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A liquid volume containing dissolved solutes moves through a charged nanofluidic channel under the influence of the concentration gradient of the solutes, non-trivially modulated by the electrostatic interaction between ionic liquid and…

Fluid Dynamics · Physics 2023-08-31 Pranab Kumar Mondal

We use computer simulations to study the kinetics and mechanism of proton passage through a narrow-pore carbon-nanotube membrane separating reservoirs of liquid water. Free energy and rate constant calculations show that protons move across…

Soft Condensed Matter · Physics 2009-11-11 Christoph Dellago , Gerhard Hummer

We derive a mathematical model of a nematic electrolyte based on the Leslie-Ericksen theory of liquid crystal flow. Our goal is to investigate the nonlinear electrokinetic effects that occur because the nematic matrix is anisotropic, in…

Soft Condensed Matter · Physics 2016-06-07 M. Carme Calderer , Dmitry Golovaty , Oleg Lavrentovich , Noel J. Walkington

Recent experimental work has suggested that electroosmotic flows (EOF) through conical nanopores exhibit rectification in the opposite sense to the well-studied effect of ionic current rectification. A positive bias voltage generates large…

Fluid Dynamics · Physics 2015-06-02 Nadanai Laohakunakorn , Ulrich F. Keyser

Ion transport in porous media is present in a wealth of technologies, e.g., energy storage devices such as batteries and supercapacitors, and environmental technologies such as electrochemical carbon capture and capacitive deionization.…

Soft Condensed Matter · Physics 2022-06-17 Filipe Henrique , Pawel J. Zuk , Ankur Gupta

Advent of nematic liquid crystals flows have attracted renewed attention in view of microfluidic transport phenomena. Among various transport processes, electroosmosis stands as one of the efficient flow actuation method through narrow…

Fluid Dynamics · Physics 2017-08-02 Antarip Poddar , Jayabrata Dhar , Suman Chakraborty

As an important property of porous membranes, the surface charge property determines many ionic behaviors of nanopores, such as ionic conductance and selectivity. Based on the dependence of electric double layers on bulk concentrations,…

Chemical Physics · Physics 2024-02-08 Jiakun Zhuang , Long Ma , Yinghua Qiu

The comprehensive depiction of the many-body effects governing nanoconfined electrolytes is an essential step for the conception of nanofluidic devices with optimized performance. By incorporating self-consistently multivalent charges into…

Soft Condensed Matter · Physics 2020-12-14 Sahin Buyukdagli

Electrokinetic transport phenomena can strongly influence the behaviour of macromolecules and colloidal particles in solution, with applications in, e.g., DNA translocation through nanopores, electro-osmotic flow in nanocapillaries, and…

Soft Condensed Matter · Physics 2016-08-03 Georg Rempfer , Gary B. Davies , Christian Holm , Joost de Graaf

We present theory for ion and water transport through reverse osmosis membranes based on a Maxwell-Stefan framework combined with hydrodynamic theory for the reduced motion of particles in thin pores. We include all driving forces and…

Chemical Physics · Physics 2018-03-07 Y. S. Oren , P. M. Biesheuvel

We perform experimental investigations of osmotically driven flows in artificial microchannels by studying the dynamics and structure of the front of a sugar solution traveling in 200 um wide and 50-200 um deep microchannels. We find that…

Fluid Dynamics · Physics 2008-10-29 Kaare Hartvig Jensen , Jinkee Lee , Tomas Bohr , Henrik Bruus

Electrophoresis is a motion of charged dispersed particles relative to a fluid in a uniform electric field. The effect is widely used to separate macromolecules, to assemble colloidal structures, to transport particles in nano- and…

Soft Condensed Matter · Physics 2011-01-21 Oleg D. Lavrentovich , Israel Lazo , Oleg P. Pishnyak

Electrolyte-filled channels with modulated wall charge distribution subjected to an applied DC electric field, form time-independent vortices whose sense of circulation is determined by the field direction [Physical Review Letters $…

Fluid Dynamics · Physics 2026-02-02 A. Shrestha , E. Kirkinis , M. Olvera de la Cruz

In this paper, we introduce a mathematical model to describe the nanoparticles transport carried by a two-phase flow in a porous medium including gravity, capillary forces and Brownian diffusion. Nonlinear iterative IMPES scheme is used to…

Numerical Analysis · Mathematics 2013-10-18 M. F. El-Amin , Jisheng Kou , Shuyu Sun , Amgad Salama

Polymer translocation experiments typically involve anionic polyelectrolytes such as DNA molecules driven through negatively charged nanopores. Quantitative modelling of polymer capture to the nanopore followed by translocation therefore…

Soft Condensed Matter · Physics 2017-10-11 Sahin Buyukdagli , Tapio Ala-Nissila

We theoretically study transient electroosmotic flow of general Maxwell fluids through polyelectrolyte grafted nanochannel with a layered distribution of charges. By applying the method of Laplace transform, we semi-analytically obtain…

Soft Condensed Matter · Physics 2023-09-08 Jun-Sik Sin , Nam-Il Ri , Hyon-Chol Kim , Sin-Hyok Hyon

A nonlinear kinetic exclusion model is used to study osmosis and pressure driven flows through nearly single file pores such as antibiotic channels, aquaporins, zeolites and nanotubules. Two possible maxima in the steady state flux as a…

Soft Condensed Matter · Physics 2007-05-23 Tom Chou

Assuming a vacancy-mediated diffusion, a continuum model for electromigration-driven transport of an embedded atom cluster across a surface terrace of a phase-separating A$_x$B$_{1-x}$ surface alloy, such as fcc AgPt(111), is presented.…

Materials Science · Physics 2021-06-10 Mikhail Khenner

A stochastic approach for charge transport in diodes is developed in consistency with the laws of electricity, thermodynamics, and microreversibility. In this approach, the electron and hole densities are ruled by diffusion-reaction…

Statistical Mechanics · Physics 2018-06-06 Jiayin Gu , Pierre Gaspard

Recently, asymmetric plasmonic nanojunctions [Karnetzky et. al., Nature Comm. 2471, 9 (2018)] have shown promise as on-chip electronic devices to convert femtosecond optical pulses to current bursts, with a bandwidth of multi-terahertz…

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