Related papers: Extended Microprestress-Solidification Theory (XMP…
Long-term creep (i.e., deformation under sustained load) is a significant material response that needs to be accounted for in concrete structural design. However, the nature and origin of creep remains poorly understood, and controversial.…
From soft polymeric gels to hardened cement paste, amorphous solids under constant load exhibit a pronounced time-dependent deformation called creep. The microscopic mechanism of such a phenomenon is poorly understood in amorphous materials…
Capillary effects such as imbibition-drying cycles impact the mechanics of granular systems over time. A multiscale poromechanics framework was applied to cement paste, that is the most common building material, experiencing broad humidity…
Motivated by the puzzle of sorption hysteresis in Portland cement concrete or cement paste, we develop in Part II of this study a general theory of vapor sorption and desorption from nanoporous solids, which attributes hysteresis to…
Ba\v{z}ant's microprestress theory relates the logarithmic basic creep of concrete to power-law relaxation of heterogeneous eigenstresses at the nanoscale. However, the link between material chemistry, nanostructure, and microprestress…
When submitted to a constant mechanical load, many amorphous solids display power law creep followed by fluidization. A fundamental understanding of these processes is still far from being achieved. Here, we characterize creep and…
While many modern studies are dedicated to ML-based large-sample hydrologic modeling, these efforts have not necessarily translated into predictive improvements that are grounded in enhanced physical-conceptual understanding. Here, we…
A continuum theory based on thermodynamics has been developed for modeling diffusional creep of polycrystalline solids. It consists of a coupled problem of vacancy diffusion and mechanics where the vacancy generation/absorption at grain…
For the development of porous materials with improved transport properties, a key missing ingredient is to determine the relations between growth kinetics, structure, and transport parameters. Here, we address these relations by studying…
A potential strategy for controlling stratification in a drying suspension of bidisperse particles is studied using molecular dynamics simulations. When the suspension is maintained at a constant temperature during fast drying, it can…
We study the effect of spatially-correlated heterogeneity on isothermal drying of porous media. We combine a minimal pore-scale model with microfluidic experiments with the same pore geometry. Our simulated drying behavior compare favorably…
Systems with a high degree of size polydispersity are becoming standard in the computational study of deeply supercooled liquids. In this work we perform a systematic analysis of continuously polydisperse fluids as a function of the degree…
Mechanical creep behaviors of natural gas hydrates (NGHs) are of importance for understanding mechanical instability of gas hydrate-bearing sediments on Earth. Limited by the experimental challenges, intrinsic creep mechanisms of…
We extend our earlier shear-transformation-zone (STZ) theory of amorphous plasticity to include the effects of thermally assisted molecular rearrangements. This version of our theory is a substantial revision and generalization of…
Although continuum theories have been proven quite robust to describe confined fluid flow at molecular length scales, molecular dynamics (MD) simulations reveal mechanistic insights into the interfacial dissipation processes. Most MD…
Large scale molecular dynamics simulations for bidisperse nanoparticle suspensions with an explicit solvent are used to investigate the effects of evaporation rates and volume fractions on the nanoparticle distribution during drying. Our…
The relationship between humidity and water content in a hydrating cement paste is largely controlled by the nanostructure of the C-S-H gel. Current hydration models do not describe this nanostructure, thus sorption isotherms and…
We propose a theoretical framework to calculate capillary stresses in complex mesoporous materials, such as moist sand, nanoporous hydrates, and drying colloidal films. Molecular simulations are mapped onto a phase-field model of the…
Additive manufacture and rapid prototyping are versatile methods for the generation of lattice materials for applications in the creep regime. However, these techniques introduce defects that can degrade the macro-scopic creep strength. In…
The effect of a "pore-size" length-scale parameter l on compaction of grounds with fluid inclusions is studied. They are modelled as continua endowed with micro-structure by means of the macro-modelling procedure proposed in [2]. We show…