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A practical method for finding free energy barriers for transitions in high-dimensional classical and quantum systems is presented and used to calculate the dissociative sticking probability of H2 on a metal surface within transition state…

chem-ph · Physics 2009-10-22 Gregory Mills , Hannes Jonsson

The task of locating first order saddle points on high-dimensional surfaces describing the variation of energy as a function of atomic coordinates is an essential step for identifying the mechanism and estimating the rate of thermally…

Chemical Physics · Physics 2025-07-24 Rohit Goswami , Maxim Masterov , Satish Kamath , Alejandro Peña-Torres , Hannes Jónsson

Sampling synthetic turbulent fields as a computationally tractable surrogate for direct numerical simulations (DNS) is an important practical problem in various applications, and allows to test our physical understanding of the main…

Fluid Dynamics · Physics 2025-11-19 Timo Schorlepp , Katharina Kormann , Jeremiah Lübke , Tobias Schäfer , Rainer Grauer

A formula suitable for a quantitative evaluation of the tunneling effect in a ferromagnetic particle is derived with the help of the instanton method. The tunneling between n-th degenerate states of neighboring wells is dominated by a…

Condensed Matter · Physics 2016-08-31 J. -Q. Liang , Y. -B. Zhang , H. J. W. Mueller-Kirsten , Jian-Ge Zhou , F. Zimmerschied , F. -C. Pu

Approximation algorithms are widely used in many engineering problems. To obtain a data set for approximation a factorial design of experiments is often used. In such case the size of the data set can be very large. Therefore, one of the…

Methodology · Statistics 2014-07-04 Mikhail Belyaev , Evgeny Burnaev , Yermek Kapushev

In this work, we initiate the study of Hamiltonian learning for positive temperature bosonic Gaussian states, the quantum generalization of the widely studied problem of learning Gaussian graphical models. We obtain efficient protocols,…

Quantum Physics · Physics 2025-04-08 Marco Fanizza , Cambyse Rouzé , Daniel Stilck França

In this work, the rate law for inhomogeneous concentration distributions has been formulated, by applying spatial integration over the products of species concentrations. Reaction rates for typical reactions have been investigated by…

Chemical Physics · Physics 2025-12-24 Xiang-Yuan Li , Xin-Yu Zhang , ChuanFeng Yue

We propose a new quantum transition-state theory for calculating Fermi's golden-rule rates in complex multidimensional systems. This method is able to account for the nuclear quantum effects of delocalization, zero-point energy and…

Chemical Physics · Physics 2019-03-27 Manish J. Thapa , Wei Fang , Jeremy O. Richardson

Machine learning methods have nowadays become easy-to-use tools for constructing high-dimensional interatomic potentials with ab initio accuracy. Although machine learned interatomic potentials are generally orders of magnitude faster than…

Computational Physics · Physics 2021-02-24 Yaolong Zhang , Ce Hu , Bin Jiang

Using the idea of the instanton approach to quantum tunneling we try to obtain a method of calculating spontaneous fission rates for nuclei with the odd number of neutrons or protons. This problem has its origin in the failure of the…

Nuclear Theory · Physics 2020-11-11 W. Brodziński , J. Skalski

Wireless power transfer (WPT) with coupled resonators offers a promising solution for the seamless powering of electronic devices. Interactive design approaches that visualize the magnetic field and power transfer efficiency based on system…

Applied Physics · Physics 2025-10-23 Yuichi Honjo , Cedric Caremel , Ken Takaki , Yuta Noma , Yoshihiro Kawahara , Takuya Sasatani

Background: Quantum tunneling in many-body systems is the subject of many experimental and theoretical studies in fields ranging from cold atoms to nuclear physics. However, theoretical description of quantum tunneling with strongly…

Nuclear Theory · Physics 2020-12-18 Patrick McGlynn , Cedric Simenel

We propose an ab-initio molecular dynamics method, capable to reduce dramatically the autocorrelation time required for the simulation of classical and quantum particles at finite temperature. The method is based on an efficient…

Strongly Correlated Electrons · Physics 2017-01-11 Sandro Sorella , Guglielmo Mazzola

We show how the path-integral formulation of quantum statistical mechanics can be used to construct practical {\em ab initio} techniques for computing the chemical potential of molecules adsorbed on surfaces, with full inclusion of quantum…

Materials Science · Physics 2015-05-18 D. Alfe` , M. J. Gillan

The optimization of atomic structures plays a pivotal role in understanding and designing materials with desired properties. However, conventional computational methods often struggle with the formidable task of navigating the vast…

Materials Science · Physics 2024-11-19 Peder Lyngby , Casper Larsen , Karsten Wedel Jacobsen

We consider the cosmological model of a self-interacting $\phi^4 - \phi^2$ quantum scalar field and extend our previous results, [3], on resonant tunneling and consequent particle production, to the case of finite temperature. Using the…

General Relativity and Quantum Cosmology · Physics 2007-05-23 L. Mersini

We propose a contrast-based estimation method for Gaussian processes with time-inhomogeneous drifts, observed under high-frequency sampling. The process is modeled as the sum of a deterministic drift function and a stationary Gaussian…

Statistics Theory · Mathematics 2025-10-07 Yasutaka Shimizu

Computing accurate estimates of the Fourier transform of analog signals from discrete data points is important in many fields of science and engineering. The conventional approach of performing the discrete Fourier transform of the data…

Machine Learning · Statistics 2017-12-08 Luca Ambrogioni , Eric Maris

This tutorial aims to provide an intuitive introduction to Gaussian process regression (GPR). GPR models have been widely used in machine learning applications due to their representation flexibility and inherent capability to quantify…

Machine Learning · Statistics 2024-01-30 Jie Wang

We present the construction of an original stochastic model for the instantaneous turbulent kinetic energy at a given point of a flow, and we validate estimator methods on this model with observational data examples. Motivated by the need…

Fluid Dynamics · Physics 2022-11-30 Mireille Bossy , Jean-Francois Jabir , Kerlyns Martinez Rodriguez