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We study ground states of a hybrid system consisting of a polymer and an attractive nanowire by means of computer simulations. Depending on structural and energetic properties of the substrate, we find different adsorbed polymer…

Soft Condensed Matter · Physics 2011-03-10 Thomas Vogel , Michael Bachmann

Spherical particles confined to a sphere surface cannot pack densely into a hexagonal lattice without defects. In this study, we use hard particle Monte Carlo simulations to determine the effects of continuously deformable shape anisotropy…

Soft Condensed Matter · Physics 2026-01-01 Gabrielle N. Jones , Philipp W. A. Schönhöfer , Sharon C. Glotzer

Field-theoretical method is efficient in predicting the assembling structures of polymeric systems. However, for the polymer/nanoparticle mixture, the continuous density description is not suitable to capture the realistic assembly of…

Soft Condensed Matter · Physics 2017-05-17 Hui-shu Li , Bo-kai Zhang , Jian Li , Wen-de Tian , Kang Chen

The design of amorphous entangled systems, specifically from soft and active materials, has the potential to open exciting new classes of active, shape-shifting, and task-capable 'smart' materials. However, the global emergent mechanics…

Soft Condensed Matter · Physics 2022-07-11 William Savoie , Harry Tuazon , M. Saad Bhamla , Daniel I. Goldman

Simulations and experiments of nanorods (NRs) show that co-assembly with block copolymer (BCP) melts leads to the formation of a superstructure of side-to-side NRs perpendicular to the lamellar axis. A mesoscopic model is validated against…

Soft Condensed Matter · Physics 2020-04-14 Javier Diaz , Marco Pinna , Andrei V. Zvelindovsky , Ignacio Pagonabarraga , Roy Shenhar

Within a closed system, physical interactions are reciprocal. However, the effective interaction between two entities of an open system may not obey reciprocity. Here, we describe a non-reciprocal interaction between nanoparticles which is…

Optics · Physics 2024-02-02 Amir M. Jazayeri , Sohila Abdelhafiz , Aristide Dogariu

We consider a theoretical model for a binary mixture of colloidal particles and spherical emulsion droplets. The hard sphere colloids interact via additional short-ranged attraction and long-ranged repulsion. The droplet-colloid interaction…

Soft Condensed Matter · Physics 2012-01-11 Ingmar Schwarz , Andrea Fortini , Claudia Simone Wagner , Alexander Wittemann , Matthias Schmidt

Recent work [1] demonstrated high coercivity and magnetic moment in cobalt carbide nanoparticle assemblies and explained the high coercivity from first principles in terms of the high magnetocrystalline anisotropy of the cobalt carbide…

Mesoscale and Nanoscale Physics · Physics 2018-09-26 Pallabi Sutradhar , Shiv N. Khanna , Jayasimha Atulasimha

The self-assembly of copolymeric vesicles and micelles in micromixers is studied by External Potential Dynamics (EPD) simulations -- a dynamic density functional approach that explicitly accounts for the polymer architecture both at the…

Soft Condensed Matter · Physics 2018-04-10 Simon Kessler , Klaus Drese , Friederike Schmid

This article reports dependence of exchange bias (EB) effect on interparticle interactions in nanocrystalline Co/CoO core/shell structures, synthesized using conventional sol-gel technique. Analysis via powder X-Ray diffraction (PXRD)…

The equilibrium properties of block copolymer micelles confined in polymer thin films are investigated using self-consistent field theory. The theory is based on a model system consisting of AB diblock copolymers and A homopolymers. Two…

Soft Condensed Matter · Physics 2014-01-16 Jiajia Zhou , An-Chang Shi

We demonstrate that nascent polymer crystals (i.e., nuclei) are anisotropic entities, with neither spherical nor cylindrical geometry, in contrast to previous assumptions. In fact, cylindrical, spherical, and other high symmetry geometries…

Soft Condensed Matter · Physics 2020-01-08 Kyle Wm. Hall , Timothy W. Sirk , Simona Percec , Michael L. Klein , Wataru Shinoda

We report on the formation and the structural properties of supermicellar aggregates also called electrostatic complexes, made from mineral nanoparticles and polyelectrolyte-neutral block copolymers in aqueous solutions. The mineral…

Soft Condensed Matter · Physics 2007-09-10 Jean-Francois Berret , Kazuhiko Yokota , Mikel Morvan , Ralf Schweins

The magnetic response of nanostructures plays an important role on biomedical applications being strongly influenced by the magnetic anisotropy. In this work we investigate the role of temperature, particle concentration and nanoparticle…

Applied Physics · Physics 2019-02-20 V. R. R. Aquino , L. C. Figueiredo , J. A. H. Coaquira , M. H. Sousa , A. F. Bakuzis

Understanding and controlling self-assembly processes at multiple length scales is vital if we are to design and create advanced materials. In particular, our ability to organise matter on the nanoscale has advanced considerably, but still…

Soft Condensed Matter · Physics 2019-11-28 Zan Hua , Joseph R Jones , Marjolaine Thomas , Maria C Arno , Anton Souslov , Thomas R Wilks , Rachel K O'Reilly

The ability to tune the degree of interaction among particles at the nanoscale is highly intriguing. The spectroscopic signature of such interaction is often subtle and requires special probes to observe. To this end, inter-layer excitons…

We present a systematic investigation of static and dynamic properties of block copolymer micelles with crosslinked cores, representing model polymer-grafted nanoparticles, over a wide concentration range from dilute regime to an arrested…

We present a systematic investigation of static and dynamic properties of block copolymer micelles with crosslinked cores, representing model polymer-grafted nanoparticles, over a wide concentration range from dilute regime to an arrested…

Introducing nanorods into a polymeric matrix can enhance the physical and mechanical properties of the resulting material. In this paper, we focus on understanding the dispersion and orientation patterns of nanorods in an unentangled…

Soft Condensed Matter · Physics 2023-04-05 Navid Afrasiabian , Venkat Balasubramanian , Colin Denniston

In this article, the Curie-Weiss type behavior and the appearance of an "interaction" or "ordering" temperature for a collection of magnetic nanoparticles is explored theoretically. We show that some systems where an interaction temperature…

Materials Science · Physics 2024-10-25 Robert E Camley , Rair Macêdo , Karen L Livesey