Related papers: On Cosmic Ray-Driven Grain Chemistry in Cold Core …
The total luminosity and spectral shape of the non-thermal emission produced by cosmic rays depends on their interstellar environment, a dependence that gives rise to correlations between galaxies' bulk properties -- star formation rate,…
Observations of line ratios in the Milky Way's warm ionized medium (WIM) suggest that photoionization is not the only heating mechanism present. For the additional heating to explain the discrepancy it would have to have a weaker dependence…
Heating of whole interstellar dust grains by cosmic-ray (CR) particles affects the gas-grain chemistry in molecular clouds by promoting molecule desorption, diffusion, and chemical reactions on grain surfaces. The frequency of such heating…
It is widely believed that water and complex organic molecules (COMs) first form in the ice mantle of dust grains and are subsequently returned into the gas due to grain heating by intense radiation of protostars. Previous research on the…
We propose a new model for treating solid-phase photoprocesses in interstellar ice analogues. In this approach, photoionization and photoexcitation are included in more detail, and the production of electronically-excited (suprathermal)…
Aims: The production of saturated organic molecules in hot cores and corinos is not well understood. The standard approach is to assume that, as temperatures heat up during star formation, methanol and other species evaporate from grain…
We present semi-analytical models of galactic outflows in high redshift galaxies driven by both hot thermal gas and non-thermal cosmic rays. Thermal pressure alone may not sustain a large scale outflow in low mass galaxies (i.e $M\sim…
The freezeout of gas-phase species onto cold dust grains can drastically alter the chemistry and the heating-cooling balance of protostellar material. In contrast to well-known species such as carbon monoxide (CO), the freezeout of various…
Grain surface chemistry and its treatment in gas-grain chemical models is an area of large uncertainty. Whilst laboratory experiments are making progress, there is still much that is unknown about grain surface chemistry. Further, the…
During the evolution of diffuse clouds to molecular clouds, gas-phase molecules freeze out on surfaces of small dust particles to form ices. On dust surfaces, water is the main constituent of the icy mantle in which a complex chemistry is…
Dynamically, cosmic rays with energies above about one GeV/nucleon may be important agents of galaxy evolution. Their pressures compare with the thermal and magnetic ones impacting galactic gas accretion, fountains and galactic outflows,…
Protoplanetary disks are the target of many chemical studies (both observational and theoretical) as they contain the building material for planets. Their large vertical and radial gradients in density and temperature make them challenging…
We present a new energy transport code that models the time dependent and non-linear evolution of spectra of cosmic-ray nuclei, their secondaries, and photon target fields. The software can inject an arbitrary chemical composition including…
Virtually all detailed gas-phase models of the chemistry of dense interstellar clouds exclude polycyclic aromatic hydrocarbons (PAH's). This omission is unfortunate because from the few studies that have been done on the subject, it is…
Dust grains play a central role in the physics and chemistry of cosmic environments. They influence the optical and thermal properties of the medium due to their interaction with stellar radiation; provide surfaces for the chemical…
Abbreviation. Thermal diffusion is one of the basic processes for the mobility and formation of species on cosmic dust grains. Recent laboratory measurements have found that the diffusion pre-exponential factor can differ from that for…
Glycoaldehyde, ethylene glycol, and methyl formate are complex organic molecules that have been observed in dark molecular clouds. Because there is no efficient gas-phase route to produce these species, it is expected that a low-temperature…
In the past decade, there has been a significant shift in astrochemistry with a renewed focus on the role of non-thermal processes on the molecular interstellar medium, in particular energetic particles (such as cosmic ray particles and…
The bulk propagation speed of GeV-energy cosmic rays is limited by frequent scattering off hydromagnetic waves. Most galaxy evolution simulations that account for this confinement assume the gas is fully ionized and cosmic rays are…
Cold dense cores are unique among the structures found in the interstellar medium (ISM), as they harbor a rich chemical inventory, including complex organic molecules (COMs), which will be inherited by future evolutionary stages. These…