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Organic functionalization of graphene is successfully performed via 1,3-dipolar cycloaddition of azomethine ylide in the liquid phase. The comparison between 1-methyl-2-pyrrolidinone and N,N-dimethylformamide as dispersant solvents, and…

Hydrogen-based fuel cells are promising solutions for the efficient and clean delivery of electricity. Since hydrogen is an energy carrier, a key step for the development of a reliable hydrogen-based technology requires solving the issue of…

Mesoscale and Nanoscale Physics · Physics 2017-03-15 Valentina Tozzini , Vittorio Pellegrini

We report electron-beam activated motion of a catalytic nanoparticle along a graphene step edge and associated etching of the edge. This approach enables beam-controlled etching of matter through activated electrocatalytic processes. The…

Applied Physics · Physics 2019-12-18 Ondrej Dyck , David Lingerfelt , Songkil Kim , Stephen Jesse , Sergei V. Kalinin

Low-cost graphene sponge electrodes were functionalized with two-dimensional (2D) materials, i.e., borophene and hexagonal boron nitride (hBN), using a one-step, hydrothermal self-assembly method. Borophene and hBN-modified graphene sponge…

Materials Science · Physics 2022-06-10 Elisabeth Cuervo Lumbaque , Luis Baptista-Piresa , Jelena Radjenovic

At present, Pt nanoparticle catalysts in fuel cells suffer from aggregation and loss of chemical activity. In this work, graphdiyne, which has natural porous structure, was proposed as substrate with high adsorption ability to stabilize Pt…

Mesoscale and Nanoscale Physics · Physics 2015-03-03 Zheng-Zhe Lin

Increasing energy demands of modern society requires deep understanding of the properties of energy storage materials as well as their performance tuning. We show that the capacitance of graphene oxide (GO) can be precisely tuned using a…

Graphene nanoribbons and constrictions are envisaged as fundamental components of future carbon-based nanoelectronic and spintronic devices. At nanoscale, electronic effects in these devices depend heavily on the dimensions of the active…

Coupled hybrid nanostructures are demonstrated using the combination of lithographically patterned graphene on top of a two-dimensional electron gas (2DEG) buried in a GaAs/AlGaAs heterostructure. The graphene forms Schottky barriers at the…

The isolation of graphene has triggered an avalanche of studies into the spin-dependent physical properties of this material, as well as graphene-based spintronic devices. Here we review the experimental and theoretical state-of-art…

Mesoscale and Nanoscale Physics · Physics 2015-03-11 Wei Han , Roland K. Kawakami , Martin Gmitra , Jaroslav Fabian

Understanding the reactions in M-O2 cells (M = Li or Na) is of great importance for further advancement of this promising technology. Computational modelling can be helpful along this way, but an adequate approach is needed to model such…

The exotic physical properties of graphene have led to intense research activities on the synthesis and characterization of graphene composites during the last decade. In this article the methods developed for preparation of such materials…

Mesoscale and Nanoscale Physics · Physics 2012-07-10 Sreemanta Mitra , Sourish Banerjee , Anindya Datta , Dipankar Chakravorty

Carbon-based nanostructures and graphene, in particular, evoke a lot of interest as new promising materials for nanoelectronics and spintronics. One of the most important issue in this context is the impact of external electrodes on…

Mesoscale and Nanoscale Physics · Physics 2012-03-16 S. Krompiewski

The present manuscript summarizes the modern view on the problem of the graphene-metal interaction. Presently, the close-packed surfaces of d metals are used as templates for the preparation of highly-ordered graphene layers. Different…

Materials Science · Physics 2017-08-23 E. N. Voloshina , Yu. S. Dedkov

This review on graphene, a one atom thick, two-dimensional sheet of carbon atoms, starts with a general description of the graphene electronic structure as well as a basic experimental toolkit for identifying and handling this material.…

Materials Science · Physics 2010-11-22 Caterina Soldano , Ather Mahmood , Erik Dujardin

The synthesis of single-wall carbon nanotubes (SWCNTs) of desired diameters and chiralities is critical to the design of nanoscale electronic devices with desired properties.1-6 The existing methods are based on self-assembly, 7-16…

Materials Science · Physics 2009-11-13 Anton Sidorov , David Mudd , Gamini Sumanasekera , P. J. Ouseph , C. S. Jayanthi , Shi-Yu Wu*

Graphene and its heterostructures exhibit interesting electronic properties and are explored for quantum spin Hall effect(QSHE) and magnetism based device applications. In present work, we propose a heterostructure of graphene encapsulated…

Materials Science · Physics 2019-10-07 Mohammed Ghadiyali , Sajeev Chacko

In this work we outline the mechanisms contributing to the oxygen reduction reaction in nanostructured cathodes of La0.8Sr0.2MnO3 (LSM) for Solid Oxide Fuel Cells (SOFC). These cathodes, developed from LSM nanostructured tubes, can be used…

Graphene is a unique material to study fundamental limits of plasmonics. Apart from the ultimate single-layer thickness, its carrier concentration can be tuned by chemical doping or applying an electric field. In this manner the…

Mesoscale and Nanoscale Physics · Physics 2017-11-30 Dmitry A. Kuzmin , Igor V. Bychkov , Vladimir G. Shavrov , Vasily V. Temnov

Nanocarbons are an important class of energy materials and one relevant application is for the nitrogen reduction reaction, i.e., the direct synthesis of NH3 from N2 and H2O via photo- and electrocatalytic approaches. Ammonia is also a…

Materials Science · Physics 2022-05-12 Gabriele Centi , Siglinda Perathoner

The electrochemical hydrogenation of graphene induces a robust and reversible conductor-insulator transition, of strong interest in logic-and-memory applications. However, its mechanism remains unknown. Here we show that it proceeds as a…