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The one-particle reduced density-matrix (1-RDM) functional theory is a promising alternative to density-functional theory (DFT) that uses the 1-RDM rather than the electronic density as a basic variable. However, long-standing challenges…

Quantum Physics · Physics 2024-08-20 Matthieu Vladaj , Quentin Marécat , Bruno Senjean , Matthieu Saubanère

We show how multi-level BCS Hamiltonians of finite systems in the strong pairing interaction regime can be accurately approximated using multi-dimensional shifted harmonic oscillator Hamiltonians. In the Shifted Harmonic Approximation…

Quantum Physics · Physics 2010-11-22 S. Y. Ho , D. J. Rowe , S. De Baerdemacker

Electronic structure simulation is an anticipated application for quantum computers. Due to high-dimensional quantum entanglement in strongly correlated systems, the quantum resources required to perform such simulations are far beyond the…

Quantum Physics · Physics 2022-01-25 Jie Liu , Zhenyu Li , Jinlong Yang

The S-matrix of the well-studied sinh-Gordon model possesses a remarkable strong/weak coupling duality $b \to 1/b$. Since there is no understanding nor evidence for such a duality based on the quantum action of the model, it should be…

High Energy Physics - Theory · Physics 2022-09-15 Denis Bernard , André LeClair

We propose a variational framework for solving ground-state problems of open quantum systems governed by quantum stochastic differential equations (QSDEs). This formulation naturally accommodates bosonic operators, as commonly encountered…

Quantum Physics · Physics 2025-12-17 Yunyan Lee , Ian R. Petersen , Daoyi Dong

We develop a systematic framework for the spin adaptation of the cumulants of p-particle reduced density matrices (RDMs), with explicit constructions for p = 1 to 3. These spin-adapted cumulants enable rigorous treatment of both S_z and S^2…

Chemical Physics · Physics 2025-10-31 Julia Liebert , Christian Schilling , David A. Mazziotti

We develop convergent variational perturbation theory for quantum statistical density matrices. The theory is applicable to polynomial as well as nonpolynomial interactions. Illustrating the power of the theory, we calculate the…

Quantum Physics · Physics 2009-10-31 M. Bachmann , H. Kleinert , A. Pelster

This chapter gives a self-contained review of the how standard open quantum system Hamiltonians can be mapped analytically onto representations in which the environments appear as one dimensional harmonic chains with nearest neighbour…

Quantum Physics · Physics 2011-12-30 Alex W. Chin , Susana F. Huelga , Martin B. Plenio

We present a new paradigm for the dynamical simulation of interacting many-boson open quantum systems. The method relies on a variational ansatz for the $n$-boson density matrix, in terms of a superposition of photon-added coherent states.…

Quantum Physics · Physics 2023-06-27 David S. Schlegel , Fabrizio Minganti , Vincenzo Savona

We establish a theoretical framework for exploring the quantum dynamics of finite ultracold bosonic ensembles based on the Born-Bogoliubov-Green-Kirkwood-Yvon (BBGKY) hierarchy of equations of motion for few-particle reduced density…

Quantum Physics · Physics 2018-07-24 Sven Krönke , Peter Schmelcher

We develop a truncated Hamiltonian method to investigate the dynamics of the $(1+1)d~\phi^4$ theory following quantum quenches. The results are compared to two different semi-classical approaches, the self-consistent Gaussian approximation…

Statistical Mechanics · Physics 2022-01-12 D. Szász-Schagrin , I. Lovas , G. Takács

The training of a parameterized model largely depends on the landscape of the underlying loss function. In particular, vanishing gradients are a central bottleneck in the scalability of variational quantum algorithms (VQAs), and are known…

Quantum Physics · Physics 2024-09-26 Alistair Letcher , Stefan Woerner , Christa Zoufal

Calculating the ground state properties of a Hamiltonian can be mapped to the problem of finding the ground state of a smaller Hamiltonian through the use of embedding methods. These embedding techniques have the ability to drastically…

Quantum Physics · Physics 2022-03-15 Lana Mineh , Ashley Montanaro

We present a basis-set-free approach to the variational quantum eigensolver using an adaptive representation of the spatial part of molecular wavefunctions. Our approach directly determines system-specific representations of qubit…

Quantum Physics · Physics 2021-01-05 Jakob S. Kottmann , Philipp Schleich , Teresa Tamayo-Mendoza , Alán Aspuru-Guzik

Seniority-zero geminal wavefunctions are known to capture bond-breaking correlation. Among this class of wavefunctions, Richardson-Gaudin states stand out as they are eigenvectors of a model Hamiltonian. This provides a clear physical…

Chemical Physics · Physics 2022-12-14 Alexandre Faribault , Claude Dimo , Jean-David Moisset , Paul A. Johnson

The scalar Yukawa model, in which a complex scalar field interact via a real scalar field, is reduced by using covariant Green functions. It is shown that exact few-particle eigenstates of the truncated QFT Hamiltonian can be obtained in…

Nuclear Theory · Physics 2009-10-31 Jurij W. Darewych

Quantum variational algorithms (QVAs) are increasingly potent tools for simulating quantum many-body systems on noisy intermediate-scale quantum (NISQ) devices. This work examines the application of the Variational Quantum Eigensolver (VQE)…

Nuclear Theory · Physics 2026-01-28 Dhritimalya Roy , Somnath Nag

We present a low-space overhead simulation algorithm based on the truncated Dyson series for time-dependent quantum dynamics. This algorithm is applied to simulating time-independent Hamiltonians by transitioning to the interaction picture,…

Quantum Physics · Physics 2019-06-07 Guang Hao Low , Nathan Wiebe

Accurate modeling of driven light-matter interactions is essential for quantum technologies, where natural and synthetic atoms are used to store and process quantum information, mediate interactions between bosonic modes, and enable…

Quantum Physics · Physics 2025-09-04 Martin Jirlow , Kunal Helambe , Axel M. Eriksson , Simone Gasparinetti , Tahereh Abad

In this paper we discuss the utilization of Variational Quantum Solver (VQE) and recently introduced Generalized Unitary Coupled Cluster (GUCC) formalism for the diagonalization of downfolded/effective Hamiltonians in active spaces. In…

Quantum Physics · Physics 2020-11-05 Nicholas P. Bauman , Jaroslav Chládek , Libor Veis , Jiří Pittner , Karol Kowalski