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It is shown that both structural phase transitions in Cd2Re2O7, which occur at T_{s1}=200 K and T_{s2}=120 K, are due to an instability of the Re tetrahedral network with respect to the same doubly degenerate long-wavelength phonon mode.…

Superconductivity · Physics 2009-11-10 I. A. Sergienko , S. H. Curnoe

We report a density-functional theory study of the structural and electronic properties of Cd2V2O7 under high-pressure conditions. The calculations have been performed by using first-principle calculations with the CRYSTAL program. The…

Materials Science · Physics 2022-05-23 Daniel Diaz-Anichtchenko , Daniel Errandonea

Tb2Ti2O7, a pyrochlore system, has garnered significant interest due to its intriguing structural and physical properties and their dependence on external physical parameters. In this study, utilizing high-brilliance synchrotron X-ray…

We performed $^{185/187}$Re nuclear quadrupole resonance (NQR) measurements under pressure to investigate the superconducting properties of noncentrosymmetric superconductor Cd$_{2}$Re$_{2}$O$_{7}$ under various crystal structures. The…

We report pressure tuned Raman and x-ray diffraction data of Bi1.98Sr2.06Y0.68Cu2O8 revealing a critical pressure at 21 GPa with anomalies in six physical quantities: electronic Raman background, electron-phonon coupling, spectral weight…

Superconductivity · Physics 2009-11-13 T. Cuk , V. Struzhkin , T. P. Devereaux , A. Goncharov , C. Kendziora , H. Eisaki , H. Mao , Z. -X. Shen

We studied the crystal and magnetic structure of Ca2RuO4 by different diffraction techniques under high pressure. The observed first order phase transition at moderate pressure (0.5 GPa) between the insulating phase and the metallic high…

Strongly Correlated Electrons · Physics 2009-11-11 P. Steffens , O. Friedt , P. Alireza , W. G. Marshall , W. Schmidt , F. Nakamura , S. Nakatsuji , Y. Maeno , R. Lengsdorf , M. M. Abd-Elmeguid , M. Braden

The phase stability of the MgMn2O4 spinel has been studied by means of high-pressure X-ray diffraction for pressures up to 30 GPa. Two samples with different inversion degrees have been considered. Both spinels undergo a phase transition…

Materials Science · Physics 2009-11-10 Lorenzo Malavasi , Cristina Tealdi , Monica Amboage , M. Cristina Mozzati , Giorgio Flor

We report the results of the X-ray diffraction study of B2O3 glass in the pressure interval up to 10 GPa in the 300-700 K temperature range, the results of in-situ volumetric measurements of the glass at pressures up to 9 GPa at room…

Disordered Systems and Neural Networks · Physics 2008-07-19 V. V. Brazhkin , Y. Katayama , K. Trachenko , O. B. Tsiok , A. G. Lyapin , Emilio Artacho , M. Dove , G. Ferlat , Y. Inamura , H. Saitoh

A new pyrochlore ruthenium oxide, Hg2Ru2O7 was synthesized under a high pressure of 6 GPa. In contrast to the extensively studied Ru4+ oxides, this compound possesses a novel Ru5+ valence state, corresponding to a half-filled t_2g_3…

This study explores the pressure evolution of the double perovskite Ba$_2$NiTeO$_6$ by employing experimental and computational techniques. For the study of structural and vibrational properties, synchrotron X-ray diffraction (XRD) and…

In this work, we investigate calcium titanate (CaTiO3 - CTO) using X-ray diffraction and Raman spectroscopy up to 60 and 55 GPa respectively. Both experiments show that the orthorhombic Pnma structure remains stable up to the highest…

We have measured the polarized Raman scattering spectra of Cd2Re2O7, the first superconducting pyrochlore, as a function of temperature. For temperatures below the cubic-to-tetragonal structural phase transition (SPT) at 200K, a peak with…

Materials Science · Physics 2007-05-23 C. A. Kendziora , I. A. Sergienko , R. Jin , J. He , V. Keppens , B. C. Sales , D. Mandrus

Iron-chalcogenide superconductor Fe$_{1.03}$Se$_{0.5}$Te$_{0.5}$ has been investigated under high pressure using synchrotron based x-ray diffraction and mid-infrared reflectance measurements at room temperature. Pressure dependence of the…

Materials Science · Physics 2013-08-16 Pallavi S. Malavi , S. Karmakar , N. N. Patel , Surinder M. Sharma

High pressure effects on the superconducting transitions of beta-pyrochlore superconductors AOs2O6 (A = Cs, Rb, K) are studied by measuring resistivity under high pressures up to 10 GPa. The superconducting transition temperature Tc first…

Superconductivity · Physics 2009-11-11 T. Muramatsu , N. Takeshita , C. Terakura , H. Takagi , Y. Tokura , S. Yonezawa , Y. Muraoka , Z. Hiroi

LaRu$_3$Si$_2$ is of current research interest as a kagome metal with a superconducting transition temperature, $T_c\sim$7 K and higher temperature charge density wave (CDW) orders. Here we report electrical transport and X-ray diffraction…

Electronic properties of the metallic pyrochlore oxide Cd2Re2O7 are studied by means of electrical resistivity and Hall measurements. Semimetallic band structures are revealed as expected from band structure calculations. It is found that…

Strongly Correlated Electrons · Physics 2009-11-07 Z. Hiroi , M. Hanawa , Y. Muraoka , H. Harima

We have carried out a detailed high-pressure investigation on the strongly correlated transition metal chalcogenide $Cr_{3}Te_4$ using Raman spectroscopy and XRD, which is ferromagnetic and metallic at ambient conditions. We find that the…

We have determined the crystal structures and superconducting transition temperatures of La1.48Nd0.4Sr0.12CuO4 under nearly hydrostatic pressures in diamond anvil cells to 5.0 GPa and 19.0 GPa, respectively. Synchrotron x-ray powder…

The high-pressure behavior of silicon telluride (Si2Te3), a two-dimensional (2D) layered material, was investigated using synchrotron X-ray powder diffraction in a diamond anvil cell to 11.5 GPa coupled with first-principles theory. Si2Te3…

Materials Science · Physics 2024-10-10 Bohan Li , Frank Cerasoli , Ethan Chen , Martin Kunz , Davide Donadio , Kristie J. Koski

We report Cd NMR and Re NQR studies on Cd2Re2O7, the first superconductor among pyrochlore oxides Tc=1 K. Re NQR spectrum at zero magnetic field below 100 K rules out any magnetic or charge order. The spin-lattice relaxation rate below Tc…

Superconductivity · Physics 2013-03-05 O. Vyaselev , K. Arai , K. Kobayashi , J. Yamazaki , K. Kodama , M. Takigaawa , M. Hanawa , Z. Hiroi