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Capacitive Deionization (CDI) is a non-energy intensive water treatment technology. To harness the enormous potential of CDI requires improving performance, while offering industrially feasible solutions. Following this idea, the…

Capacitive deionization (CDI) is a fast-emerging water desalination technology in which a small cell voltage of ~1 V across porous carbon electrodes removes salt from feedwaters via electrosorption. In flow-through electrode (FTE) CDI cell…

Computational Engineering, Finance, and Science · Computer Science 2017-02-01 Eric N. Guyes , Amit N. Shocron , Anastasia Simanovski , P. M. Biesheuvel , Matthew E. Suss

In the growing field of capacitive deionization (CDI), a number of performance metrics have emerged to describe the desalination process. Unfortunately, the separation conditions under which these metrics are measured are often not…

Many industrial and agricultural applications require the treatment of water streams containing high concentrations of ionic species for closing material cycles. High concentration factors are often desired, but hard to achieve with…

Over the past decade, capacitive deionization (CDI) has realized a surge in attention in the field of water desalination and can now be considered as an important technology class, along with reverse osmosis and electrodialysis. While many…

Faradaic deionization (FDI) is a promising technology for energy-efficient water desalination using porous electrodes containing redox-active materials. Herein, we demonstrate for the first time the capability of a symmetric FDI flow cell…

Chemical Physics · Physics 2023-06-09 Vu Q. Do , Erik R. Reale , Irwin C. Loud , Paul G. Rozzi , Haosen Tan , David A. Willis , Kyle C. Smith

Several harmful or valuable ionic species present in sea, brackish and wastewaters are amphoteric, and thus their properties depend on the local water pH. Effective removal of these species can be challenging by conventional membrane…

Capacitive deionization (CDI) is a fast-emerging technology most commonly applied to brackish water desalination. In CDI, salt ions are removed from the feedwater and stored in electric double layers (EDLs) within micropores of electrically…

Chemical Physics · Physics 2017-10-11 Matthew E. Suss

In this paper, we propose the Coupled Axial and Transverse currents (I) (CATI) method, as an efficient and accurate finite element approach for modelling the electric and magnetic behavior of periodic composite superconducting conductors.…

Accelerator Physics · Physics 2024-06-25 Julien Dular , Fredrik Magnus , Erik Schnaubelt , Arjan Verweij , Mariusz Wozniak

A two-scale model is presented to simulate the dynamic ion transport and adsorption processes in porous electrodes used for capacitive deionization (CDI). At the pore scale, the Stokes equation governing water flow in porous CDI electrodes…

Fluid Dynamics · Physics 2022-01-14 Min Liu , John Waugh , Siddharth Komini Babu , Jacob S. Spendelow , Qinjun Kang

We perform a combined experimental and theoretical investigation of the orientational dynamics of rod-like colloidal particles in dilute suspension as they are subjected to a time-dependent homogeneous planar elongational flow. Our…

We present porous electrode theory for capacitive deionization (CDI) with electrodes containing nanoparticles that consist of a redox-active intercalation material. A geometry of a desalination cell is considered which consists of two…

Chemical Physics · Physics 2019-12-24 K. Singh , H. J. M. Bouwmeester , L. C. P. M de Smet , M. Z. Bazant , P. M. Biesheuvel

An efficient, iterative semi-implicit (SI) numerical method for the time integration of stiff wave systems is presented. Physics-based assumptions are used to derive a convergent iterative formulation of the SI scheme which enables the…

Computational Physics · Physics 2008-07-02 N. F. Loureiro , G. W. Hammett

Water desalination by capacitive deionization (CDI) is performed via electrochemical cells consisting of two porous carbon electrodes. Upon transferring charge from one electrode to the other, ions are removed from the feedwater by…

Materials Science · Physics 2015-06-15 P. M. Biesheuvel , M. E. Suss , H. V. M. Hamelers

Electrochemical desalination devices that use redox-active cation intercalation electrodes show promise for desalination of salt-rich water resources with high water recovery and low energy consumption. While previous modeling and…

Applied Physics · Physics 2018-04-02 Sizhe Liu , Kyle C. Smith

Capacitive deionization (CDI) is a technology in which water is desalinated by ion electrosorption into the electric double layers (EDLs) of charging porous electrodes. In recent years significant advances have been made in modeling the…

Chemical Physics · Physics 2017-02-01 Amit N. Shocron , Matthew E. Suss

The need for a high-performance transceiver with high Signal to Noise Ratio (SNR) has driven the communication system to utilize the latest technique identified as oversampling systems. It was the most economical modulator and decimation in…

Signal Processing · Electrical Eng. & Systems 2018-07-30 Rozita Teymourzadeh , Yazan Samir Algnabi , Masuri Othman , Md Shabiul Islam , Mok Vee Hong

The cross-spectral density (CSD) of the non-linear forcing in resolvent analyses is here quantified for the first time for turbulent channel flows. Direct numerical simulations (DNS) at $Re_{\tau} =179$ and $Re_{\tau} =543$ are performed.…

Four different applications of spectral proper orthogonal decomposition (SPOD): low-rank reconstruction, denoising, frequency-time analysis, and prewhitening are demonstrated on large-eddy simulation data of a turbulent jet. SPOD-based…

Fluid Dynamics · Physics 2021-09-22 Akhil Nekkanti , Oliver T. Schmidt

We present a simple, top-down approach for the calculation of minimum energy consumption of electrosorptive ion separation using variational form of the (Gibbs) free energy. We focus and expand on the case of electrostatic capacitive…

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