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Because they may provide ultrathin, high-flux, and energy-efficient membranes for precise ionic and molecular sieving in aqueous solution, GO membranes (partially oxidized, stacked sheets of graphene) have shown great potential in water…

Graphene-based membranes have been investigated as promising candidates for water filtration and gas separation applications. Experimental evidences have shown that graphene oxide can be impermeable to liquids, vapors and gases, while…

Materials Science · Physics 2017-02-02 Daiane D. Borges , Cristiano F. Woellner , Pedro A. S. Autreto , Douglas S. Galvao

Graphene oxide (GO) membranes continue to attract intense interest due to their unique molecular sieving properties combined with fast permeation rates. However, the membranes' use has been limited mostly to aqueous solutions because GO…

Ultrahigh water permeance, together with a high rejection rate through nanofiltration and separation membranes1,2, is crucial but still challenging for multivalent ion sieving in water treatment processes of desalination, separation, and…

Water transport through graphene-derived membranes has gained much interest recently due to its promising potential in filtration and separation applications. In this work, we explore water permeation in graphene oxide membranes using…

Mesoscale and Nanoscale Physics · Physics 2014-06-05 Ning Wei , Xinsheng Peng , Zhiping Xu

Membranes are ubiquitous in nature with primary functions that include adaptive filtering and selective transport of chemical and molecular species. Being critical to cellular functions, they are also fundamental in many areas of science…

Reverse electrodialysis is a promising method to harvest the osmotic energy stored between seawater and freshwater, but it has been a long-standing challenge to fabricate permselective membranes with the power density surpassing the…

Applied Physics · Physics 2019-12-09 Zhenkun Zhang , Wenhao Shen , Lingxin Lin , Mao Wang , Ning Li , Zhifeng Zheng , Feng Liu , Liuxuan Cao

Experimental evidences have shown that graphene oxide (GO) can be impermeable to liquids, vapors and gases, while it allows a fast permeation of water molecules. The understanding of filtration mechanisms came mostly from studies dedicated…

Mesoscale and Nanoscale Physics · Physics 2017-06-21 Daiane Damasceno Borges , Cristiano F. Woellner , Pedro A. S. Autreto , Douglas S. Galvao

Active research in nanotechnology contemplates the use of nanomaterials for engineering applications. However, a primary challenge is understanding the effects of nanomaterial properties on industrial device performance and translating…

Permeation through nanometer pores is important in the design of materials for filtration and separation techniques and because of unusual fundamental behavior arising at the molecular scale. We found that submicron-thick membranes made…

Materials Science · Physics 2012-01-30 R. R. Nair , H. A. Wu , P. N. Jayaram , I. V. Grigorieva , A. K. Geim

The layers of graphene oxide (GO) are found to be good for permeation of water but not for helium (Science 2012 335 (6067): 442-444) suggesting that the GO layers are dynamic in the formation of permeation route depending on the environment…

Mesoscale and Nanoscale Physics · Physics 2015-10-01 Nallani Raghav , Sudip Chakraborty , Prabal K. Maiti

The data by Q.Yang et al suggest absence of "ultrafast flow" of solvent across graphene oxide (GO) membranes. The "ultrafast flow" is result of using unrealistic geometrical model with close packed hole-free micrometer sized GO flakes…

Applied Physics · Physics 2018-12-11 Alexandr Talyzin

Water inside the low dimensional carbon structures has been considered seriously owing to fundamental interest in its flow and structures as well as its practical impact. Recently, the anomalous perfect penetration of water through graphene…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Danil W. Boukhvalov , Mikhail I. Katsnelson , Young-Woo Son

Carbon nanomaterials such as carbon nanotubes and graphene have proved to be efficient building blocks for active optoelectronic devices. Especially, the exotic properties of crystalline graphene, such as a linear/gapless energy dispersion,…

There has been intense interest in filtration and separation properties of graphene-based materials that can have well-defined nanometer pores and exhibit low frictional water flow inside them. Here we investigate molecular permeation…

Materials Science · Physics 2014-02-18 R. K. Joshi , P. Carbone , F. C. Wang , V. G. Kravets , Y. Su , I. V. Grigorieva , H. A. Wu , A. K. Geim , R. R. Nair

Separation of salt ions from seawater using graphene oxide (GO) membrane is an emerging desalination method. Here, we investigate the dynamic behavior of water, sodium, and chloride ions inside GO membrane using a computational approach.…

Chemical Physics · Physics 2021-08-25 One-Sun Lee

We investigate diffusion of a peptide drug through Graphene Oxide (GO) membranes that are modeled as a porous layered laminate constructed from aligned flakes of GO. Our experiments using a peptide drug show a tunable non-linear dependence…

Materials Science · Physics 2015-12-29 T. M. Puvirajesinghe , Z. L. Zhi , R. V. Craster , S. Guenneau

The understanding of water transport in graphene oxide (GO) membranes stands out as a major theoretical problem in graphene research. Notwithstanding the intense efforts devoted to the subject in the recent years, a consolidated picture of…

Mesoscale and Nanoscale Physics · Physics 2017-03-08 A. Montessori , C. A. Amadei , G. Falcucci , M. Sega , C. D. Vecitis , S. Succi

Due to its ultrahigh electron transmissivity in a wide electron energy range, molecular impermeability, high electrical conductivity and excellent mechanical stiffness the suspended graphene membranes appear to be a nearly ideal window…

Materials Science · Physics 2015-06-11 Joshua D. Stoll , Andrei Kolmakov

Isolated, atomically thin conducting membranes of graphite, called graphene, have recently been the subject of intense research with the hope that practical applications in fields ranging from electronics to energy science will emerge.…

Mesoscale and Nanoscale Physics · Physics 2010-09-17 S. Garaj , W. Hubbard , A. Reina , J. Kong , D. Branton , J. A. Golovchenko
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