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A gas-phase optical spectrum of a large polycyclic aromatic hydrocarbon (PAH) cation - C78H26 +- in the 410-610 nm range is presented. This large all-benzenoid PAH should be large enough to be stable with respect to photodissociation in the…

Instrumentation and Methods for Astrophysics · Physics 2015-12-04 Junfeng Zhen , Giacomo Mulas , Anthony Bonnamy , Christine Joblin

The formation of polycyclic aromatic hydrocarbons (PAHs) and their methyl derivatives occurs mainly in the dust shells of asymptotic giant branch (AGB) stars. The bands at 3.3 and 3.4 $\mu$m, observed in infrared emission spectra of several…

Solar and Stellar Astrophysics · Physics 2016-04-20 T. Monfredini , F. Fantuzzi , M. A. C. Nascimento , W. Wolff , H. M. Boechat-Roberty

We use archival data from the Diffuse Infrared Background Experiment (DIRBE) to map the polycyclic aromatic hydrocarbon (PAH) 3.3 $\mu$m emission feature and analyze its correlation with AME in 98 compact sources identified by the Planck…

Cosmology and Nongalactic Astrophysics · Physics 2025-09-05 Danielle Sponseller , David T. Chuss , Brandon Hensley , Alan Kogut

This study presents optical and near-infrared photometric observations, alongside mid-infrared spectroscopic data from the ISO SWS instrument, to examine potential correlations between Aromatic Infrared Band (AIB) features and the optical…

Astrophysics of Galaxies · Physics 2025-08-08 Rahul Kumar Anand , Atul Kumar Singh , Saurabh Sharma , Brijesh Kumar , Shantanu Rastogi

We investigated the dissociation of dications and trications of three polycyclic aromatic hydrocarbons (PAHs), fluorene, phenanthrene, and pyrene. PAHs are a family of molecules ubiquitous in space and involved in much of the chemistry of…

Aims. We present a systematic theoretical study on 40 polycyclic aromatic hydrocarbons dications (PAHs++) containing up to 66 carbon atoms. Methods. We performed our calculations using well established quantum-chemical techniques in the…

Astrophysics · Physics 2009-11-11 G. Malloci , C. Joblin , G. Mulas

I summarize the results of two recent studies, based on ISO and Spitzer mid-IR spectra of galaxies and Galactic regions, aimed at understanding the origins of the variations of the aromatic features among and inside galaxies. I show that…

Astrophysics · Physics 2007-05-23 F. Galliano

Spitzer 'hidden' observations of the background are used to construct a catalog of 4,090 spectra and examine the signature of polycyclic aromatic hydrocarbon (PAH) molecules and their connection to extinction by dust. A strong positive…

Astrophysics of Galaxies · Physics 2024-11-04 Christiaan Boersma , Jesse D. Bregman , Louis J. Allamandola , Pasquale Temi , Alexandros Maragkoudakis

Polycyclic aromatic hydrocarbons (PAHs) are believed to be ubiquitous in the interstellar medium. Yet, to date no specific PAH molecule has been identified. In this paper, a new observational avenue is suggested to detect individual PAHs,…

Astrophysics of Galaxies · Physics 2015-08-21 Yacine Ali-Haïmoud

We propose to evaluate the contribution of polycyclic aromatic hydrocarbon molecules that carry side groups to the mid-infrared emission spectra. Within this framework, the IR absorption spectra of 2- and 9-vinylanthracene were measured in…

Solar and Stellar Astrophysics · Physics 2015-06-05 Anju Maurya , Shantanu Rastogi , G. Rouillé , Friedrich Huisken , Thomas Henning

The Interest in polycyclic aromatic hydrocarbons (PAHs) spans numerous fields and infrared spectroscopy is usually the method of choice to disentangle their molecular structure. In order to compute vibrational frequencies, numerous…

Chemical Physics · Physics 2021-05-18 Gaétan Laurens , Malalatiana Rabary , Julien Lam , Daniel Peláez , Abdul-Rahman Allouche

Accurate correction for extinction by Galactic dust is essential for studying the extragalactic sky. In the low-extinction regions of the Ursa Major molecular cloud complex, we demonstrate that Galactic dust reddening maps constructed from…

Astrophysics of Galaxies · Physics 2025-10-28 Dennis Lee , Brandon S. Hensley , Tzu-Ching Chang , Olivier Doré

Polycyclic aromatic hydrocarbons (PAHs) and fullerenes play a major role in the physics and chemistry of the interstellar medium. Based on a number of recent experimental and theoretical investigations we developed a model in which PAHs are…

Astrophysics of Galaxies · Physics 2022-11-09 M. S. Murga , V . V. Akimkin , D. S. Wiebe

We present a large sample of 2.5-38 $\mu m$ galaxy spectra drawn from a cross-archival comparison in the AKARI-Spitzer Extragalactic Spectral Survey (ASESS), and investigate a subset of 113 star-forming galaxies with prominent polycyclic…

Astrophysics of Galaxies · Physics 2020-12-23 Thomas S. -Y. Lai , J. D. T. Smith , Shunsuke Baba , Henrik W. W. Spoon , Masatoshi Imanishi

Polarized emission from polycyclic aromatic hydrocarbons (PAHs) potentially provides a new way to test basic physics of the alignment of ultrasmall grains. In this paper, we present a new model of polarized PAH emission that takes into…

Astrophysics of Galaxies · Physics 2017-04-12 Thiem Hoang

Observationally, the interstellar gas-phase abundance of deuterium (D) is considerably depleted and the missing D atoms are often postulated to have been locked up into carbonaceous solids and polycyclic aromatic hydrocarbon (PAH)…

Astrophysics of Galaxies · Physics 2021-08-04 X. J. Yang , Aigen Li , C. Y. He , R. Glaser

Evolutionary properties of infrared (IR) luminous galaxies are important keys to understand dust-obscured star formation history and galaxy evolution. Based on the near- to mid-IR imaging with 9 continuous filters of AKARI space telescope,…