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Materials with reduced dimensions have been shown to host a wide variety of exotic properties and novel quantum states that often defy textbook wisdom1-5. Ferroelectric polarization and metallicity are well-known examples of mutually…

We review the class of materials known as polar metals, in which polarity and metallicity coexist in the same phase. While the notion of polar metals was first invoked more than 50 years ago, their practical realization has proved…

Materials Science · Physics 2022-10-07 Sayantika Bhowal , Nicola A. Spaldin

Polar metals characterized by the simultaneous coexistence of ferroelectric distortions and metallicity have attracted tremendous attention. Developing such materials at low dimensions remains challenging since both conducting electrons and…

Materials Science · Physics 2020-03-24 Tao Xu , Jingtong Zhang , Yuquan Zhu , Jie Wang , Takahiro Shimada , Takayuki Kitamura , Tong-Yi Zhang

Polar metals are an underexplored material class combining two properties that are typically incompatible, namely a polar crystal structure and reasonable electrical conductivity. These intriguing materials offer a unique combination of…

Intrinsic polar metals are rare, especially in oxides, because free electrons screen electric fields in a metal and eliminate the internal dipoles that are needed to break inversion symmetry. Here we use first-principles high-throughput…

Materials Science · Physics 2020-02-06 Yue-Wen Fang , Hanghui Chen

Polar metals, materials in which electric polarisation and metallicity coexist, are exceptionally rare because itinerant electrons screen long-range dipoles and favour centrosymmetric structures. Engineering polar textures in a conducting…

Polar metals and noncentrosymmetric superconductors are exceptionally rare, yet their broken inversion symmetry can give rise to emergent electronic phenomena including mixed singlet-triplet superconducting pairing. As only a few such…

Two-dimensional polar liquid crystals have been discovered recently in monolayers of anisotropic molecules. Here, we provide a systematic theoretical description of liquid-crystalline phases for polar particles in two spatial dimensions.…

Soft Condensed Matter · Physics 2014-01-28 Raphael Wittkowski , Hartmut Löwen , Helmut R. Brand

Near-infrared-to-visible second harmonic generation from air-stable two-dimensional polar gallium and indium metals is described. The photonic properties of 2D metals - including the largest second-order susceptibilities reported for metals…

The first switchable electric polarization in metals was recently discovered in bilayer and trilayer WTe2. Strangely, despite the tininess of the ordered polarization, the ferroelectricity survives up to 350 K, rendering the mechanism of…

Materials Science · Physics 2025-07-25 Fangyuan Gu , Ruoshi Jiang , Wei Ku

Integrating multiple properties in a single system is crucial for the continuous developments in electronic devices. However, some physical properties are mutually exclusive in nature. Here, we report the coexistence of two seemingly…

The simultaneous presence of polarity and metallicity in a material signifies an exotic polar metal state, but such materials are extremely rare, especially in bulk form, due to mutually exclusive nature of the fundamental defining…

The coexistence of metallicity and ferroelectricity has been an intriguing and controversial phenomenon as these two material properties are considered incompatible in bulk. We clarify the concept of ferroelectric metal by revisiting the…

Materials Science · Physics 2021-11-01 Changming Ke , Jiawei Huang , Shi Liu

Over the past decade, materials that combine broken inversion symmetry with metallic conductivity have gone from a thought experiment to one of the fastest growing research topics. In 2013, the observation of the first uncontested polar…

Materials Science · Physics 2023-01-10 Daniel Hickox-Young , Danilo Puggioni , James M. Rondinelli

The polar metal is a material that hosts both polar distortion and metallicity. Such a material is expected to show exotic magneto-electric phenomena if superconducts. Here, we theoretically explore ferroelectric and superconducting…

Superconductivity · Physics 2021-05-26 Minjae Ghim , Nobuya Sato , Ryosuke Akashi , Seung-Hoon Jhi , Shinji Tsuneyuki

A methodology for forming a qubit state is essential for quantum applications of room temperature polaritons. While polarization degree of freedom is expected as a possible means for this purpose, the coupling of linearly polarized…

Materials Science · Physics 2023-05-12 Yuta Moriyama , Takaya Inukai , Tsukasa Hirao , Yusuke Ueda , Shun Takahashi , Kenichi Yamashita

Two-dimensional (2D) materials are not expected to be metals at low temperature due to electron localization. Consistent with this, pioneering studies on thin films reported only superconducting and insulating ground states, with a direct…

Superconductivity · Physics 2016-03-23 A. W. Tsen , B. Hunt , Y. D. Kim , Z. J. Yuan , S. Jia , R. J. Cava , J. Hone , P. Kim , C. R. Dean , A. N. Pasupathy

The recent observation of a ferroelectric-like structural transition in metallic LiOsO$_3$ has generated a flurry of interest in the properties of polar metals. Such materials are thought to be rare because free electrons screen out the…

Materials Science · Physics 2016-02-29 Nicole A. Benedek , Turan Birol

Almost all oxide two-dimensional electron gases are formed in SrTiO$_3$-based heterostructures and the study of non-SrTiO$_3$ systems is extremely rare. Here, we report the realization of a two-dimensional electron gas in a CaTiO$_3$-based…

In the early 2000s, low dimensional systems were predicted to have topologically nontrivial polar structures, such as vortices or skyrmions, depending on mechanical or electrical boundary conditions. A few variants of these structures have…

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