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Related papers: Relaxation dynamics in the one-dimensional organic…

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We report a molecular dynamics (MD) study of the collective dynamics of a simple monatomic liquid -interacting through a two body potential that mimics that of lithium- across the liquid-glass transition. In the glassy phase we find…

Disordered Systems and Neural Networks · Physics 2009-11-07 T. Scopigno , G. Ruocco , F. Sette , G. Viliani

Glass-forming liquids have only a modest tendency to crystallize and hence their dynamics can be studied even below the melting temperature. The relaxation dynamics of most of these liquids shows at a temperature $T_c$, somewhat above the…

Soft Condensed Matter · Physics 2025-01-17 Francesco Rusciano , Raffaele Pastore , Francesco Greco , Walter Kob

The charge degrees of freedom in several different organic charge transfer salts display slow or glassy dynamics. In order to gain insight into this behaviour, we obtain the low energy theory for an extended dimer Hubbard model, taking into…

Strongly Correlated Electrons · Physics 2022-08-31 Meldon B. Deglint , Krishant Akella , Malcolm P. Kennett

We present a molecular-dynamics study of the solvent reorganization energy of electron transfer in supercooled water. We observe a sharp decrease of the reorganization energy at a temperature identified as the temperature of structural…

Soft Condensed Matter · Physics 2007-05-23 Pradip K. Ghorai , Dmitry V. Matyushov

We present results of the coefficient of thermal expansion for the frustrated quasi-two-dimensional molecular conductor $\theta$-(BEDT-TTF)$_2$RbZn(SCN)$_4$ for temperatures 1.5 K $\leq T \leq$ 290 K. A pronounced first-order phase…

Strongly Correlated Electrons · Physics 2024-05-08 Yohei Saito , Owen Ganter , Chao Shang , Kenichiro Hashimoto , Takahiko Sasaki , Stephen M. Winter , Jens Müller , Michael Lang

We report a thorough characterization of the dielectric relaxation behavior and the ionic conductivity in the plastic-crystalline mixture of 60% succinonitrile and 40% glutaronitrile. The plastic phase can be easily supercooled and the…

Disordered Systems and Neural Networks · Physics 2011-02-16 Th. Bauer , M. Köhler , P. Lunkenheimer , A. Loidl , C. A. Angell

Slow relaxation and heterogeneous dynamics are characteristic features of glasses. The presence of glassy dynamics in nonequilibrium systems, such as active matter, is of significant interest due to its implications for living systems and…

Soft Condensed Matter · Physics 2024-06-27 Antina Ghosh , Sayan Maity , Vijayakumar Chikkadi

Charge-ordering phenomena have been highly topical over the last few years. A phase transition towards a charge ordered state has been observed experimentally in several classes of materials. Among them, many studies have been devoted to…

Strongly Correlated Electrons · Physics 2013-08-01 Mariano de Souza , Jean-Paul Pouget

We utilize a glass-like structural transition in order to induce a Mott metal-insulator transition in the quasi-two-dimensional organic charge-transfer salt $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Br. In this material, the terminal ethylene…

Strongly Correlated Electrons · Physics 2014-12-19 B. Hartmann , J. Müller , T. Sasaki

Non-equilibrium charge dynamics, such as cooling-rate-dependent charge vitrification and physical aging, have been demonstrated for a charge-cluster glass in $\theta$-(BEDT-TTF)$_2$CsZn(SCN)$_4$ using electron transport measurements. The…

Strongly Correlated Electrons · Physics 2014-03-17 T. Sato , F. Kagawa , K. Kobayashi , K. Miyagawa , K. Kanoda , R. Kumai , Y. Murakami , Y. Tokura

The out-of-equilibrium excess conductance of electron-glasses typically relaxes with a logarithmic time-dependence. Here it is shown that the log(t) relaxation of a weakly-disordered amorphous indium-oxide films crosses-over asymptotically…

Disordered Systems and Neural Networks · Physics 2018-06-04 Z. Ovadyahu

Temporal relaxation of density fluctuations in supercooled liquids near the glass transition occurs in multiple steps. The short-time $\beta$-relaxation is generally attributed to spatially local processes involving the rattling motion of a…

Statistical Mechanics · Physics 2016-03-02 Smarajit Karmakar , Chandan Dasgupta , Srikanth Sastry

Amorphous solids or glasses are known to exhibit stretched-exponential decay over broad time intervals in several of their macroscopic observables: intermediate scattering function, dielectric relaxation modulus, time-elastic modulus etc.…

Soft Condensed Matter · Physics 2017-01-19 B. Cui , R. Milkus , A. Zaccone

Complementary Neutron Spin Echo and X-ray experiments and Molecular Dynamics simulations have been performed on difluorotetrachloroethane (CFCl2-CFCl2) glassy crystal. Static, single-molecule reorientational dynamics and collective dynamics…

Soft Condensed Matter · Physics 2009-11-11 F. Affouard , E. Cochin , F. Danède , R. Decressain , M. Descamps , W. Haeussler

We provide broadband dielectric loss spectra of glass-forming glycerol with varying additions of LiCl. The measurements covering frequencies up to 10 THz extend well into the region of the fast beta process, commonly ascribed to caged…

Soft Condensed Matter · Physics 2013-08-07 M. Köhler , P. Lunkenheimer , Y. Goncharov , A. Loidl

We report the combined results of molecular dynamics simulations and theoretical calculations concerning various dynamical arrest transitions in a model system representing a dipolar fluid, namely, N (softcore) rigid spheres interacting…

The principal theme of this paper is that anomalously slow, super-Arrhenius relaxations in glassy materials may be activated processes involving chains of molecular displacements. As pointed out in a preceding paper with A. Lemaitre, the…

Materials Science · Physics 2009-11-11 J. S. Langer

Equilibration of a one-dimensional system of interacting electrons requires processes that change the numbers of left- and right-moving particles. At low temperatures such processes are strongly suppressed, resulting in slow relaxation…

Mesoscale and Nanoscale Physics · Physics 2010-07-22 K. A. Matveev , A. V. Andreev , M. Pustilnik

Deep eutectic solvents with admixed lithium salts are considered as electrolytes in electrochemical devices like batteries or supercapacitors. Compared to eutectic mixtures of hydrogen-bond donors and lithium salts, their raw-material costs…

Soft Condensed Matter · Physics 2024-04-22 A. Schulz , P. Lunkenheimer , A. Loidl

Using a combination of resistance fluctuation (noise) and dielectric spectroscopy we investigate the nature of relaxor-type electronic ferroelectricity in the organic conductor $\kappa$-(BETS)$_2$Mn[N(CN)$_2$]$_3$, a system representative…