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Low-resolution, mid-infrared Spitzer/IRS spectral maps are presented for three nearby, low-metallicity dwarf galaxies (NGC 55, NGC 3109 and IC 5152) for the purpose of examining the spatial distribution and variation of polycyclic aromatic…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-19 Korey Haynes , John M. Cannon , Evan D. Skillman , Dale C. Jackson , Robert D. Gehrz

While powerful techniques exist to accurately account for anharmonicity in vibrational molecular spectroscopy, they are computationally very expensive and cannot be routinely employed for large species and/or at non- zero vibrational…

Chemical Physics · Physics 2018-10-17 Giacomo Mulas , Cyril Falvo , Patrick Cassam-Chenaï , Christine Joblin

Interstellar polycyclic aromatic hydrocarbon (PAHs) are an important component of the interstellar medium of galaxies, containing some 10 percent of the elemental carbon. Their vibrational emission dominates the mid-infrared spectra of…

Astrophysics of Galaxies · Physics 2026-03-06 A. G. G. M. Tielens

For star-forming galaxies, we investigate a global relation between polycyclic aromatic hydrocarbon (PAH) emission luminosity at 3.3 um, L_PAH3.3, and infrared (8-1000 um) luminosity, L_IR, to understand how the PAH 3.3 um feature relates…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-16 Rika Yamada , Shinki Oyabu , Hidehiro Kaneda , Mitsuyoshi Yamagishi , Daisuke Ishihara , Ji Hoon Kim , Myungshin Im

We have carried out a detailed analysis of the 3.4 micron spectral feature arising from Polycyclic Aromatic Hydrocarbons (PAH), using JWST archival data. For the first time in an external galaxy (NGC 6240), we have identified two distinct…

Cyano-substituted polycyclic aromatic hydrocarbons (CN-PAHs) may contribute to the emission detected in the 7 - 9 $\mu$m (1430 - 1100 cm$^{-1}$) and 11 - 15 $\mu$m (900 - 670 cm$^{-1}$) regions of astronomical IR spectra. Anharmonic quantum…

Astrophysics of Galaxies · Physics 2024-12-10 Vincent J. Esposito , Ryan C. Fortenberry , Christiaan Boersma , Louis J. Allamandola

The polycyclic aromatic hydrocarbon (PAH) hypothesis proposes that the aromatic infrared bands (AIBs) observed at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 mic originate from gas-phase PAH molecules. These bands exhibit consistent peak wavelengths…

Astrophysics of Galaxies · Physics 2025-11-03 Alan T. Tokunaga , Lawrence S. Bernstein , Takashi Onaka

Emission from a class of benzene-based molecules known as Polycyclic Aromatic Hydrocarbons (PAHs) dominates the infrared spectrum of star-forming regions. The observed emission appears to arise from the combined emission of numerous PAH…

Instrumentation and Methods for Astrophysics · Physics 2014-03-20 Kevin H. Knuth , Man Kit Tse , Joshua Choinsky , Haley A. Maunu , Duane F. Carbon

We report new properties of the 11 and 12.7 {\mu}m emission complexes of polycyclic aromatic hydrocarbons (PAHs) by applying a Gaussian-based decomposition technique. Using high-resolution \textit{Spitzer} Space Telescope data, we study in…

Astrophysics of Galaxies · Physics 2016-06-29 M. J. Shannon , D. J. Stock , E. Peeters

In this Letter we report the results of density functional theory calculations on medium-sized neutral Polycyclic Aromatic Hydrocarbon (PAH) molecules with armchair edges. These PAH molecules possess strong C-H stretching and bending modes…

Astrophysics of Galaxies · Physics 2014-10-09 A. Candian , P. J. Sarre , A. G. G. M. Tielens

We examine the annihilation of positrons on polycyclic aromatic hydrocarbon (PAH) molecules in interstellar medium conditions. We estimate the annihilation rates of positrons on PAHs by a semi-empirical approach. We show that PAHs can play…

High Energy Astrophysical Phenomena · Physics 2015-05-14 N. Guessoum , P. Jean , W. Gillard

Polycyclic aromatic hydrocarbons (PAHs) are some of the major dust components in the interstellar medium (ISM). We present our evolution models for the abundance of PAHs in the ISM on a galaxy-evolution timescale. We consider shattering of…

Astrophysics of Galaxies · Physics 2015-06-18 Ji Yeon Seok , Hiroyuki Hirashita , Ryosuke S. Asano

Infrared (IR) emission spectra are calculated for dust composed of mixtures of amorphous silicate and graphitic grains, including varying amounts of polycyclic aromatic hydrocarbon (PAH) particles. The models are constrained to reproduce…

Astrophysics · Physics 2008-11-26 B. T. Draine , Aigen Li

A distinct set of broad emission features at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 $\mu$m, is often detected in protoplanetary disks (PPDs). These features are commonly attributed to polycyclic aromatic hydrocarbons (PAHs). We model these…

Solar and Stellar Astrophysics · Physics 2017-02-08 Ji Yeon Seok , Aigen Li

Infrared emission features at 3.3, 6.2, 7.7, 8.6, and 11.2 $\mu$m, attributed to polycyclic aromatic hydrocarbons, show variations in relative intensity, shape, and peak position. These variations depend on the physical conditions of the…

Astrophysics of Galaxies · Physics 2021-11-24 C. Knight , E. Peeters , M. Wolfire , D. J. Stock

We present a charge distribution-based emission model that calculates the infrared spectrum of fullerenes (C$_{60}$). Analysis of the modelled spectrum of C$_{60}$ in various charge states shows that the relative intensity of the features…

Astrophysics of Galaxies · Physics 2023-04-25 Ameek Sidhu , A. G. G. M. Tielens , Els Peeters , Jan Cami

Recognized as important interstellar constituents, polycyclic aromatic hydrocarbons (PAHs) have been intensively studied in astrochemistry and their spectroscopy, thermodynamics, dynamics, and fragmentations are now amply documented. There…

Chemical Physics · Physics 2017-06-13 Georges Trinquier , Aude Simon , Mathias Rapacioli , Florent Xavier Gadéa

Using the AKARI, Wide-field Infrared Survey Explorer (WISE), Infrared Astronomical Satellite (IRAS), Sloan Digital Sky Survey (SDSS) and Hubble Space Telescope (HST) data, we investigated the relation of polycyclic aromatic hydrocarbon…

Polycyclic aromatic hydrocarbons (PAHs) are responsible for strong mid-IR emission features near star-forming regions. It is well known that low-metallicity environments exhibit weaker PAH emission, but it is not clear how the metallicity…

Astrophysics of Galaxies · Physics 2025-06-09 Congcong Zhang , Joelene Hales , Els Peeters , Jan Cami , Ameek Sidhu , Junfeng Zhen