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Using real-time spectroscopic ellipsometry, we directly observed a reversible lattice and electronic structure evolution in SrCoOx (x = 2.5 - 3) epitaxial thin films. Drastically different electronic ground states, which are extremely…

Strongly Correlated Electrons · Physics 2013-08-29 Woo Seok Choi , Hyoungjeen Jeen , Jun Hee Lee , S. S. Ambrose Seo , Valentino R. Cooper , Karin M. Rabe , Ho Nyung Lee

We have investigated the atomically-resolved substrate and homoepitaxial thin film surfaces of SrTiO3(001) using low-temperature scanning tunneling microscopy/spectroscopy (STM/STS) combined with pulsed laser deposition (PLD). It was found…

Materials Science · Physics 2015-05-18 Takeo Ohsawa , Katsuya Iwaya , Ryota Shimizu , Tomihiro Hashizume , Taro Hitosugi

Many of the recent advancements in oxide heterostructures have been attributed to modification of spin, charge, lattice, and orbital order parameters at atomically well-defined interfaces. However, the details on the structural, chemical,…

We investigate the effect of the laser parameters of pulsed laser deposition on the film stoichiometry and electronic properties of LaAlO_3/SrTiO_3 (001) heterostructures. The La/Al ratio in the LaAlO_3 films was varied over a wide range…

Materials Science · Physics 2015-06-15 H. K. Sato , C. Bell , Y. Hikita , H. Y. Hwang

The durability of passivable metals and alloys is often limited by the stability of the surface oxide film, the passive film, providing self-protection against corrosion in aggressive environments. Improving this stability requires to…

Materials Science · Physics 2019-07-26 Li Ma , Frederic Wiame , Vincent Maurice , Philippe Marcus

Cross-sectional scanning tunneling microscopy was utilized to study fractured perovskie oxide surfaces. It was found for the non-cleavable perovskite oxide, SrTiO$_{3}$, that atomically flat terraces could be routinely created with a…

Mesoscale and Nanoscale Physics · Physics 2010-07-07 TeYu Chien , Nathan P. Guisinger , John W. Freeland

We present atomic scale images of a V_2O_3 (0001)-surface, which show that the surface is susceptible to reconstruction by dimerization of vanadium ions. The atomic order of the surface depends sensitively on the surface preparation.…

Strongly Correlated Electrons · Physics 2009-11-07 M. Preisinger , J. Will , M. Klemm , S. Klimm , S. Horn

A first-principles atomic orbital-based electronic structure method is used to investigate the low index surfaces of rutile Titanium Dioxide. The method is relatively cheap in computational terms, making it attractive for the study of oxide…

Materials Science · Physics 2009-10-28 O. Gulseren , R. James , D. W. Bullett

X-ray diffraction studies showed that the structure of (Sr$_{1-x}$Pr$_x$)TiO$_3$ solid solutions at 300 K changes from the cubic $Pm3m$ to the tetragonal $I4/mcm$ with increasing $x$. The analysis of XANES and EXAFS spectra of the solid…

Materials Science · Physics 2012-07-26 I. A. Sluchinskaya , A. I. Lebedev , A. Erko

The emerging field of complex oxide interfaces is generically built on one of the most celebrated substrates - strontium titanate (SrTiO3). This material hosts a range of phenomena, including ferroelasticity, incipient ferroelectricity, and…

Mesoscale and Nanoscale Physics · Physics 2013-12-13 Maayan Honig , Joseph A. Sulpizio , Jonathan Drori , Arjun Joshua , Eli Zeldov , Shahal Ilani

A large challenge in determining the physics of helimagnetic SrFeO3 is in stabilizing the stoichiometric chemical phase over long enough time scales to conduct extensive measurements. Degradation in SrFeO3 manifests mainly as a crossover…

Atomically engineered oxide multilayers and superlattices display unique properties responsive to the electronic and atomic structures of the interfaces. We have followed the growth of ferroelectric BaTiO3 on SrRuO3 electrode with in situ…

A heterostructure of Ba$_{1-x}$Sr$_x$TiO$_3$/La$_{1.1}$Sr$_{0.9}$NiO$_3$ /SrTiO$_3$ has been analysed by magnetic sector secondary ion mass spectrometry (SIMS). The stoichiometry parameter $x$ of the top layer was made varying continuously…

Materials Science · Physics 2025-03-06 J. Scola , F. Jomard , E. Loire , J. Wolfman , B. Negulescu , G. Z. Liu , M. -A. Pinault-Thaury

A magnetite (Fe3O4) single crystal (111) surface has been studied at various oxygen-iron surface stoichiometries. The stoichiometry was modified by controlling the in-situ sample anneal conditions. We have found the conditions that lead to…

Soft Condensed Matter · Physics 2007-05-23 N. Berdunov , S. Murphy , G. Mariotto , I. V. Shvets

The highly conducting and transparent inorganic perovskites SrBO$_3$ with V, Nb, Mo, and their mixtures at the B-site have recently attracted the attention of the oxide electronics community as novel alternative transparent conducting…

Perovskite oxide interfaces have attracted tremendous research interest for their fundamental physics and promising all-oxide electronics applications. Here, based on first-principles calculations, we propose a novel surface La interstitial…

Materials Science · Physics 2017-12-06 Jun Zhou , Ming Yang , Yuan Ping Feng , Andrivo Rusydi

The electronic structure of SrTiO3 and SrHfO3 (001) surfaces with oxygen vacancies is studied by means of first-principles calculations. We reveal how oxygen vacancies within the first atomic layer of the SrTiO3 surface (i) induce a large…

Strongly Correlated Electrons · Physics 2016-01-13 A. C. Garcia-Castro , M. G. Vergniory , E. Bousquet , A. H. Romero

Understanding the structural phase diagram of nano scale SrTiO3 has important implications on the basic physics and applications of the general class of transition metal oxide perovskites. Pressure dependent structural measurements on…

The surface composition of polycrystalline niobium-doped strontium titanate (SrTiO3 : Nb) is studied using X-ray photoelectron emission microscopy (XPEEM) for many grain orientations in order to characterise the surface chemistry with high…

LaAlO$_{3}$ and NdGaO$_{3}$ thin films of different thickness have been grown by pulsed laser deposition on TiO$_2$-terminated SrTiO$_{3}$ single crystals and investigated by soft X-ray photoemission spectroscopy. The surface sensitivity of…