Related papers: Continuous condensation in nanogrooves
We consider the location and order of capillary condensation transitions occurring in deep grooves of width $L$ and depth $D$. For walls that are completely wet by liquid (contact angle $\theta=0$) the transition is continuous and its…
We study the low temperature phase equilibria of a fluid confined in an open capillary slit formed by two parallel walls separated by a distance $L$ which are in contact with a reservoir of gas. The top wall of the capillary is of finite…
We consider the phase equilibria of a fluid confined in a deep capillary groove of width $L$ with identical side walls and a bottom made of a different material. All walls are completely wet by the liquid. Using density functional theory…
We study the phase equilibria of a fluid confined in an open capillary slit formed when a wall of finite length $H$ is brought a distance $L$ away from a second macroscopic surface. This system shows rich phase equilibria arising from the…
We study the order of capillary condensation and evaporation transitions of a simple fluid adsorbed in a deep capillary groove using a fundamental measure density functional theory (DFT). The walls of the capillary interact with the fluid…
The dynamics of saturated vapor between two intersecting walls is examined. It is shown that, if the angle $\phi$ between the walls is sufficiently small, the vapor becomes unstable, and spontaneous condensation occurs in the corner,…
The geometry of walls forming a narrow pore may qualitatively affect the phase behaviour of the confined fluid. Specifically, the nature of condensation in nanopores formed of sinusoidally-shaped walls (with amplitude $A$ and period $P$) is…
We report a new first-order phase transition preceding capillary condensation and corresponding to the discontinuous formation of a curved liquid meniscus. Using a mean-field microscopic approach based on the density functional theory we…
Using grand canonical Monte Carlo simulations, we have explored the phenomenon of capillary condensation (CC) of Ar at the triple temperature inside infinitely long, cylindrical pores. Pores of radius R= 1 nm, 1.7 nm and 2.5 nm have been…
We consider capillary condensation transitions occurring in open slits of width $L$ and finite height $H$ immersed in a reservoir of vapour. In this case the pressure at which condensation occurs is closer to saturation compared to that…
Liquid in grooved capillaries, made by e.g. inserting a plate in a cylindrical tube, exhibits unusual spreading and flow properties. One example is capillary rise, where a long, upward tongue on top of the usual meniscus has been observed…
We investigate imbibition of a monodisperse emulsion into a low-aspect ratio microfluidic channel with the height h comparable to the droplet diameter d. For confinement ratio d/h = 1.2, the tightly confined disk-like droplets in the…
We show that condensation in a capped capillary slit is a continuous interfacial critical phenomenon, related intimately to several other surface phase transitions. In three dimensions (3d), the adsorption and desorption branches correspond…
A simple fluid, in a microscopic capillary capped at one end, is studied by means of fundamental measure density functional. The model represents a single, infinitely long nanogroove with long-range wall-fluid attractive (dispersion)…
We consider theoretically liquid rise against gravity in capillaries with height-dependent cross-section. For a conical capillary made from a hydrophobic surface and dipped in a liquid reservoir, the equilibrium liquid height depends on the…
We study the phase transitions of a fluid confined in a capillary slit made from two adjacent walls each of which are a periodic composite of stripes of two different materials. For wide slits the capillary condensation occurs at a pressure…
We present a macroscopic theory of capillary condensation in slits formed by parallel walls of unequal length. Using the concept of an edge contact angle, we identify four distinct condensation states and derive Kelvin-like relations for…
Liquid dropout and retention in gas-condensate reservoirs, specially in the near wellbore region, obstruct gas flowing paths and impact negatively the produced fluid volume and composition. Yet, condensate banking forecasting is commonly…
Condensation on vertical surfaces leads to fluid retention, which limits the efficiency of applications ranging from heat exchangers to atmospheric water harvesters. A common strategy is to structure the surface with grooves, yet whether…
Capillary condensation of water is ubiquitous in nature and technology. It routinely occurs in granular and porous media, can strongly alter such properties as adhesion, lubrication, friction and corrosion, and is important in many…