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The electrocaloric effect refers to the temperature change in a material when an electric field is applied or removed. Significant breakthroughs revealed its potential for solid-state cooling technologies in past decades. These devices…

Mesoscale and Nanoscale Physics · Physics 2025-04-10 Jean Spièce , Valentin Fonck , Charalambos Evangeli , Phil S. Dobson , Jonathan M. R. Weaver , Pascal Gehring

Giant electrocaloric (EC) effect is observed in BaTiO3 multilayer thick film structure. The temperature change is as high as 4.0 oC under an applied electric field of 352 kV/cm. Most importantly, the EC effect is found to depend on the…

Materials Science · Physics 2015-05-18 Yang Bai , Guang-Ping Zheng , San-Qiang Shi

Recent progress on caloric effects are reviewed. The application of external stimuli such as magnetic field, hydrostatic pressure, uniaxial stress and electric field give rise respectively to magnetocaloric, barocaloric, elastocaloric and…

Materials Science · Physics 2013-03-18 Lluis Manosa , Antoni Planes , Mehmet Acet

Due to critical environmental and technological issues, there is a pressing need to switch from current refrigeration methods based on compression of gases to novel solid-state cooling technologies. Solid-state cooling is based on the…

Materials Science · Physics 2020-05-12 Claudio Cazorla

Application of a negative field on a positively poled ferroelectric sample can enhance the electrocaloric cooling and appears as a promising method to optimize the electrocaloric cycle. Experimental measurements show that the maximal…

Materials Science · Physics 2016-11-21 Yang-Bin Ma , Nikola Novak , Karsten Albe , Bai-Xiang Xu

The electrocaloric effect (ECE) in BaTiO3 is simulated using two different first-principles based effective Hamiltonian molecular dynamics methods. The calculations are performed for a wide range of temperatures (30--900 K) and external…

Materials Science · Physics 2013-11-12 Takeshi Nishimatsu , Jordan A. Barr , Scott P. Beckman

Single-crystalline ferroelectric (FE) perovskites show a large electrocaloric effect at electric field-induced phase transitions, promising for solid-state cooling technologies. However, paraelectric-FE transition temperatures are often too…

Materials Science · Physics 2024-10-03 Lan-Tien Hsu , Frank Wendler , Anna Grünebohm

An atomistic effective Hamiltonian is used to investigate electrocaloric (EC) effects of Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) relaxor ferroelectrics in its ergodic regime, and subject to electric fields applied along the pseudocubic [111]…

Materials Science · Physics 2018-04-03 Zhijun Jiang , Y. Nahas , S. Prokhorenko , S. Prosandeev , D. Wang , Jorge Íñiguez , L. Bellaiche

Ferroelectrics are attractive candidate materials for environmentally friendly solid state refrigeration free of greenhouse gases. Their thermal response upon variations of external electric fields is largest in the vicinity of their phase…

Materials Science · Physics 2016-05-20 G. G. Guzmán-Verri , P. B. Littlewood

An atomistic effective Hamiltonian is used to compute electrocaloric (EC) effects in rare-earth substituted BiFeO$_{3}$ multiferroics. A phenomenological model is then developed to interpret these computations, with this model indicating…

We present a numerical simulation study of the exchange bias (EB) effect in nanoparticles with core/shell structure aimed to unveil the microscopic origin of some of the experimental phenomenology associated to this effect. In particular,…

Materials Science · Physics 2008-06-20 Oscar Iglesias , Xavier Batlle , Amilcar Labarta

Computer simulations are used to investigate the response of a charged colloid and its surrounding microion cloud to an external electric field. Both static fields (DC) and alternating fields (AC) are considered. A mesoscopic simulation…

Soft Condensed Matter · Physics 2013-07-19 Jiajia Zhou , Roman Schmitz , Burkard Duenweg , Friederike Schmid

The temperature and electric field dependence of electronic contribution to the thermal conductivity (TC) of a granular superconductor is considered within a 3D model of inductive Josephson junction arrays. In addition to a low-temperature…

Superconductivity · Physics 2009-11-07 Sergei Sergeenkov

We investigate the effect of epitaxial strain on the electrocaloric effect (ECE) in BaTiO$_3$ by means of ab initio based molecular dynamics simulations. We show that tensile strain can be used to optimize the operation range for ferroic…

Materials Science · Physics 2016-10-12 Anna Grünebohm , Madhura Marathe , Claude Ederer

We experimentally investigate thermoelectric response of a 100~nm thick SnSe single crystal flake under the current-induced dc electric field. Thermoelectric response appears as a second-harmonic transverse voltage $V_{xy}^{2\omega}$, which…

Mesoscale and Nanoscale Physics · Physics 2021-07-14 N. N. Orlova , A. V. Timonina , N. N. Kolesnikov , E. V. Deviatov

While it is well established that elevated temperatures can induce surface roughening of metal surfaces, the effect of a high electric field on the atomic structure at ambient temperature has not been investigated in detail. Here we show…

Electrocaloric (EC) materials show promise in eco-friendly solid-state refrigeration and integrable on-chip thermal management. While direct measurement of EC thin-films still remains challenging, a generic theoretical framework for…

Materials Science · Physics 2021-04-21 Yuping Shi , Limin Huang , Ai Kah Soh , George J. Weng , Shuangyi Liu , Simon A. T. Redfern

We describe magneto-, baro- and elastocaloric effects (MCEs, BCEs and eCEs) in materials which possess both discontinuous (first-order) and continuous (second-order) magnetic phase transitions. Our ab initio theory of the interacting…

Materials Science · Physics 2020-06-03 Eduardo Mendive-Tapia , Julie B. Staunton

An external electric field changes the physical properties of polar-liquids due to the reorientation of their permanent dipoles. For example it should affect significantly the physical properties of water confined in a nanochannel. The…

Mesoscale and Nanoscale Physics · Physics 2016-08-03 Sobrino Fernández Mario , M. Neek-Amal , F. M. Peeters

In this study, we report on a direct measurement method for the electrocaloric effect, the heating/cooling upon application/removal of an electric field in dielectric materials, based on a lock-in thermography technique. By use of…

Materials Science · Physics 2023-03-08 Ryo Iguchi , Daisuke Fukuda , Jun Kano , Takashi Teranishi , Ken-ichi Uchida