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Spin crossover (SCO) molecules are promising bi-stable magnetic switches with applications in molecular spintronics. However, little is known about the switching effects of a single SCO molecule when it is confined between two metal…

Mesoscale and Nanoscale Physics · Physics 2020-06-12 Alex Gee , Ayoub H. Jaafar , Barbora Brachňaková , Jamie Massey , Christopher H. Marrows , Ivan Šalitroš , N. T. Kemp

Spin crossover (SCO) complexes are highly flexible bistable molecular switches with two distinct spin states that can be switched into each other by external stimuli such as temperature, pressure, or light. In the condensed phase, this spin…

Realization of spin crossover (SCO) based applications requires studying of spin state switching characteristics of SCO complex molecules at nanostructured environments especially on-surface. Except for a very few cases, the SCO of a…

Spin crossover (SCO) complexes are highly promising candidates for a myriad of potential applications in room-temperature electronics; however, as it stands, establishing a clear connection between their spin-state switching and transport…

Materials Science · Physics 2025-07-18 Archit Dhingra , M. Zaid Zaz

The ability to control and understand the phase transitions of individual nanoscale building blocks is key to advancing the next generation of low-power reconfigurable nanophotonic devices. To address this critical challenge, molecular…

The ability to make electrical contact to single molecules creates opportunities to examine fundamental processes governing electron flow on the smallest possible length scales. We report experiments in which we controllably stretch…

Despite a clear demonstration of bistability in spin-crossover (SCO) materials, the absence of long-range magnetic order and poor electrical conductivity limit their prospect in spintronic and nanoelectronic applications. Intending to…

We analyze the electronic transport through a model spin-1 molecule as a function of temperature, magnetic field and bias voltage. We consider the effect of magnetic anisotropy, which can be generated experimentally by stretching the…

Strongly Correlated Electrons · Physics 2011-06-24 P. S. Cornaglia , P. Roura Bas , A. A. Aligia , C. A. Balseiro

We study the switching behavior of two spin-crossover molecules residing in a nanojunction device consisting of two closely spaced gold electrodes. The spin states are monitored through a real-time measurement of the resistance of the…

Mesoscale and Nanoscale Physics · Physics 2021-09-29 Philipp Stegmann , Alex Gee , Neil T. Kemp , Jürgen König

One promising route toward encoding information is to utilize the two stable electronic states of a spin crossover molecule. However, while this property is clearly manifested in transport across single molecule junctions, evidence linking…

Molecular spin crossover switches are the objects of intense theoretical and experimental studies in recent years. This interest is due to the fact that these systems allow one to control their spin state by applying an external photo-,…

Mesoscale and Nanoscale Physics · Physics 2016-02-17 Oleg V. Farberovich , Victoria L. Mazalova , Valeri S. Stepanyuk

The electronic origin of a large resistance change in nanoscale junctions incorporating spin crossover molecules is demonstrated theoretically by using a combination of density functional theory and the non-equilibrium Green's functions…

Mesoscale and Nanoscale Physics · Physics 2012-06-01 N. Baadji , S. Sanvito

Precise control of spin states and spin-spin interactions in atomic-scale magnetic structures is crucial for spin-based quantum technologies. A promising architecture is molecular spin systems, which offer chemical tunability and…

We use the electrode-less time-resolved microwave conductivity (TRMC) technique to characterize spin-crossover (SCO) nanoparticles. We show that TRMC is a simple and accurate mean for simultaneously as-sessing the magnetic state of SCO…

Controlling electronic transport through a single-molecule junction is crucial for molecular electronics or spintronics. In magnetic molecular devices, the spin degree-of-freedom can be used to this end since the magnetic properties of the…

Spin crossover molecules have recently emerged as a family of compounds potentially useful for implementing molecular spintronics devices. The calculations of the electronic properties of such molecules is a formidable theoretical challenge…

Materials Science · Physics 2015-06-04 Andrea Droghetti , Dario Alfe' , Stefano Sanvito

Controlling the spin transport at the single-molecule level, especially without the use of ferromagnetic contacts, becomes a focus of research in spintronics. Inspired by the progress on atomic-level molecular synthesis, through…

Atomic and Molecular Clusters · Physics 2022-11-17 Yan-Dong Guo , Xue Zhao , Hong-Ru Zhao , Li Yang , Li-Yan Lin , Yue Jiang , Dan Ma , Yu-Ting Chen , Xiao-Hong Yan

We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation…

Mesoscale and Nanoscale Physics · Physics 2010-11-16 Youngsang Kim , Hyunwook Song , Florian Strigl , Hans-Fridtjof Pernau , Takhee Lee , Elke Scheer

Individual magnetic molecules are promising building blocks for quantum technologies because of their chemical tunability, nanoscale dimensions, and ability to self-assemble into ordered arrays. However, harnessing their properties in…

The appealing feature of molecular electronics is the possibility of exploiting functionality built within a single molecule. This functionality can be employed, for example, for sensing or switching purposes. Thus, ideally, the associated…

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