causal nonlinear response functions, expressed in terms of nested commutators in…

Mesoscale and Nanoscale Physics · Physics 2021-07-07 Habib Rostami , Mikhail I. Katsnelson , Giovanni Vignale , Marco Polini

We have developed a computational method to describe the nonlinear light propagation of an intense and ultrashort pulse at oblique incidence on a flat surface. In the method, coupled equations of macroscopic light propagation and…

Optics · Physics 2022-06-29 Mitsuharu Uemoto , Kazuhiro Yabana

The projection of the eigenfunctions obtained in standard plane-wave first-principle electronic-structure calculations into atomic-orbital basis sets is proposed as a formal and practical link between the methods based on plane waves and…

Condensed Matter · Physics 2009-10-28 Daniel Sanchez-Portal , Emilio Artacho , Jose M. Soler

We propose an approach for the ab initio calculation of materials with strong electronic correlations which is based on all local (fully irreducible) vertex corrections beyond the bare Coulomb interaction. It includes the so-called GW and…

Strongly Correlated Electrons · Physics 2015-03-19 A. Toschi , G. Rohringer , A. A. Katanin , K. Held

We present an approach to calculate the optical absorption spectra that combines the quasiparticle self-consistent GW method [Phys. Rev. B, 76 165106 (2007)] for the electronic structure with the solution of the ladder approximation to the…

Materials Science · Physics 2018-03-21 Brian Cunningham , Pooya Azarhoosh , Dimitar Pashov , Myrta Gruening , Mark van Schilfgaarde

We present novel model reduction methods for rapid solution of parametrized nonlinear partial differential equations (PDEs) in real-time or many-query contexts. Our approach combines reduced basis (RB) space for rapidly convergent…

Numerical Analysis · Mathematics 2024-10-04 Ngoc Cuong Nguyen

Wannier functions that are maximally localized help in understanding many properties of crystalline materials. In the absence of topological obstructions, they are at least exponentially localized. In some cases such as flat-band…

Mesoscale and Nanoscale Physics · Physics 2021-07-30 Pratik Sathe , Fenner Harper , Rahul Roy

We define Wannier functions for interacting systems, and show that the results on the localization of the Wannier functions for non-interacting systems carry over to the Wannier functions for interacting systems. In addition we demonstrate…

Strongly Correlated Electrons · Physics 2009-11-07 Erik Koch , Stefan Goedecker

The construction of Wannier functions from Bloch orbitals offers a unitary freedom that can be exploited to yield Wannier functions with advantageous properties. Minimizing the spatial variance is a well-known choice; another, previously…

Materials Science · Physics 2026-04-29 Aaron Mahler , Jacob Z. Williams , Neil Qiang Su , Weitao Yang

In this paper, we first apply the Fitzpatrick algorithm to osculatory rational interpolation. Then based on Fitzpatrick algorithm, we present a Neville-like algorithm for Cauchy interpolation. With this algorithm, we can determine the value…

Numerical Analysis · Mathematics 2011-03-17 Peng Xia , Shugong Zhang , Na Lei

We introduce a new numerical method for the computation of the inverse nonlinear Fourier transform and compare its computational complexity and accuracy to those of other methods available in the literature. For a given accuracy, the…

Numerical Analysis · Mathematics 2015-11-26 Stella Civelli , Luigi Barletti , Marco Secondini