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Recent developments in Macroscopic Fluctuation Theory show that many interacting particle systems behave macroscopically as a combination of a gradient flow with Hamiltonian dynamics. This observation leads to the natural question how these…

Mathematical Physics · Physics 2024-02-07 D. R. Michiel Renger

Thermodynamics as limiting behaviors of statistics is generalized to arbitrary system with probability {\it a priori} where thermodynamic infinite-size limit is replaced by multiple-measurement limit. A duality symmetry between Massieu's…

Statistical Mechanics · Physics 2022-09-28 Zhiyue Lu , Hong Qian

A statistical thermodynamic approach of moving particles forming an elastic body is presented which leads to reveal molecular-mechanical properties of classical and nonextensive dynamical systems. We derive the Boltzmann-Gibbs (BG) entropy…

Statistical Mechanics · Physics 2009-11-10 Enrique Canessa

The generalized entropic measure, which is optimized by a given arbitrary distribution under the constraints on normalization of the distribution and the finite ordinary expectation value of a physical random quantity, is considered and its…

Statistical Mechanics · Physics 2009-11-10 Sumiyoshi Abe , G. Kaniadakis , A. M. Scarfone

Fluctuation scaling is observed phenomenon from complex networks through finance to ecology. It means that the variance and the mean of a specific quantity are related as $\ev{\sigma^2|n}\propto \ev{n|A}^{2\alpha}$ with $1/2\geq \alpha \geq…

Physics and Society · Physics 2008-12-02 Zoltan Eisler , Janos Kertesz

A way to construct Boltzmann entropy, i.e., the entropy as a function of a microscopic pure state, for quantum field systems is proposed. Operators that shift the field in wavevector space are used in the construction. By employing an…

Statistical Mechanics · Physics 2020-03-25 Kyo Yoshida

Tropical limit for macroscopic systems in equilibrium defined as the formal limit of Boltzmann constant k going to 0 is discussed. It is shown that such tropical limit is well-adapted to analyse properties of systems with highly degenerated…

Mathematical Physics · Physics 2015-05-20 M. Angelelli , B. Konopelchenko

Very recently, the validity of the concept of negative temperature has been challenged by several authors since they consider Boltzmann's entropy (that allows negative temperatures) inconsistent from a mathematical and statistical point of…

Statistical Mechanics · Physics 2016-12-21 Pierfrancesco Buonsante , Roberto Franzosi , Augusto Smerzi

This is an analysis of the additivity of the entropy of thermodynamical systems with finite heat baths. It is presented an expression for the physical entropy of weakly interacting ergodic systems, and it is shown that it is valid for both…

Statistical Mechanics · Physics 2007-05-23 M. P. Almeida

Introducing the Boltzmann distribution very early in a statistical thermodynamics course (in the spirit of Feynmann) has many didactic advantages, in particular that of easily deriving the Gibbs entropy formula. In this note, a short…

Statistical Mechanics · Physics 2023-02-03 Didier Lairez

Boltzmann-Gibbs statistical mechanics applies satisfactorily to a plethora of systems. It fails however for complex systems generically involving strong space-time entanglement. Its generalization based on nonadditive $q$-entropies…

Statistical Mechanics · Physics 2021-01-15 R. M. de Oliveira , Samuraí Brito , L. R. da Silva , Constantino Tsallis

Common ground to recent studies exploiting relations between dynamical systems and non-equilibrium statistical mechanics is, so we argue, the standard Gibbs formalism applied on the level of space-time histories. The assumptions (chaoticity…

Mathematical Physics · Physics 2015-06-26 Christian Maes

We analytically study a one dimensional compaction model in the glassy regime. Both correlation and response functions are calculated exactly in the evolving dense and low tapping strength limit, where the density relaxes in a $1/\ln t$…

Statistical Mechanics · Physics 2009-11-10 Martin Depken , Robin Stinchcombe

Within its range of applicability, the Boltzmann equation seems unique in its capacity to accurately describe the transition from almost any initial state to a self-equilibrated thermal state. Using information-theoretic methods to rephrase…

Statistical Mechanics · Physics 2025-10-07 Jürgen T. Stockburger

We prove that information-theoretic maximum entropy (MaxEnt) approach to canonical ensemble is mathematically equivalent to the classic approach of Boltzmann, Gibbs and Darwin-Fowler. The two approaches, however, "interpret" a same…

Statistical Mechanics · Physics 2011-06-01 Hao Ge , Hong Qian

This short book is an elementary course on entropy, leading up to a calculation of the entropy of hydrogen gas at standard temperature and pressure. Topics covered include information, Shannon entropy and Gibbs entropy, the principle of…

Statistical Mechanics · Physics 2025-11-18 John C. Baez

The probability distribution of the total entropy production in the non-equilibrium steady state follows a symmetry relation called the fluctuation theorem. When a certain part of the system is masked or hidden, it is difficult to infer the…

Statistical Mechanics · Physics 2020-04-29 Deepak Gupta , Sanjib Sabhapandit

The method of Maximum (relative) Entropy (ME) is used to translate the information contained in the known form of the likelihood into a prior distribution for Bayesian inference. The argument is guided by intuition gained from the…

Data Analysis, Statistics and Probability · Physics 2009-11-10 Ariel Caticha , Roland Preuss

A dynamical estimate is given for the Boltzmann entropy of the Universe, under the simplifying assumptions provided by Newtonian cosmology. We first model the cosmological fluid as the probability fluid of a quantum-mechanical system. Next,…

Quantum Physics · Physics 2023-07-19 D. Cabrera , P. Fernandez de Cordoba , J. M. Isidro

The mixing of two different gases is one of the most common natural phenomena, with applications ranging from CO$_2$ capture to water purification. Traditionally, mixing is analyzed in the context of local thermal equilibrium, where systems…

Quantum Physics · Physics 2025-07-08 Budhaditya Bhattacharjee , Rohit Kishan Ray , Dominik Šafránek