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We demonstrate the potential of perylene bisimide (PBI) for label-free sensing of organic molecules by investigating the change in electronic properties of five symmetric and asymmetric PBI derivatives, which share a common backbone, but…

Mesoscale and Nanoscale Physics · Physics 2015-01-22 Qusiy Al-Galiby , Iain Grace , Hatef Sadeghi , Colin J. Lambert

Perylene bisimides (PBIs) are organic dyes with photoluminescence quantum yields (PLQY) close to unity in solution and great thermal and photo-chemical stability. These features alongside the tunability of their solid-state packing…

Electric force microscopy was used to record the light-dependent impedance spectrum and the probe transient photoconductivity of a film of butylammonium lead iodide, BA$_{2}$PbI$_{4}$, a 2D Ruddlesden--Popper perovskite semiconductor. The…

Mesoscale and Nanoscale Physics · Physics 2020-06-02 Ali Moeed Tirmzi , Ryan P. Dwyer , Fangyuan Jiang , John A. Marohn

Exciton plasmon polaritons have gained increasing interests over recent years due to their versatile properties emerging by the underlying light-matter coupling and making them potential candidates for new photonic applications. We have…

A new type of detector for positron-emission tomography (PET) has been proposed recently, using a heavy organo-metallic liquid - TriMethyl Bismuth (TMBi) - as target material. TMBi is a transparent liquid with the high Z element Bismuth…

Instrumentation and Detectors · Physics 2023-01-12 S. Peters , B. Gerke , V. Hannen , C. Huhmann , N. Marquardt , K. Schäfers , D. Yvon , V. Sharyy , C. Weinheimer

Van der Waals heterostructures of 2D layered materials have gained much attention due to their flexible electronic properties, which make them promising candidates for energy, sensing, catalytic, and biomedical applications. Lead iodide…

We show that adding ethylenediamine (EDA) to perovskite precursor solution improves the photovoltaic device performance and material stability of high-bromide-content, methylammonium-free, formamidinium cesium lead halide perovskites…

Photoelectron spectra of aromatic anhydrides and imides like PTCDA (perylene-tetracarboxylic dianhydride), PTCDI (perylene-tetracarboxylic diimide), and NDCA (naphthalene-dicarboxylic anhydride) on smooth single crystal surfaces show…

Materials Science · Physics 2007-05-23 M. Jung , U. Baston , T. Porwol , H. -J. Freund , E. Umbach

The systematic trends in structural and electronic properties of perylene diimide (PDI) derived dye molecules have been investigated by DFT calculations based on projector augmented wave (PAW) method including gradient corrected…

Materials Science · Physics 2008-01-15 E. Mete , D. Uner , M. Cakmak , O. Gulseren , S. Ellialtioglu

Small molecule organic semiconductors hold great promise for efficient, printable, and flexible optoelectronic applications like solar cells and displays. However, strong excited-state quenching due to uncontrolled aggregation currently…

A series of donor-acceptor-donor (D-A-D) structured small-molecule compounds, with 3,3'-(ethane-1,2-diylidene)bis(indolin-2-one) (EBI) as a novel electron acceptor building block coupled with various electron donor end-capping moieties…

Materials Science · Physics 2017-06-27 Mylene Le Borgne , Jesse Quinn , Jaime Martín , Natalie Stingelin , Yuning Li , Guillaume Wantz

Owing to the versatility in their chemical and physical properties, transition metal perovskite oxides have emerged as a new category of highly efficient photocatalysts for photoelectrochemical water splitting. Here, to understand the…

In this paper we analyze the band-structure of two-dimensional (2D) halide perovskites by considering structures related to the simpler case of the series, (BA)$_2$PbI$_4$, in which PbI$_4$ layers are intercalated with butylammonium…

Materials Science · Physics 2023-07-24 Efstratios Manousakis

Metal halide perovskites (MHPs) are low-temperature processable hybrid semiconductor materials with exceptional performances that are revolutionizing the field of optoelectronic devices. Despite their great potential, commercial deployment…

A new approach for fabricating open and closed porous structures based on laser processing is presented. Liquid polyimide (PI) was mixed with azodicarbonamide (ADC, ADA) which is a chemical blowing agent (CBA) and mixture was pre-cured in…

Instrumentation and Detectors · Physics 2016-09-21 Yong-Won Ma , Jae Yong Oh , Seokyoung Ahn , Bo Sung Shin

Phenyl-disubstituted polyacetylene (PDPA) is an organic semiconductor which has been studied during the last years for its efficient photo-luminescence. In contrast, the molecular geometry, providing the basis for the electronic and optical…

Materials Science · Physics 2010-08-02 Priya Sony , Alok Shukla , Claudia Ambrosch-Draxl

Using all-atom molecular dynamics simulations, we report the structure and ion transport characteristics of a new class of solid polymer electrolytes that contain biodegradable and mechanically stable biopolymer pectin. We simulate a highly…

Electron transfer (ET) in molecular donor-acceptor dye systems is crucial for charge transport in organic semiconductors. Classically, ET rates should decrease with increasing donor-acceptor distance while the microscopic mechanism is more…

Following the identification of the pi bond in graphene, in this work, a pi bond constructed through side-to-side overlap of half-filled 6pz orbitals was observed in a non-carbon crystal of Pb1-xSnxSe (x=0.34) (PSS), a prototype topological…

Materials Science · Physics 2015-06-24 G. J. Shu , S. C. Liou , S. Karna , R. Sankar , M. Hayashi , M. -W. Chu , F. C. Chou

Peptide surfactants (PEPS) are studied to capture and retain rare earth elements (REEs) at air-water interfaces to enable REE separations. Peptide sequences, designed to selectively bind REEs, depend crucially on the position of ligands…

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