Related papers: Computing the linear viscoelastic properties of so…
We develop and validate a simulation framework for colloidal gelation. We first reproduce the benchmark results of Santos, Campanella, and Carignano for spherical, gel-forming particles, then extend the methodology to more complex systems…
Colloidal gels are out of equilibrium soft solids composed of attractive Brownian particles that form a space-spanning network at low volume fractions. The elastic properties of these systems result from the network microstructure, which is…
Colloidal gels assembled from nanoparticles (NPs) are a versatile class of soft network-based materials capable of rich dynamic, mechanical, and even optical or magnetic responses to stimuli. Understanding how their hierarchically organized…
Soft particulate gels include materials we can eat, squeeze, or 3D print. From foods to bio-inks to cement hydrates, these gels are composed of a small amount of particulate matter (proteins, polymers, colloidal particles, or agglomerates…
Thermoresponsive microgels are polymeric colloidal networks that can change their size in response to a temperature variation. This peculiar feature is driven by the nature of the solvent-polymer interactions, which triggers the so-called…
We report on the response of a yield stress material, namely a colloidal gel made of attractive carbon black particles, submitted to large amplitude oscillatory shear stress (LAOStress). At a constant stress amplitude well below its…
Nearly all dense suspensions undergo dramatic and abrupt thickening transitions in their flow behaviour when sheared at high stresses. Such transitions occur when the dominant interactions between the suspended particles shift from…
Soft particles display highly versatile properties with respect to hard colloids, even more so at fluid-fluid interfaces. In particular, microgels, consisting of a cross-linked polymer network, are able to deform and flatten upon adsorption…
Simple homogeneous shear flows of frictionless, deformable particles are studied by particle simulations at large shear rates and for differently soft, deformable particles. The particle stiffness sets a time-scale that can be used to scale…
Recent interest in structure solution and refinement using electron diffraction (ED) has been fuelled by its inherent advantages when applied to crystals of sub-micron size, as well as a better sensitivity to light elements. Currently, data…
Passive microrheology typically deduces shear elastic loss and storage moduli from displacement time series or mean-squared displacement (MSD) of thermally fluctuating probe particles in equilibrium materials. Common data analysis methods…
We investigate the molecular origin of shear-thinning in melts of flexible, semiflexible and rigid oligomers with coarse-grained simulations of a sheared melt. Alignment, stretching and tumbling modes or suppression of the latter all…
We study the microrheology of nanoparticle shells [Dinsmore et al. Science 298, 1006 (2002)] and viral capsids [Ivanovska et al. PNAS 101, 7600 (2004)] by computing the mechanical response function and thermal fluctuation spectrum of a…
We study the electrokinetic flow of viscoelastic fluids subjected to an oscillatory pressure gradient, and particularly focus on the resonance behaviors in the flow. The governing equations are restricted to linear regime so that the…
This is an integrated experimental and theoretical study of the dynamics and rheology of self-crosslinked, slightly charged, temperature responsive soft Poly(N-isopropylacrylamide) (pNIPAM) microgels over a wide range of concentration and…
Robust empirical constitutive laws for granular materials in air or in a viscous fluid have been expressed in terms of timescales based on the dynamics of a single particle. However, some behaviours such as viscosity bifurcation or shear…
An important class of fluid-structure problems involve the dynamics of ordered arrays of immersed, flexible fibers. While specialized numerical methods have been developed to study fluid-fiber systems, they become infeasible when there are…
Waveform relaxation (WR) methods are based on partitioning large circuits into sub-circuits which then are solved separately for multiple time steps in so-called time windows, and an iteration is used to converge to the global circuit…
In this paper, we present a computational framework based on fully Eulerian models for fluid-structure interaction for the numerical simulation of biological capsules. The flexibility of such models, given by the Eulerian treatment of the…
We use large scale computer simulations and finite size scaling analysis to study the shear rheology of dense three-dimensional suspensions of frictionless non-Brownian particles in the vicinity of the jamming transition. We perform…